Developing non-precious metal catalysts with high activity and stability for electrochemical hydrogen evolution reaction(HER)is of great significance in both scie nee and tech no logy.In this work,N-doped CMK-3,which ...Developing non-precious metal catalysts with high activity and stability for electrochemical hydrogen evolution reaction(HER)is of great significance in both scie nee and tech no logy.In this work,N-doped CMK-3,which was prepared with a casting method using SBA-15 as thehard template and ammonia as the nitrogen source,has been utilized to hold MoS2 and restrict its growth to form MoS2@N-CMK-3 composite.As a result,M0S2 was found to have poorly crystallized and the limited space of porous N-CMK-3 made its size much small.Then there are moreactive sites in MoS2.Accordingly,MoS2@N-CMK-3 has exhibited good electrocatalytic performance toward HER in acids with a quite small Tafelslope of 32 mV·dec^-1.And more importantly,compared to MoS2@CMK-3,its stability has been greatly improved,which can be attributedto the interaction between M0S2 and nitrogen atoms avoiding aggregation and mass loss.This work provides an idea that doping a porouscarbon support with nitrogen is an effective way to enhance the stability of the catalyst.展开更多
基金This work was supported by the Nature Science Foundation of Zhejiang Province(No.LY20B010004)and the National Natural Science Foundation of China(Nos.21671152,51672193,51420105002, 21671014).
文摘Developing non-precious metal catalysts with high activity and stability for electrochemical hydrogen evolution reaction(HER)is of great significance in both scie nee and tech no logy.In this work,N-doped CMK-3,which was prepared with a casting method using SBA-15 as thehard template and ammonia as the nitrogen source,has been utilized to hold MoS2 and restrict its growth to form MoS2@N-CMK-3 composite.As a result,M0S2 was found to have poorly crystallized and the limited space of porous N-CMK-3 made its size much small.Then there are moreactive sites in MoS2.Accordingly,MoS2@N-CMK-3 has exhibited good electrocatalytic performance toward HER in acids with a quite small Tafelslope of 32 mV·dec^-1.And more importantly,compared to MoS2@CMK-3,its stability has been greatly improved,which can be attributedto the interaction between M0S2 and nitrogen atoms avoiding aggregation and mass loss.This work provides an idea that doping a porouscarbon support with nitrogen is an effective way to enhance the stability of the catalyst.
