Electrochemical synthesis of poly（2,6-pyridinediamine） （PPa） in aqueous sodium hydroxide solution has been carried out by using cyclic voltammetry for the first time. The scanning electron microscopy （SEM） revea...Electrochemical synthesis of poly（2,6-pyridinediamine） （PPa） in aqueous sodium hydroxide solution has been carried out by using cyclic voltammetry for the first time. The scanning electron microscopy （SEM） revealed the interpenetrating network structure of the as-prepared PPa film, which makes it possible that anions can be doped into the polymer in the oxidation process, and vice versa in the reduction process. The results from FT-IR spectrum provided a possible polymerization mechanism of 2,6- pyridinediamine.展开更多
基金supports of National Natural Science Foundation of China(No.21275023)Natural Science Foundation of Jiangsu Province(No.BK2012593)the Project Funded by the Priority Academic Program Development of Jiangsu Higher Education Institutions(PAPD)
文摘Electrochemical synthesis of poly（2,6-pyridinediamine） （PPa） in aqueous sodium hydroxide solution has been carried out by using cyclic voltammetry for the first time. The scanning electron microscopy （SEM） revealed the interpenetrating network structure of the as-prepared PPa film, which makes it possible that anions can be doped into the polymer in the oxidation process, and vice versa in the reduction process. The results from FT-IR spectrum provided a possible polymerization mechanism of 2,6- pyridinediamine.
