Energy Transfer Dynamics between Carbon Quantum Dots and Molybdenum Disulfide Revealed by Transient Absorption Spectroscopy

Zero-dimensional environmentally friendly carbon quantum dots(CQDs)combined with two-di-mensional materials have a wide range of applications in optoelec-tronic devices.We combined steady-state and transient absorp-tion spectroscopies to study the energy transfer dynamics between CQDs and molybdenum disulfide(MoS_(2)).Transient absorption plots showed photoinduced absorption and stimulated emission features,which involved the intrinsic and defect states of CQDs.Adding MoS_(2)to CQDs solution,the lowest unoccupied molecular orbital of CQDs transferred energy to MoS_(2),which quenched the intrinsic emission at 390 nm.With addition of MoS_(2),CQD-MoS_(2)composites quenched defect emission at 490 nm and upward absorption,which originated from another energy transfer from the defect state.Two energy transfer paths between CQDs and MoS_(2)were efficiently manipulated by changing the concentration of MoS_(2),which laid a foundation for improving device performance.

Research on the "three shells" cooperative support technology of large-section chambers in deep mines

The"three shells"cooperative support technology was proposed herein according to both the large deformation of the rock surrounding large-section chambers in deep mines and the precarious stability of the support structures therein.The development range of the plastic zone in the surrounding rock was controlled by a stress shell to reduce the difficulty of controlling the surrounding rock.Additionally,the residual strength of the rock mass in the plastic zone and the self-bearing capacity of the surrounding rock were improved by a reinforced load-bearing shell.Furthermore,a passive load-bearing shell could restore the triaxial stress state of the surrounding rock on the free surface,reduce the influence of the external environment on the surrounding rock,and reinforce the surrounding rock with the strength of the shell.Reasonable layouts of large-section chambers were determined by analyzing the control effect of the stress shell on the surrounding rock under three kinds of in situ stress fields.The orthogonal test method was applied to reveal the influences of different support parameters in the reinforced loadbearing shell and passive load-bearing shell on the surrounding rock stability.The surrounding rock control effect of the"three shells"collaborative support technology was analyzed through numerical simulation and field monitoring.The results show that the maximum displacement between the roof and floor of the coal preparation chamber in the Xinjulong coal mine was approximately 48 mm,and the maximum displacement between its two sides was approximately 65 mm,indicating that the technology proposed herein could meet the long-term control requirements of the surrounding rock stability for large-section chambers in deep mines.

Numerical simulation of coal wall cutting and lump coal formation in a fully mechanized mining face

It is difficult to accurately calculate the lump coal rate in a fully mechanized mining face.Therefore,a numerical simulation of the coal wall cutting process,which revealed the crack expansion,development,evolution in the coal body and the corresponding lump coal formation mechanism,was performed in PFC2D.Moreover,a correlation was established between the cutting force and lump coal formation,and a statistical analysis method was proposed to determine the lump coal rate.The following conclusions are drawn from the results:(1)Based on a soft ball model,a coal wall cutting model is established.By setting the roller parameters based on linear bonding and simulating the roller cutting process of the coal body,the coal wall cutting process is effectively simulated,and accurate lump coal rate statistics are provided.(2)Under the cutting stress,the coal body in the working face underwent three stages—microfracture generation,fracture expansion,and fracture penetration—to form lump coal,in which the fracture direction is orthogonal to the cutting pressure chain.Within a certain range from the roller,as the cutting depth of the roller increased,the number of new fractures in the coal body first increases and then stabilizes.(3)Under the cutting stress,the fractured coal body is locally compressed,thereby forming a compact core.The formation and destruction of the compact core causes fluctuations in the cutting force.The fluctuation amplitude is positively related to the coal mass.(4)Because the simulation does not consider secondary damage in the coal,the simulated lump coal rate is larger than the actual lump coal rate in the working face;this deviation is mainly concentrated in large lump coal with a diameter greater than 300 mm.

Expression of Med 19 Protein in Tongue Cancer and Its Significance

[Objectives] To study the expression of Med 19 protein in tongue cancer and its significance. [Methods] Immunohistochemical method was used to detect the expression of Med 19 protein in tongue cancer tissue and paracancerous tissue. [Results]The expression of Med19 protein in tongue cancer tissue was higher than paracancerous tissue and normal tissue. The expression of Med 19 protein was related to the tumor lymph node metastasis. However,there was no significant difference in sex,age,Tumor Node Metastasis( TNM),and differentiation degree. [Conclusions] Med 19 protein participates in incidence and development of tongue cancer and may become diagnostic indicator and therapeutic target for tongue cancer.