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多孔氮化钛载体上铂催化剂的原子层沉积制备及其催化氧气还原性能 被引量:3
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作者 唐小龙 张盛辉 +7 位作者 于婧 吕春晓 迟雨晴 孙君伟 宋誉 袁丁 马兆立 张立学 《物理化学学报》 SCIE CAS CSCD 北大核心 2020年第7期84-90,共7页
为有效解决铂(Pt)催化剂用于氧气还原反应(ORR)面临的催化活性及稳定性问题,本文首先合成了具有良好导电性、电化学稳定以及耐腐蚀等优点的一维多孔氮化钛(Ti N)纳米管载体材料,然后使用原子层沉积技术(ALD)在Ti N载体上沉积制备了Pt催... 为有效解决铂(Pt)催化剂用于氧气还原反应(ORR)面临的催化活性及稳定性问题,本文首先合成了具有良好导电性、电化学稳定以及耐腐蚀等优点的一维多孔氮化钛(Ti N)纳米管载体材料,然后使用原子层沉积技术(ALD)在Ti N载体上沉积制备了Pt催化剂(ALD-Pt/Ti N),所得的Pt纳米颗粒尺寸均匀、高度分散且与Ti N载体之间存在着较强的相互作用。催化氧气还原活性和稳定性测试表明,所得的ALD-Pt/Ti N对ORR具有较高的催化活性,同时兼具良好的稳定性和耐久性。相比商用Pt/C,ALD-Pt/Ti N的起始电位和稳态极限电流密度与其相近,半波电位则高出了20 m V,表现出优异的电催化性能。其优良的电催化性能主要归因于ALD沉积Pt纳米颗粒的高分散性,一维多孔结构Ti N载体的高比表面积、良好导电性和抗腐蚀性能以及ALD-Pt与Ti N载体间较强的相互作用等综合影响。本工作为设计新型高催化活性、高稳定性的Pt基催化剂提供了有益借鉴。 展开更多
关键词 多孔氮化钛 Pt纳米颗粒 原子层沉积 电催化 氧气还原反应
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Heavy metals in sediments of Yellow Sea and East China Sea: Chemical speciation,distribution,influence factor,and contamination
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作者 Miao ZHAO shenghui zhang +1 位作者 Haitao HAN Dawei PAN 《Journal of Oceanology and Limnology》 SCIE CAS CSCD 2021年第4期1277-1292,共16页
Metal species and the degree of environmental pollution are related to the hydrogen sulfide(H_(2)S),an important product of early diagenesis that can react with metals to form stable compounds.To investigate the eff e... Metal species and the degree of environmental pollution are related to the hydrogen sulfide(H_(2)S),an important product of early diagenesis that can react with metals to form stable compounds.To investigate the eff ects of H_(2)S to metals and evaluate metal environment eff ect in the sediments of the East China Sea(ECS)and Yellow Sea(YS),geochemical characteristic and spatial distribution of nine heavy metals and H_(2)S profile were studied.Higher H_(2)S content and lower metal content was observed in the sediments 10 cm in depth in the North Yellow Sea and the west coast of South Korea.The pollution load index(I_(pl))indicates that the southern coast of Shandong Peninsula underwent moderate pollution(I_(pl)=1)of heavy metals and no heavy metal pollution appeared in other areas(I_(pl)<1).To some extents,the ecological risk of Cd and As enrichment was moderately severe in all stations.The chance of heavy metal combination to be toxic in ECS and YS during summer was 21%.In addition,correlation between H_(2)S content and metals in both solid and porewater phases was obvious,corroborating important eff ect of H_(2)S on metal distribution.Moreover,H_(2)S could aff ect the spatial distributions of heavy metals in porewater directly and be indicative of potential biological eff ects of combined toxicant groups in the study region. 展开更多
关键词 hydrogen sulfide heavy metal East China Sea and Yellow Sea sediment POREWATER risk assessment
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Effects of swirl and hot streak on thermal performances of a high-pressure turbine
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作者 shenghui zhang Shuiting DING +1 位作者 Peng LIU Tian QIU 《Chinese Journal of Aeronautics》 SCIE EI CAS CSCD 2023年第5期250-267,共18页
Advanced civil aero-engines tend to adopt lean burn combustors to meet emission requirements.The exit of a lean burn combustor experiences highly non-uniformities in both temperature(Hot Streak,HS)and flow(swirl).This... Advanced civil aero-engines tend to adopt lean burn combustors to meet emission requirements.The exit of a lean burn combustor experiences highly non-uniformities in both temperature(Hot Streak,HS)and flow(swirl).This paper presents a numerical investigation on the behaviors of a High-Pressure(HP)turbine under a combined effect of swirl and hot streak.The investigation was conducted on a GE-E3 HP turbine with unsteady numerical simulations,which considered the realistic clocking position of the HP Nozzle Guide Vane(NGV)relative to the combustor.The influences of swirl orientations on the HS migration and thermal performances on the blade surface were examined.Results indicate that,inside the NGV passage,the swirl’s induced incidence angle effect dominates the HS radial migration.The transversal movement of HS follows the cross flow and thus makes itself approach the Suction Side(SS)and keep away from the Pressure Side(PS)as passing through the NGV,so that HS near the SS is more influenced by the incidence angle effect than that near the PS.As for the heat transfer,swirl affects the Heat Transfer Coefficient(HTC)on the NGV’s PS and SS mainly through the incidence angle effect.Different from the NGV,the inlet swirl and HS have limited effect on the HTC on the rotor blade’s PS,while on the rotor blade’s SS,the original vortex system dominates;therefore,the inlet non-uniformities merely enhance the HTC on the SS rather than alter its distribution characteristics. 展开更多
关键词 High-pressure turbine Hot streak Thermal performances SWIRL ORIENTATIONS VORTEX
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Bi-Fo time scaling method in the numerical simulation of transient conjugate heat transfer
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作者 Yu Shi Shuiting Ding +2 位作者 Tian Qiu Chuankai Liu shenghui zhang 《Propulsion and Power Research》 SCIE 2021年第3期209-223,共15页
Reliable transient thermal analysis plays a very important role in the engine safety analysis.Transient conjugate heat transfer simulation is an important way of temperature analysis.But there exists a great disparity... Reliable transient thermal analysis plays a very important role in the engine safety analysis.Transient conjugate heat transfer simulation is an important way of temperature analysis.But there exists a great disparity in the time scales between solid conduction and fluid convection.The calculation cost of transient conjugate heat transfer analysis is very huge because of the tiny time step of computational fluid dynamics.The Bi-Fo time scaling method is proposed to improve the computational efficiency of transient conjugate heat transfer.On the one hand,this method carries out a similar transformation on solid heat conduction,scaling the calculation time with the product of density and specific heat capacity to maintain the consistency of Fourier number.On the other hand,it takes very short time for the fluid domain to recover stability after a boundary disturbance.Based on the above characteristic,the flow time is directly compressed to the same as that of the solid domain.It is verified by Mark II vane that increasing the solid thermal diffusivity can reduce the time scale of heat conduction.In the situation of rapidly stable flow field,scaling flow time does not affect the solid thermal boundary under corresponding dimensionless time.Within the application scope,the Bi-Fo time scaling method can greatly reduce the time cost of transient conjugate heat transfer simulation while maintaining the accuracy of transient temperature analysis. 展开更多
关键词 TRANSIENT Temperature analysis Conjugate heat transfer Similar transformation Time scaling
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