Disposcope内镜在气管插管中的应用进展

随着可视化技术的进步,越来越多的可视化工具被应用于气管插管领域,其拥有定位准确、创伤小、插管成功率高及并发症少等优点,增加了麻醉医师气道管理安全性和有效性。帝视内镜(DE)是一款可视管芯类气管插管工具,具有可视、镜身可弯曲和无线传输等特点。该文就目前DE在气管插管中的应用进展进行综述。

可视支气管堵塞器插管和可视双腔支气管导管插管的对比研究

目的比较可视支气管堵塞器(EBB)插管和可视双腔支气管导管(VDLT)插管在胸科手术中插管定位时间、单肺通气效果及对气道炎症应激反应的比较。方法选择行胸腔镜肺叶切除术的患者40例,随机分为两组,分别用VDLT插管和EBB插管。比较两组的插管时间、定位时间、导管移位率,记录两组患者插管前(T0)、插管即刻(气管导管主套囊过声门的时间)(T1)、插管定位成功即刻(T2)和插管定位成功后5 min(T3)时引起的心率(HR)、平均动脉压(MAP)变化和插管前后血清去甲肾上腺素(NE)、血清皮质醇(Cor)和C反应蛋白(CRP)等炎症应激水平的变化,并进行对比,以及比较单肺通气后两组不同时间点肺萎陷的程度。结果EBB组插管时间比VDLT组短,在T1和T2时刻,两组的HR和MAP相比差异有统计学意义,在T3时刻,两组患者炎症应激水平(NE、Cor和CRP)差异有统计学意义;VDLT组定位时间快于EBB组;两组导管移位率、纤维支气管镜(FOB)使用率、单肺通气后各时点肺萎陷的程度比较,差异无统计学意义。结论EBB插管时间快、定位准确、插管刺激小,术中持续气道可视化管理方便,值得推广。

Microstructure and creep properties of Ni-based single-crystal superalloys with Mo/Al addition at 760℃/850 MPa

The effect of Mo and Al addition on the microstructure as well as creep rupture properties at760.C/850 MPa was investigated by transmission electron microscopy(TEM)in a Ni-based single-crystal(SC)alloy with the composition of Ni-6.5Al-8.0Mo-2.4Cr-6.2Ta-4.9Co-1.5Re-(0.01-0.05)Y(wt%).The microstructure analysis shows that 0.5 wt%Al addition induces rapid decrease in creep rupture life,and this can be attributed to the formation of dense stacking faults cutting intoγ'precipitates,which can be explained by the increase in Orowan stress caused by the narrowerγchannel width and the decrease in stacking faults energy.Besides,1.5 wt%Mo addition increases the anti-phase boundary energy and decreases the stacking faults energy,resulting in fewer stacking faults and thus a slight decrease in the creep rupture life.

Cyclic oxidation behavior of Ni_(3)Al-based single crystal alloy IC21

In this study,the cyclic oxidation tests of the Ni3Al-based single-crystal super alloy IC21 were carried out at 800,900,950,1000,1050 and 1100℃in air.The present study shows that the complex oxide scale on the surface of the alloy is made up of an outer columnar NiO layer,an intermediate mixture of NiO and NiAl2O4layer with a small amount of Mo oxides and an inner continuous layer ofα-Al_(2)O_(3).The cyclic oxidation kinetics curves show that oxidation resistance at 800,900,950,1000 and1050℃seems to follow a similar law and is better than that at 1100℃.The overall weight changes at 1100℃follows a parabolic law.Spallation and severe rumpling of the oxide scale are observed on the surface of the alloy at1100℃,revealing the occurrence of disastrous oxidation.

Oxidation behaviour of electron beam physical vapour deposition β-NiAlHf coatings at 1100℃ in dry and humid atmospheres

NiA1 intermetallic compounds attract increas- ing attention for high-temperature applications due to their combination of excellent properties, especially as metallic protective coatings on superalloys or as bond coats in thermal barrier coatings （TBCs）. Oxidation behaviour of the β-NiA1Hf coatings prepared by electron beam physical vapour deposition （EB-PVD） was investigated at 1100 ℃ for short time and 100h in 20% 02＋Ar and 15 % H20 ＋ Ar, respectively. The results of mass changes re- veal that the addition of minor reactive element Hf sig- nificantly improves the cyclic oxidation resistance of the 13- NiA1 coatings in both dry and humid atmospheres. During the initial oxidation stage, water vapour retards the phase transformation from 0-A1203 to a-A1203. Moreover, com- pared with the case in dry atmosphere, water vapour sig- nificantly reduces the surface roughness of the oxide scales formed on EB-PVD β-NiA1Hf coatings after 100 h cyclic oxidation, which corresponds with the difference of surface morphologies of the oxide scales.

Deposition of TiN/TiAlN multilayers by plasma-activated EB-PVD:tailored microstructure by jumping beam technology

Plasma-activated electron beam-physical vapor deposition（EB-PVD）was used for depositing nitride multilayer coatings in this work.Different from the conventional coating methods,the multilayers were obtained by manipulating electron beam（EB）to jump between two different evaporation sources alternately with variable frequencies（jumping beam technology）.The plasma activation was generated by a hollow cathode plasma unit.The deposition process was demonstrated by means of tailoring TiN/TiAlN multilayers with different modulation periods（M1：26.5 nm,M2：80.0 nm,M3：6.0 nm,M4：4.0 nm）.The microstructure and hardness of the multilayer coatings were comparatively studied with TiN and TiAlN singlelayer coatings.The columnar structure of the coatings（TiN,TiAlN,M1,M2）is replaced by a glassy-like microstructure when the modulation period decreases to less than 10 nm（M3,M4）.Simultaneously,superlattice growth occurs.With the decrease of modulation period,both the hardness and the plastic deformation resistance（H^3/E^2,H-hardness and E-elastic modulus）increase.M4coating exhibits the maximum hardness of（49.6±2.7）GPa and the maximum plastic deformation resistance of^0.74 GPa.

Improved mechanical properties of Ni-rich Ni3Al coatings produced by EB-PVD for repairing single crystal blades

Active control of turbine blade tip clearance for aircraft engine continues to be a concern in engine opera- tion, because turbine blades are subjected to wear and therefore cause an increasing tip clearance between the rotating blades and the shroud and also reduce the engine efficiency. In this work, a Ni-rich Ni3A1 coating with γ＇/γ two-phase microstructure was deposited by electron beam physical vapor deposition （EB-PVD）, which worked as repairing the worn blade tips of single crystal blades. Nb molten pool was used to increase the molten pool tem- perature and thus to enhance the deposition rate. The microstructures and mechanical properties can be modified by the deposition temperatures and the following heat treatments. All coatings consist of γ＇ and γ phases. At deposition temperature of 600 ℃, a dense microstructure can be achieved to produce a coating with grain size of 1 μm and microhardness of -HV 477. After being heated for 4 h at a temperature of 1,100 ℃, the coatings have a more uniform microstructure, and microhardness maintains at a high level of -HV 292. Effect of Hf and Zr on EB-PVD Ni3Al repair coating will be further investigated.

Thermal cycling performance of La_(2)Ce_(2)O_(7)/YSZ TBCs with Pt/Dy co-doped NiAl bond coat on single crystal superalloy

Thermal barrier coatings(TBCs) consisting ofLa_(2)Ce_(2)O_(7)(LCO) and Y_(2)O_(3)-stabilized-ZrO_(2)(YSZ) doubleceramic layer and Dy/Pt co-doped NiAl bond coat were produced by electron beam physical vapor deposition(EBPVD). Thermal cyclic performance of the TBCs was evaluated by flame shock testing at 1300 ℃. For comparison, the TBCs with a undoped NiAl bond coat were also studied. The microstructural evolution and failure mechanisms of the above TBCs during thermal cycling were investigated. Spallation failure of the TBCs with the undoped bond coat occurs after around 500 cycles by cracking at the interface between YSZ ceramic layer and thermally grown oxides(TGO) layer. The TBCs with Pt/Dy modified bond coat reveal improved interface bonding even after 1200 thermal cycles, whereas some delamination cracks are presented in the LCO layer. On the other hand,the Pt/Dy modified bond coat effectively suppresses the formation of the needle-like topologically closed packed phases(TCP) in the single crystal superalloy.

Partitioning behavior and lattice misfit of γ/γ’phases in Ni-based superalloys with different Mo additions

A low-density single crystal(LDS) alloy with the composition of high Mo content was designed.The extra 1.5 wt% Mo was added in the Alloy A with the composition of Ni-6.5 Al-8.0 Mo-2.4 Cr-6.2 Ta-4.9 Co-1.5 Re-(0.01-0.05) Y(wt%) to study the influence of Mo on the lattice parameter and partitioning behavior.Scanning electron microscope(SEM) with energy-dispersive spectrometer(EDS),transmission electron microscopy(TEM)and high-temperature X-ray diffraction(HT-XRD) were used to observe the microstructure,analyze the elemental content and measure the lattice parameter of the alloys.The natural lattice misfit was calculated by lattice constants which were measured by HT-XRD at the temperature from 25 to 1150℃,and the results showed that the lattice misfit would be more and more negative with temperature increasing.It was found that 1.5 wt% addition of Mo will increase the absolute value of the lattice misfit of γ/γ’phases and the volume fraction of γ’,and at the same time,influence the elemental distribution in γ and γ’ phases,especially Re and Cr.Re has a higher partitioning ratio(k) after the addition of Mo.

Existence patterns of Dy in β-NiAl from first-principles calculations

Intermetallic compound β-NiA1 is a promising material in high temperature applications due to its high melting temperature, high strength, low density, and good oxidation resistance. However, its application remains limited because of its relatively poor cyclic oxidation resistance. Addition of reactive element （RE） Dy can improve the cyclic oxidation of NiA1 alloys significantly. However, the mechanism of Dy addition is not clear. Even the existence pattern of Dy in NiA1 is unspecified. Therefore, in the present study, the impurity formation energies of Dy in stoichiometric NiA1, Ni-rich, and Al-rich NiA1 for the substitution cases were studied by first-principles density functional theory. The results show that Dy could hardly substitute for either Ni or A1 atoms in NiA1. However, calculations for dissolution energies show that Dy could be easily dissolved in AI vacancies in all three types of NiA1, which provides a new existence pattern of Dy in NiA1 beyond experimental detection.

Directional solidification behavior of turbine blades in DZ125 alloy:design of blade numbers on assembly

The influence of blades assembly,i.e.,the blade number on the solidification process,heat exchange and grain structure on a directionally solidified Ni-based superalloy DZ125 was investigated by combining the experimental and simulation results.The casting process was simulated thermodynamically by ProCAST software,where the interface heat transfer coefficient was precisely determined by a measurement with thermocouples.There is a good agreement between experimental and simulation results.It was interestingly found that with the number of blades increasing from 6 to 10,due to the decrease in radiation absorption efficiency,the maximum temperature and the heating rate decrease in the mold,during the preheat process.During the withdrawal procedure,increased assembly numbers reduce the radiation exchange from mold to the enclosure,resulting in the decrease in cooling rate and temperature gradient of the blades.At the end of withdrawal,the slower cooling rate of the outside balances the temperature distribution of internal and external surfaces on the rabbet of blade.

Effect of applied stress on r'-rafting behavior in a Ni-based singlecrystal superalloy:experiments and finite element analysis

The effect of applied tensile stress on the r'-rafting behavior for a Ni-based single-crystal superalloy with more negative misfit was investigated.By conducting interrupted creep tests at high temperature,it indicated that the increase in the applied stress accelerates the r'-rafting(directional coarsening of yr phase).In the early stage of rafting,the r'-cubes start interconnecting at the ends of the parallel-to-applied-stress r'-channel.The distributions of misfit stress,coherent strain and strain energy density of the r/r'phases are then calculated by finite element analysis.The calculation results show that the rafting acceleration is mainly ascribed to the reduced strain energy density in the parallel-to-applied-stress r'-channel that is driven from the couple interaction of external load and misfit stress.Interface dislocation network formation,resulting from the misfit-induced increase in resolved shear stress,also contributes to the r'-rafting.

Cyclic oxidation behavior of Cr-/Si-modified NiAlHf coatings on single-crystal superalloy produced by EB-PVD

The Cr-/Si-modified Ni Al Hf coatings were produced on single-crystal（SC） superalloy N5 by electron beam physical vapor deposition（EB-PVD）. The cyclic oxidation behavior of the coatings at 1100 °C was investigated. The microstructures of the oxide scales grown on the coatings were characterized by scanning electron microscope（SEM） with energy-dispersive X-ray spectrum（EDX）,electron probe micro-analyzer（EPMA） and X-ray diffraction（XRD）. The effects of Cr and Si on the cyclic oxidation behavior of the Ni Al Hf coatings were discussed. The addition of Si to the Ni Al Hf Cr coating not only reduces the oxidation rate but also enhances the oxide scale adherence.Owing to the addition of Si in the coating, the segregation of Cr and Mo beneath the oxide scale is effectively avoided,which contributes to enhancing oxide scale adherence.

Effect of trace Ce on high-temperature oxidation behavior of an Al-Sicoated Ni-based single crystal superalloy

Ni-based single crystal superalloy IC21 with different Ce con tents was prepared by screw selection method,and Al-Si coatings were prepared by pack cementation.Cyclic oxidation and transient oxidation were carried out at 1150℃ to investigate the effect of Ce on the high-temperature oxidation behavior of Al-Si coatings.After cyclic oxidation at 1150℃,the addition of trace Ce decreased the mass gain of the Al-Si-coated samples and effectively improved oxidation perform a nee and spallation resistance.In specimens without Ce doping,microstructure examinatio n revealed that bulkyγ-Ni3Al precipitated in oxidized coating because of high Al con sumption,and this finding suggests that Ce inhibits the consumption of Al in the coating during oxidation.Ce slows down the Ininsformation of O-Al2O3 to oc-Al2O3 and improves the adhesion of the oxide scale.

Microstructure stability of γ’+β Ni-Al coated single-crystal superalloy N5 annealed at 1100℃

γ’+β Binary-phase Ni-Al coatings were prepared on second-generation single-crystal superalloy Rene N5(N5) substrates by electron beam physical vapor deposition.Inter-diffusion behavior between coatings and substrates at 1100℃ and its effects on microstructure stability of the substrates were investigated.A 3-μm-thick substrate diffusion zone(SDZ) layer forms beneath the coating/substrate interface after 5-h heat treatment.The SDZ layer is composed of γ’-Ni_(3) Al phases and needle-like precipitates growing along(100)(110) or(100) <■> direction.After100-h annealing,the thickness of the SDZ layer increases to~17 μm,much lower than that of the single β-NiAl-coated substrate,while keeping single-crystal microstructure.

Sub-micron Co-Al_(2)O_(3) composite powders prepared by room-temperature ultrasonic-assisted electroless plating

Sub-micron Co-Al_(2)O_(3)composite powders were synthesized by ultrasonic-assisted electroless plating process at room temperature with a one-step activating method pretreatment.The effect of process parameters on plating rate,Co content,and the uniformity of cobalt layer was analyzed by transmission electron microscopy(TEM).The results show that as the initial pH values of plating bath increase,the plating rate increases.The plating rate declines as the load increases when the load of powders is less than 12 g·L^(-1),but increases when the load is greater than 12 g·L^(-1).The relative Co content of the Co-Al_(2)O_(3) powder declines with the powder load increasing.