A blockchain and IoT-based lightweight framework for enabling information transparency in supply chain finance

Supply Chain Finance(SCF)refers to the financial service in which banks rely on core enterprises to manage the capital flow and logistics of upstream and downstream enterprises.SCF adopts a self-testing and closed-loop credit model to control funds and risks.The key factor in a successful SCF service is the deployment of SCF businessoriented information systems that allow businesses to form partnerships efficiently and expedite cash flows throughout the supply chain.Blockchain Technology(BCT),featuring decentralization,tamper-proofing,traceability,which is usually paired with the Internet of Things(IoT)in real-world contexts,has been widely adopted in the field of finance and is perfectly positioned to facilitate innovative collaborations among participants in supply chain networks.In this paper,we propose a BCT and IoT-based information management framework(named BC4Regu),which works as the regulatory to improve the information transparency in the business process of SCF.With BC4Regu,the operation cost of the whole supply chain can be significantly reduced through the coordination and integration of capital flow,information flow,logistics and trade flow in the supply chain.The contributions in this paper include:(1)proposing a novel information management framework which leverages Blockchain and IoT to solve the problem of information asymmetry in the trade of SCF;(2)proposing the technical design of BC4Regu,including the Blockchain infrastructure,distributed ledger-based integrated data flow service,and reshaped SCF process;and(3)applying BC4Regu to a group of scenarios and conducting theoretical analysis by introducing the principal-agent model to validate the BC4Regu.

DFT计算结合固体NMR研究富铝SSZ-13的铝分布和Brønsted酸性

具有菱沸石(CHA)结构的SSZ-13分子筛在甲醇制烯烃(MTO)及柴油机车尾气氨选择性催化还原(NH3-SCR)反应中具有重要的应用,采用富铝SSZ-13可以调节MTO反应的烯烃选择性和提升NH3-SCR的低温脱硝活性,因此SSZ-13中的铝含量和分布与对应的酸性决定了其催化性能。本文采用密度泛函理论结合固体核磁共振实验研究了富铝和富硅HSSZ-13的Al位置与Brønsted酸强度的内在关系。通过计算取代能发现,对于孤立Al位,质子位于Al周围4个不同O位时能量差异较小,最稳定的B酸位点是O(1)-H。对于富铝SSZ-13,两个Al原子位于同一六元环的对位是Al-Si-Si-Al(NNNN)序列中最稳定的结构,而Al-Si-Al(NNN)序列中能量最优的Al分布是两个铝原子排布于六棱柱上下不同的六元环上。通过计算最稳定构型下的质子亲和势、NH3脱附能和吸附氘代乙腈后的1H NMR化学位移,发现富铝SSZ-13中含有Si(2Al)分布的NNN序列导致了其Brønsted酸强度弱于高硅的分子筛。分峰拟合29Si魔角旋转核磁共振(MAS NMR)谱图表明富铝SSZ-13中Si(2Al)的含量在43%以上,而吸附氘代乙腈后的1H MAS NMR实验显示富铝SSZ-13的桥羟基化学位移向低场移动,进一步证明富铝SSZ-13具有较弱的Brønsted酸强度。

Hierarchical distributed control for decentralized battery energy storage system based on consensus algorithm with pinning node

A decentralized battery energy storage system(DBESS)is used for stabilizing power fluctuation in DC microgrids.Different state of charge(SoC)among various battery energy storage units(BESU)during operation will reduce batteries’service life.A hierarchical distributed control method is proposed in this paper for SoC balancing and power control according to dispatching center requirement in DBESS.A consensus algorithm with pinning node is employed to allocate power among BESUs in the secondary control whereas in the primary control,the local controller of BESU adjusts output power according to the reference power from secondary control.Part of BESUs are selected to be pinning node for accepting command from dispatching center while other BESUs as following nodes which exchange output power and SoC information with the adjacent nodes through communication network.After calculating reference power of each BESU by adopting consensus algorithm,the power sharing in DBESS is achieved according to their respective SoC of BESUs.Meanwhile,the total output power of DBESS follows the varying requirements of dispatching center.The stability of DBESS is also improved because of having no center controller.The feasibility of the proposed control strategy is validated by simulation results.

Multi-decadal trends in the tropical Pacific western boundary currents retrieved from historical hydrological observations

As large-scale ocean circulation is a key regulator in the redistribution of oceanic energy, evaluating the multi-decadal trends in the western Pacific Ocean circulation under global warming is essential for not only understanding the basic physical processes but also predicting future climate change in the western Pacific. Employing the hydrological observations of World Ocean Atlas 2018(WOA18) from 1955 to 2017, this study calculated the geostrophic currents, volume transport and multidecadal trends for the North Equatorial Current(NEC), the North Equatorial Countercurrent(NECC), the Mindanao Current(MC), the Kuroshio Current(KC) in the origin and the New Guinea Coastal Undercurrent(NGCUC) within tropical western Pacific Ocean over multi-decades. Furthermore, this study examined the contributions of temperature and salinity variations. The results showed significant strengthening trends in NEC, MC and NGCUC over the past six decades, which is mainly contributed by temperature variations and consistent with the tendency in the dynamic height pattern. Zonal wind stress averaged over the western Pacific Ocean in the same latitude of each current represents the decadal variation and multi-decadal trends in corresponding ocean currents, indicating that the trade wind forcing plays an important role in the decadal trend in the tropical western Pacific circulation. Uncertainties in the observed hydrological data and trends in the currents over the tropical western Pacific are also discussed. Given that the WOA18 dataset covers most of the historical hydrological sampling data for the tropical western Pacific, this paper provides important observational information on the multi-decadal trend of the large-scale ocean circulation in the western Pacific.