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磷酸根修饰的Mn掺杂介孔TiO_(2)在VUV-PCO体系高效催化氧化甲苯性能 被引量:3
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作者 舒亚婕 梁诗敏 +2 位作者 肖家勇 涂志凌 黄海保 《物理化学学报》 SCIE CAS CSCD 北大核心 2021年第8期119-129,共11页
真空紫外光解协同催化氧化(VUV-PCO)工艺作为常温下的一种高效目标物消除方式,具有真空紫外光解(VUV)、光催化(PCO)以及臭氧催化氧化(OZCO)三重功效。由于甲苯毒性强,存在广泛,本文选取甲苯作为雾霾重要前驱体的挥发性有机污染物(VOCs)... 真空紫外光解协同催化氧化(VUV-PCO)工艺作为常温下的一种高效目标物消除方式,具有真空紫外光解(VUV)、光催化(PCO)以及臭氧催化氧化(OZCO)三重功效。由于甲苯毒性强,存在广泛,本文选取甲苯作为雾霾重要前驱体的挥发性有机污染物(VOCs)的目标污染物,采用自制固定床连续流反应器(VUV光解和PCO工艺),通过浸渍法成功制备了介孔P-Mn-TiO_(2)催化剂,考察其在VUV-PCO体系降解甲苯性能。本文通过扫描电镜(SEM)、透射电镜(TEM)、紫外可见吸收光谱(UVVis)、X射线衍射光谱(XRD)等表征手段分析催化剂结构特征与活性的构效关系,探究Mn和磷酸改性对复合催化剂的光催化、臭氧催化活性以及吸附性能的影响机制。实验结果表明,磷酸修饰和Mn掺杂改性协同作用能有效提高催化剂臭氧催化活性及光催化性能,实现了臭氧的完全消除的同时,促进甲苯的高效降解。Mn^(3+)掺杂进Ti的晶格提高了TiO_(2)的吸光性能,同时可以在催化剂表面产生氧空位,增强催化剂对氧气、臭氧等的吸附和转化。适量磷酸修饰则能进一步提高催化剂对O_(2)、O_(3)等物种的吸附性能和表面光生电子-空穴分离效率,进一步增强催化剂光催化活性及臭氧催化活性。催化剂优异的性能归因于催化剂介孔结构对污染物的有效吸附、表面氧空位上催化分解O_(3)生成O(1D),O(3P),·OH及高效光催化反应产生的活性氧物种共同作用。甲苯首先被VUV光解打断,生成大量中间产物后,经光催化和臭氧催化氧化使最终生成的中间产物和剩余甲苯被系统中的活性氧物种进一步氧化降解为CO_(2)和H_(2)O。与此同时,出口臭氧彻底消除。 展开更多
关键词 磷酸 MN掺杂 VUV-PCO 甲苯 臭氧催化氧化
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Experimental study on the operating performance of the air source heat pump(ASHP)with variable outdoor airflow rate under the standard frosting condition
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作者 shimin liang Han Wang +4 位作者 Xuefeng Gao Xiaohui Tian Hui Zhu Songtao Hu Chunwen Lin 《Energy and Built Environment》 EI 2024年第5期719-726,共8页
Frosting is a common phenomenon of the ASHP under the heating mode in winter,and the outdoor air flow rate flowing through the evaporator of the ASHP was always thought to be a major contributor.In order to validate i... Frosting is a common phenomenon of the ASHP under the heating mode in winter,and the outdoor air flow rate flowing through the evaporator of the ASHP was always thought to be a major contributor.In order to validate its contribution,effects of outdoor fan airflow rate on the performance of air source heat pumps(ASHPs)were investigated under the winter heating condition.The experiment was conducted in a laboratory at the standard 2℃ air dry bulb temperature(DB)/1℃ air wet bulb temperature(WB)frosting condition,which enabled the analysis of the operating performance,frosting performance,and heating performance of the ASHP unit by changing the airflow rate of the outdoor fan.Results showed that as the airflow rate of the outdoor fan reduced from 100%to 36%,the operating performance decline and the elevated frosting-defrosting loss were observed.Meanwhile,both the frosting rate and the operating efficiency during frosting-defrosting cycles showed an increasing trend then followed by decreasing tendency.The maximum frosting rate and operating efficiency were 0.92 g/m^(2).min and 2.92,respectively,which were observed at 74%airflow rate of the outdoor fan of the ASHP unit.The observation implied the existence of the“minimum frosting suppression airflow rate”.At 36%airflow rate of the outdoor fan of the ASHP unit,however,the performance of the ASHP unit was attenuated greatly,with the frosting-defrosting efficiency loss coefficient of 0.47,the heating capacity and COP reduction by 51.5 and 38.8%,respectively.These findings provided significant references to the optimization of ASHPs performance with variable airflow rate of the outdoor fan under frosting conditions. 展开更多
关键词 ASHP Variable outdoor airflow rate FROSTING Heating performance
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