含硒杂环的电化学合成、分析及表征综合实验设计

化学综合实验是学生开展创新实践训练的重要课程。笔者结合团队的科研成果,设计了一个电化学合成含硒杂环的综合实验。实验通过底物制备→电化学合成分析→结构表征→晶体培养解析等环节,对学生的合成操作、过程分析和结构解析等技能进行系统训练。实验中的电化学合成思路有助于提升学生的绿色化学意识,激发实验学习兴趣。

A Reevaluation of the Status of Lilium nepalense Based on Complete Chloroplast Genome Sequences

Lilium nepalense D. Don is an ornamental plant and exhibits high morphological variation across its distribution range in China. There is incongruence between different data sets for the status of it in Lilium. In this study, we reported a complete chloroplast genome of L. nepalense sampled in Hengduan Mountains, China. The whole chloroplast genome possessed a total length of 152,206 bp with typical circular structure, and contained a large single copy (LSC) of 81,854 bp and a small single copy (SSC) of 17,563 bp, which were separated by a pair of inverted repeats (IRa/IRb) of 26,399 bp. The average GC content among the whole chloroplast genome sequence was 37%, and the GC content in LSC, SSC, IRs regions were 34.8%, 30.6%, and 42.5%, respectively. There were 135 genes detected from the whole chloroplast genome sequence, including 89 protein-coding genes, 38 tRNAs, and 8 rRNAs. Phylogenetic results using maximum likelihood and Bayesian methods showed congruent results that L. nepalense together with the other two L. nepalense samples collected from different habitats formed a single branch, indicating a close relationship of L. nepalense with L. taliense belonging to the section Sinomartagon. This newly characterized chloroplast genome will provide essential data for the further population genetics research of L. nepalense.

Dynamic crushingof cellular materials: a particle velocity-based analytical method and its application

Cellular material under high-velocity impacthas a typical feature oflayer-wise collapse.A cell-based finite element model is employed to simulate the direct impact of closed-cell foam, and one-dimensional velocity field distributionsareobtained to characterize thecrushing bandpropagating through a cellular material. An explicit expression of continuous velocity distribution is derivedbased on the features of velocity gradient distribution. The velocity distribution function is adopted to determine the dynamic stress-strain statesof cellular materials under dynamic loading.The local stress-strain history distribution reveals that sectional cells experience a process from the precursor of elastic behavior to the shock stress state, through the dynamic initial crushing state. A power-law relation between the dynamic initial crushing stress andthe strainrate isestablished, which confirms the strain-rate effect of cellular materials. By extracting the critical points immediately before the unloading stage on the local dynamic stress-strain history curves, the dynamic stress-strain statesof cellular materials are determined. They exhibit loading rate-dependence but are independent of the initial impact velocity.Furthermore, with the increase of relative density, the dynamic hardening behaviorof cellular specimen is enhanced and the crushing process event is advanced. The particle velocity-based analytical method is appliedto analyze the dynamic responses of cellular materials.This method is better than continuum-based shock models, since itdoes not require a pre-assumed constitutive relation.Therefore,the particle velocity-based analytical method proposed in this study may provide new ideas to carry out dynamic experimental measurement, which is especially applicable toinhomogeneous materials.

Demonstration and Promotion of Integrated Management Technology of Wheat Sheath Blight and Wheat Crown Rot in Zibo City

Since 2014, Zibo Plant Protection Station has carried out a series of prevention and control tests in the city to solve the problem of increasingly aggravated root and stem diseases of wheat. According to the results of individual test, the technical procedures for integrated management of wheat sheath blight and wheat crown rot based on deep tillage, seed coating and chemical control in spring are integrated. The technique has been greatly promoted through on-site meetings, training and publicity, demonstration and promotion, unified prevention and control, and green prevention and control, which increases wheat yield in technology application area, reduces the use of chemical pesticides, and protects the ecological environment. The radiation drives increasing production and incomes of the surrounding farmers, receiving remarkable economic, social and ecological benefits.

On the stress–strain states of cellular materials under high loading rates

A virtual Taylor impact of cellular materials is analyzed with a wave propagation technique, i.e. the Lagrangian analysis method, of which the main advantage is that no pre-assumed constitutive relationship is required. Time histories of particle velocity, local strain, and stress profiles are calculated to present the local stress-strain history curves, from which the dynamic stress-strain states are obtained. The present results reveal that the dynamic-rigid-plastic hardening （D-R-PH） material model introduced in a previous study of our group is in good agreement with the dynamic stress-strain states under high loading rates obtained by the Lagrangian analysis method. It directly reflects the effectiveness and feasibility of the D-R-PH material model for the cellular materials under high loading rates.

多孔材料吸能行为对相对密度和冲击速度的依赖性

多孔材料是一种优异的吸能缓冲材料,但由于其变形模式的非单一性以及动态应力应变曲线的难获取性,其吸能行为对相对密度和冲击速度的依赖性关系还并不完全明朗.论文基于不需要提前作本构假定的波传播法,开展了多孔材料的吸能行为研究.采用多孔材料的细观有限元模型进行Taylor冲击虚拟实验,获取全场质点速度时程曲线,结合Lagrange分析法得到多孔材料的局部应力应变信息,进而探讨了动态吸能性能对材料相对密度和冲击速度的依赖性.研究结果表明多孔材料的吸能行为可依据变形模式分为三个阶段.在冲击模式下,多孔材料单位体积吸能与相对密度成线性增加关系,此时惯性起主导作用;在过渡模式下,惯性的主导作用减弱,单位体积吸能量的增加速率随相对密度的增加而减弱;在准静态模式下,多孔材料只能发生微小的变形,其吸能很少.论文进一步获得了区别于多孔材料准静态应力-应变曲线的动态应力-应变状态曲线,并考察了其与相对密度之间的关系.结果表明:随着相对密度的增加,多孔材料的动态压实应变将变小,而动态塑性平台应力将提高.

Development of a supercritical and an ultra-supercritical circulating fluidized bed boiler

The supercritical circulating fluidized bed(CFB)boiler,which combines the advantages of CFB combustion with low cost emission control and supercritical steam cycle with high efficiency of coal energy,is believed to be the future of CFB combustion technology.It is also of greatest importance for low rank coal utilization in China.Different from the supercritical pulverized coal boiler that has been developed more than 50 years,the supercritical CFB boiler is still a new one which requires further investigation.Without any precedentor engineering reference,Chinese researchers have con ducted fundamental research,development,design of the supercritical CFB boilers independently.The design theory and key technology for supercritical CFB boiler were proposed.Key components and novel structures were invented.The first 600 MWe supercritical CFB boiler and its auxiliaries were successfully developed and demonstrated in Baima Power Plant,Shenhua Group as well as the simulator,control technology,installation technology,commissioning technology,system integration and operation technology.Compared with the 460 MWe supercritical CFB in Poland,developed in the same period and the only other supercritical one of commercial running in the word beside Baima,the 600 MWe one in Baima has a better performance.Besides,supercritical CFB boilers of 350 MWe have been developed and widely commercialized in China.In this paper,the updated progress of 660 MWe ultra-supercritical CFB boilers under development is introduced.

Combined amendment reduces soil Cd availability and rice Cd accumulation in three consecutive rice planting seasons

The scientific application of stabilized materials has been considered an effective method for the in situ remediation of Cd-contaminated soil.This study aimed to investigate the persistence of the effect of a combined amendment of limestone and sepiolite(LS)on soil Cd availability and accumulation in rice grown in a mildly Cd-contaminated paddy field(0.45 mg/kg of Cd)over three consecutive rice seasons.1125–4500 kg/ha of LS was applied to the soil before the first rice planting season and 562.5–2250 kg/ha of LS was supplemented before the third rice planting season.The application of LS(1125–4500 kg/ha)increased the soil p H by 0.44–1.09,0.18–0.53,and 0.42–0.68 in the first,second,and third season,respectively,and decreased the soil acid-extractable Cd content by 18.2–36.4%,17.7–33.5%,and9.6–17.6%.LS application significantly decreased the Cd contents in the rice tissues.The application of 4500 kg/ha of LS decreased the Cd content in brown rice to below the National Food Limit Standard of 0.2 mg/kg(GB 2762-2017)in the three consecutive rice seasons.However,the effect of LS on the soil-rice system was significantly weakened in the third season.The supplementary application of 562.5–2250 kg/ha of LS further decreased the Cd content in brown rice by 26.1–56.5%and decreased the health risk index by 23.7–43.8%.Therefore,it was recommended to apply 4500 kg/ha of LS in the first season and to supplement2250 kg/ha of LS in the third season to effectively guarantee the clean production of rice in three consecutive rice seasons.

Effects of droplet size and spray volume parameters on droplet deposition of wheat herbicide application by using UAV

With the characteristic of flexible and precise,unmanned aerial vehicles(UAVs)for low volume applications are increasing substantially and quickly around the globe.However,little attention has been paid to the study of wheat herbicides with UAV,especially the research on the spray volume and droplet size of the herbicide sprayed by UAVs.The objectives of this study were to compare the droplet deposition from a typical commercial UAV under four different spray volumes of 7.5 L/hm2,15.0 L/hm2,22.5 L/hm2,and 30.0 L/hm2 and three different volume median diameter(VMD)of 150μm,200μm,and 300μm during winter wheat weeding period.DepositScan software was used to analyze droplet deposition parameters including the percentage of spray coverage and the number of droplets in various sampling positions.The test results showed that the droplet deposition waseffected by each factor andtheirinteractions.When the spray volume was 7.5 L/hm2,the effect of VMD on the percentage of spray coverage was not significant.However,these variation rules were changed to smaller droplets with greater coverage when the spray volume higher than 15.0 L/hm2.In all treatments,the number of droplets increased with decreasing VMD or increasing spray volume.The maximum percentage of spray coverage and the number of droplets that were achieved under the VMD of 150μm and the spray volume of 30.0 L/hm2 were 12.8%and 40.0 droplets/cm2,respectively.The variation coefficients of the percentage of spray coverage and the number of droplets were 29.0%-73.3%and 20.2%-54.1%,respectively.The most uniform deposition was achieved under the spray volume of 15.0 L/hm2and the VMD of 150μm.The results revealed the effect of droplet size and spray volume parameters on droplet deposition,which was useful for guiding farmers on how to use UAVs for weeding in winter wheat fields.

Stress-strain relationship of recycled self-compacting concrete filled steel tubular column subjected to eccentric compression

As a typical compression member,the concrete-filled steel tube has been widely used in civil engineering structures.However,little research on recycled self-compacting concrete flled circular steel tubular(RSCCFCST)columns subjected to eccentric load was reported.In this study,21 specimens were designed and experimental studies on the stress-strain relationship of were carried out to study the mechanical behaviors.Recycled coarse aggregate replacement ratio,concrete strength grade,length to diameter ratio and eccentric distance of specimens were considered as the main experimental parameters to carry out eccentric compression tests.The corresponding stress-strain relationship curves were used to analyze the influence of concerned parameters on ecentric load-bearing capacity of RSCCFCST columns.The experimental results show that the strain of the eccentric compression stress-strain curves increase with the increase of recycled coarse aggregate replacement ratio and concrete strength grade.With increase of eccentric distance,the ductility of specimens increases while the bearing capacity decreases.Moreover,a phenomenological model of RSCCFCST columns is proposed,which exhibits versatile ability to capture the process during loading.The present study is expected to further understanding the behaviors and to provide guidance of RSCCFCST columns in design and engineering applications.