Glufosinate-ammonium is a highly efficient, non-selective herbicide. The former synthesis schemes of glufosinate-ammonium were introduced and analyzed, the main of which are Arbuzov synthesis method, method under cata...Glufosinate-ammonium is a highly efficient, non-selective herbicide. The former synthesis schemes of glufosinate-ammonium were introduced and analyzed, the main of which are Arbuzov synthesis method, method under catalyzer and high pressure, targeted method under low temperature, Gabriel synthesis method, Zelinsky-Strecher synthetic method, synthetic method with chiral-synthon, and several special methods such as with enzyme or stereochemistry. Based on the structure and synthesis characteristic of glufosinate-ammonium as well as Arbuzov reaction and Michael reaction, a novel and reasonable scheme, which was named Arbuzov-Michael method, was put forward as the more economical one with simpler raw reagents and less waste.展开更多
文摘Glufosinate-ammonium is a highly efficient, non-selective herbicide. The former synthesis schemes of glufosinate-ammonium were introduced and analyzed, the main of which are Arbuzov synthesis method, method under catalyzer and high pressure, targeted method under low temperature, Gabriel synthesis method, Zelinsky-Strecher synthetic method, synthetic method with chiral-synthon, and several special methods such as with enzyme or stereochemistry. Based on the structure and synthesis characteristic of glufosinate-ammonium as well as Arbuzov reaction and Michael reaction, a novel and reasonable scheme, which was named Arbuzov-Michael method, was put forward as the more economical one with simpler raw reagents and less waste.
