The synthesis, structure and characterization of a new one-dimensional cyanide-bridgedcomplex [Ni(pn)_2Ni(CN)4]n'nH2O (where pn = 1,2-diaminopropane) are described. The structure ofthis complex consists of a one-d...The synthesis, structure and characterization of a new one-dimensional cyanide-bridgedcomplex [Ni(pn)_2Ni(CN)4]n'nH2O (where pn = 1,2-diaminopropane) are described. The structure ofthis complex consists of a one-dimensional polymeric chain-Ni(pn)2-NC-Ni(CN)2-CN-Ni(pn)2- inwhich the Ni(II) centers are linked by two CN groups.展开更多
A deep red cfystalline binuclear cobalt-iron cyano-bridged complex [L3Co(Ⅲ)-Nc-Fe(Ⅱ)(CN)5]-(L=ethylencdiamine)was firstly prepared. Electron transfer between remote redox centers of iron(Ⅱ) and cobalt(Ⅲ) was inves...A deep red cfystalline binuclear cobalt-iron cyano-bridged complex [L3Co(Ⅲ)-Nc-Fe(Ⅱ)(CN)5]-(L=ethylencdiamine)was firstly prepared. Electron transfer between remote redox centers of iron(Ⅱ) and cobalt(Ⅲ) was investigated by means of IR,cyclic voltammogram and electronic spectra.展开更多
文摘The synthesis, structure and characterization of a new one-dimensional cyanide-bridgedcomplex [Ni(pn)_2Ni(CN)4]n'nH2O (where pn = 1,2-diaminopropane) are described. The structure ofthis complex consists of a one-dimensional polymeric chain-Ni(pn)2-NC-Ni(CN)2-CN-Ni(pn)2- inwhich the Ni(II) centers are linked by two CN groups.
文摘A deep red cfystalline binuclear cobalt-iron cyano-bridged complex [L3Co(Ⅲ)-Nc-Fe(Ⅱ)(CN)5]-(L=ethylencdiamine)was firstly prepared. Electron transfer between remote redox centers of iron(Ⅱ) and cobalt(Ⅲ) was investigated by means of IR,cyclic voltammogram and electronic spectra.
