Anisotropic polyaniline （PAni） plates decorated with self-aligned nanofiber arrays were synthesized under the hydrothermaI conditions. The formation mechanism of the self-assembled structures was investigated by stu...Anisotropic polyaniline （PAni） plates decorated with self-aligned nanofiber arrays were synthesized under the hydrothermaI conditions. The formation mechanism of the self-assembled structures was investigated by studying the effect on PAni micro-structure with additive electrolyte in reaction system, and numerical simulation for dependence of systematic electrostatic energy on cross angles of self-assembled nanofiber arrays in grid textured PAni plates. It is proposed that the electrostatic interaction based on ionic doping charges plays an important role in the formation of the self-assembled PAni structures.展开更多
基金This work was supported by the National Natural Science Foundation of China （No.90606021, No.60676006, and No.60706019） and the State Key Program for Basic Research of China （No.2006CBOL1000）.
文摘Anisotropic polyaniline （PAni） plates decorated with self-aligned nanofiber arrays were synthesized under the hydrothermaI conditions. The formation mechanism of the self-assembled structures was investigated by studying the effect on PAni micro-structure with additive electrolyte in reaction system, and numerical simulation for dependence of systematic electrostatic energy on cross angles of self-assembled nanofiber arrays in grid textured PAni plates. It is proposed that the electrostatic interaction based on ionic doping charges plays an important role in the formation of the self-assembled PAni structures.
