Optimization of deformation parameters of dynamic recrystallization for 7055 aluminum alloy by cellular automaton

In order to simulate the microstructure evolution during hot compressive deformation,models of dynamic recrystallization(DRX)by cellular automaton(CA)method for7055aluminum alloy were established.The hot compression tests were conducted toobtain material constants,and models of dislocation density,nucleation rate and recrystallized grain growth were fitted by leastsquare method.The effects of strain,strain rate,deformation temperature and initial grain size on microstructure variation werestudied.The results show that the DRX plays a vital role in grain refinement in hot deformation.Large strain,high temperature andsmall strain rate are beneficial to grain refinement.The stable size of recrystallized grain is not concerned with initial grain size,butdepends on strain rate and temperature.Kinetic characteristic of DRX process was analyzed.By comparison of simulated andexperimental flow stress–strain curves and metallographs,it is found that the established CA models can accurately predict themicrostructure evolution of7055aluminum alloy during hot compressive deformation.

Effect of prestressed ultrasonic peen forming parameters on bending curvature and spherical deformation of plate

The elastic prestressed ultrasonic peen forming(UPF)was adopted in order to solve problems of insufficient bending deformation and large spherical deformation of plate during free UPF.The theoretical analysis of prestressed UPF and the influence of elastic prebending moment on deformation were analyzed.Spherical deformation coefficient was defined to quantificationally describe the spherical deformation.Experiments were conducted to compare the differences between free UPF and prestressed UPF processes and the effects of processing parameters on bending curvature and spherical deformation coefficient were studied.The results show that peening trajectory in chordwise direction is beneficial to enlarging spanwise bending deformation and decreasing spherical deformation coefficient.Large prebending curvature is helpful to increase spanwise bending deformation and decrease chordwise deformation,thereby obviously decreasing spherical deformation coefficient.Large spanwise deformation can be obtained under large firing pin velocity,small plate thickness and small offset distance.Large firing pin velocity plays a positive role in decreasing spherical deformation,while plate thickness and offset distance have little effect on it.Above all,prebending curvature and peening trajectory are the most important factors during prestressed UPF process.This study provides guidance for parameters optimization of prestressed UPF for wing plate with large thickness.

A domino desulfitative coupling and decarboxylative coupling of 3,4-dihydropyrimidine-2-thiones with copper(Ⅰ)carboxylates

A novel and general carbon-nitrogen and carbon-carbon cross-coupling reaction between 3,4-dihydropyrimidine-2-thiones and copper（Ⅰ） carboxylates were performed in the presence of palladium acetate.The copper（Ⅰ） carboxylates act not only as desulfurative reagents but also as sources of carbon nudeophiles.A wide array of highly substituted and functionalized pyrimidines scaffolds were synthesized in good yields.