FEA-Based Fatigue Life Assessment of Cycloidal Displacement Cam and Flat-Faced Follower Mechanism

Cam-followers provide reliable and controlled motions in various mechanical systems. Due to the highly fluctuating load between the cam and follower in operation, the cam-follower may be subjected to a high risk of contact fatigue failure. This paper assesses the fatigue life of a cycloidal displacement cam and a flat-faced follower under the defined loads and constraints. Computer-aided design (CAD) model of the cam-follower is developed in CATIA software and imported to ANSYS software for finite element analysis (FEA) of fatigue life. MATLAB programming is developed for determining the appropriate spring constant and pre-load force to always keep the cam and follower in contact. The fatigue life of the cam-follower has been estimated under the specified operating conditions. The analysis method can be applied to investigate the fatigue life of cams with other profiles, including the modified trapezoidal functions, polynomial functions, etc.

Chemical looping reforming of the micromolecular component from biomass pyrolysis via Fe_(2)O_(3)@SBA-16

To solve the problems of low gasification efficiency and high tar content caused by solid–solid contact between biomass and oxygen carrier in traditional biomass chemical looping gasification process.The decoupling strategy was adopted to decouple the biomass gasification process,and the composite oxygen carrier was prepared by embedding Fe_(2)O_(3) in molecular sieve SBA-16 for the chemical looping reforming process of pyrolysis micromolecular model compound methane,which was expected to realize the directional reforming of pyrolysis volatiles to prepare hydrogen-rich syngas.Thermodynamic analysis of the reaction system was carried out based on the Gibbs free energy minimization method,and the reforming performance was evaluated by a fixed bed reactor,and the kinetic parameters were solved based on the gas–solid reaction model.Thermodynamic analysis verified the feasibility of the reaction and provided theoretical guidance for experimental design.The experimental results showed that the reaction performance of Fe_(2)O_(3)@SBA-16 was compared with that of pure Fe_(2)O_(3) and Fe_(2)O_(3)@SBA-15,and the syngas yield was increased by 55.3%and 20.7%respectively,and it had good cycle stability.Kinetic analysis showed that the kinetic model changed from three-dimensional diffusion to first-order reaction with the increase of temperature.The activation energy was 192.79 kJ/mol by fitting.This paper provides basic data for the directional preparation of hydrogen-rich syngas from biomass and the design of oxygen carriers for pyrolysis of all-component chemical looping reforming.

A Comparative Study on the Truck Frame Stiffness with Solid and Beam Element FEA Models

Truck frames should be designed and fabricated with enough rigidity to avoid excessive deflections. Finite element analysis (FEA) plays an important role in all stages of frame designs. While being accurate, 3D solid element FEA models are built upon frame configuration details which are not feasible in the preliminary design stage, partially because of limited available design data of frames and heavy computation costs. This research develops 1D beam element FEA models for simulating frame structures. In this paper, the CAD model of a truck frame is first created. The solid element FEA analysis, which is adopted as the baseline in this study, is subsequently conducted for the stiffness of the frame, Next, beam element FEA analysis is performed for validating the feasibility of the beam element FEA model by comparing the results from the solid and beam element FEA models. It is found that the beam element FEA model can predict the frame stiffness with acceptable accuracy and reduce the computation cost significantly.

Parametric CAD Modelling of Aircraft Wings for FEA Vibration Analysis

Excessive vibration of aircraft wings during flight is harmful and may cause propagation of existing cracks in the material, leading to catastrophic failures as a result of material fatigue. This study investigates the variations of modal characteristics of aircraft wings with respect to changes in the structural configurations. We develop parametric Computer-Aided Design (CAD) models to capture new design intend on the aircraft wing architectures. Subsequent Finite Element Analysis (FEA) based vibration analysis is performed to study the effects of architecture changes on the wing’s natural frequencies and mode shapes. It is concluded that the spar placement and the number of ribs have significant influence on the wing’s natural vibration properties. Integrating CAD modelling and FEA vibration analysis enables designers to develop alternative wing architectures to implement design requirements in the preliminary design stage.

Nonlinear Finite Element Analysis and Optimum Design of Spot-Welded Joints and Weld-Bonded Joints

Resistance spot welding and hybrid weld bonding have wide applications in the body work construction within the automobile industry. The integrity of the spot welds and applied adhesives determines the body assembly rigidity and dynamic performance. Incorporating contact nonlinearity and geometric nonlinearity, finite element analysis (FEA) have been carried out to investigate the structural stiffness and strength of both spot-welded and weld-bonded assemblies. Topology optimization has been performed to reveal the distributions of material effectiveness in the overlap regions and suggest a feasible method for removing underutilized material for weight reduction. Design optimization has been conducted with an aim to reduce the maximum von Mises stress in the assembly to minimum by choosing optimum values for a set of design variables, including the weld spacing, weld diameter and overlap width.

Nonlinear Finite Element Analysis of Thin-Walled Beam on Pre- and Post-Buckling Stiffness and Gauge Sensitivity Index

Lightweight design has a significant impact on reducing fuel consumption and harmful emission of conventional vehicles and improving driving range of electric vehicles. Reducing the thickness of components in vehicle bodies and closures is an efficient approach for weight reduction. Thickness reduction, however, will reduce structural stiffness, especially in the presence of lateral displacements of buckling when critical stress is reached. In this paper, nonlinear FEA models of a thin-walled beam with variable thickness are developed for calculating the changes of beam stiffness as to thickness reduction in the pre- and post-buckling stages. Next, these stiffness values are used to calculate gauge sensitivity of the beam, which changes with respect to beam thickness changes. It is concluded that the presence of buckling will reduce the beam stiffness, worsen the stress uniformity, and increase the gauge sensitivity value of the beam.

Computing Method of Multivariate Process Capability Index Based on Normalized Pretreatment

For the traditional multi-process capability construction method based on principal component analysis,the process variables are mainly considered,but not the process capability,which leads to the deviation of the contribution rate of principal component.In response to the question,this paper first clarifies the problem from two aspects:theoretical analysis and example proof.Secondly,aiming at the rationality of principal components degree,an evaluation method for pre-processing data before constructing MPCI using PCA is proposed.The pre-processing of data is mainly to standardize the specification interval of quality characteristics making the principal components degree more reasonable and optimizes the process capability evaluation method.Finally,the effectiveness and feasibility of the method are proved by an application example.

Electrocatalytic Multicomponent Cascade Cross-Coupling for the Synthesis of Chalcogenosulfonates

An electrocatalytic multicomponent cascade cross-coupling for the synthesis of chalcogenosulfonates has been established.This approach does not require the use of transition metals,acids,and external oxidants.The gentle conditions and tolerance to a wide variety of functional groups permit the derivatization of complex indoles.

A NIR fluorescent probe for imaging thiophenol in the living system and revealing thiophenol-induced oxidative stress

Thiophenol(PhSH)is an important raw material for organic synthesis,while its high toxicity to organisms makes it an environmental pollutant.Therefore,it is crucial to accurately detect PhSH and explore its metabolic process in the living system.Herein,a near-infrared(NIR)fluorescent probe TEM-FB was developed for sensing PhSH with a turn-on fluorescent signal at 719nm and a large Stokes shift(198 nm)based on generating the intramolecular charge transfer(ICT)process.TEM-FB shows high specificity and significant sensitivity towards PhSH(detection limit:10 nmol/L)via the aromatic nucleophilic substitution mechanism.Furthermore,it was successfully applied to image PhSH in multiple cell lines and in zebrafish.Notably,we revealed the oxidative stress process caused by PhSH and demonstrated that the hydrogen peroxide(H_(2)O_(2))in cells would alleviate the poisonousness from exogenous PhSH for the first time.This work provides a promising bioimaging tool for monitoring PhSH in living systems and visualizing the process of oxidative stress induced by PhSH.

Structural modification of BODIPY: Improve its applicability

BODIPY has been considered a potential scaffold because of their neutral total charge, sharp absorption,and emission with high fluorescence quantum yield. However, the drawback of emission wavelength at less than 600 nm and hydrophobicity limit its application. One of the extremely interesting properties of BODIPY is that small modifications to their structures could be able to tune their properties, mainly including the absorption/emission wavelength and the hydrophilicity. This review focuses on the modification at different positions of BODIPY to improve the water-solubility and emission wavelength that describe their spectral, photophysical properties and applicability, which is helpful for the researchers to rationally design BODIPY dyes to adapt a wide range of applications.

Construction and regulation of imidazo[1,5-a]pyridines with AIE characteristics via iodine mediated Csp^(2)-H or Csp-H amination

The widespread applications of aggregation-induced emission luminogens(AIEgens)inspire the creation of AIEgens with novel structures and functionalities.In this work,we focused on the direct and efficient synthesis of a new type of AIEgens,imidazo[1,5-a]pyridicne derivatives,via iodine mediated cascade oxidative Csp^(2)–H or Csp–H amination route from phenylacetylene or styrenes under mild conditions.The resulted compounds showed excellent AIE characteristics with tunable maximum emissions,attractive bioimaging performance,and potential anti-inflammatory activity,which exert broad application prospects in material,biology,medicine,and other relevant areas.

Synthesis and application of highly sensitive fluorescent probe for Hg2＋ regulated by sulfur

Rhodamine-based fluorescent probe is widely used in chemical analysis, environmental analysis and life sciences area due to their excellent optical properties. Based on the thiophilic property of Hg2＋, using C = S structural motif as the core segment, our group have designed and synthesized three novel probes containing cinnamyl aldehyde with different substituents, exhibiting high selectivity and excellent sensitivity. The structure-property relationships of these probes have been investigated that the optical change caused by electron withdrawing effect and heavy atom effect. Furthermore, these Hg2＋ probes could be applied in living mice imaging, which provide a promising tool for quantitative mercury（Ⅱ） ion imaging in living organism.