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银纳米粒子修饰的二维金属-有机框架纳米片用于光热增强银离子释放抗菌 被引量:2
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作者 赵信硕 邱海燕 +7 位作者 邵依 王攀捷 余石龙 李海 周郁斌 周战 马录芳 谭超良 《物理化学学报》 SCIE CAS CSCD 北大核心 2023年第7期100-109,共10页
近年来,二维(2D)金属-有机框架(MOF)纳米复合材料被广泛的应用于生物医学领域,尤其是在抗菌方面。在此,我们通过光照诱导还银离子成功在二维MOF纳米片上生长银纳米粒子,得到了一种银纳米粒子(AgNPs)修饰的二维ZrFc-MOF(MOF-Ag)纳米片,... 近年来,二维(2D)金属-有机框架(MOF)纳米复合材料被广泛的应用于生物医学领域,尤其是在抗菌方面。在此,我们通过光照诱导还银离子成功在二维MOF纳米片上生长银纳米粒子,得到了一种银纳米粒子(AgNPs)修饰的二维ZrFc-MOF(MOF-Ag)纳米片,并将其用于光热增强Ag+释放抗菌治疗。通过水热法和超声处理合成MOF纳米片,然后通过原位光辐照诱导还原在MOF纳米片上生长AgNPs。系列表征结果表明AgNPs成功负载到MOF纳米片上。聚乙烯吡咯烷酮(PVP)的修饰不仅可以增强MOF-Ag在溶液中的稳定性,还可以增强它的生物相容性。在近红外激光(NIR)照射下,MOF纳米片可以在短时间升温,而温度的升高可以加速AgNPs在溶液中氧化为银离子。通过细菌生长曲线、菌落相对数和细菌形态变化等实验表明PVP@MOF-Ag纳米片具有优异的广谱杀菌性能。此外,2D MOF纳米片良好的光热性能不仅可以增强Ag+的释放,还可以增强细胞膜的通透性,随后进入细菌中的Ag+可以诱导内源性活性氧的产生,从而引发细菌的氧化应激,实现高效抗菌。基于良好的体外抗菌性能,进一步将PVP@MOF-Ag纳米片用于小鼠伤口愈合,在此期间PVP@MOF-Ag纳米片表现出良好的治疗效果和生物安全性。我们的研究结果表明,PVP@MOF-Ag纳米片可以作为光热增强Ag+释放抗菌治疗和伤口愈合的有效平台。 展开更多
关键词 二维金属-有机框架材料 二维复合材料 银离子释放 光热治疗 抗菌
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Quasi-three-dimensional high-lift wing design approach considering three-dimensional effects of slipstream for distributed electric propulsion aircraft
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作者 Tianshi CAO Junqiang BAI +3 位作者 Yasong QIU Kai HAN Shaodong FENG shilong yu 《Chinese Journal of Aeronautics》 SCIE EI CAS 2024年第11期300-316,共17页
The efficient utilization of propeller slipstream energy is important for improving the ultra-short takeoff and landing capability of Distributed Electric Propulsion(DEP)aircraft.This paper presents a quasi-three-dime... The efficient utilization of propeller slipstream energy is important for improving the ultra-short takeoff and landing capability of Distributed Electric Propulsion(DEP)aircraft.This paper presents a quasi-three-dimensional(2.5D)high-lift wing design approach considering the three-dimensional(3D)effects of slipstream for DEP aircraft,aiming at maximizing the comprehensive lift enhancement benefit of the airframe-propulsion coupling unit.A high-precision and efficient momentum source method is adopted to simulate the slipstream effects,and the distributed propellers are replaced by a rectangular actuator disk to reduce the difficulty of grid generation and improve the grid quality.A detailed comparison of the 2.5D and 3D configurations based on the X-57 ModⅣis performed in terms of flow characteristics and computational cost to demonstrate the rationality of the above design approach.The optimization results of the high-lift wing of the X-57 ModⅣshow that the aerodynamic performance of the landing configuration is significantly improved,for instance,the lift coefficient increases by 0.094 at the angle of attack of 7°,and 0.097 at the angle of attack of 14°.This novel approach achieves efficient and effective design of high-lift wings under the influence of distributed slipstream,which has the potential to improve the design level of DEP aircraft. 展开更多
关键词 High-lift wing design Quasi-three-dimensional optimization Three-dimensional effects of slipstream Distributed electric propulsion aircraft Ultra-short takeoff and landing
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