Characteristics of permafrost degradation in Northeast China and its ecological effects: A review

Latitudinal permafrost in Northern Northeast(NNE)China is located in the southern margin of the Eurasian continent,and is very sensitive to climatic and environmental change.Numerical simulations indicate that air temperature in the permafrost regions of Northeast China has been on the rise since the 1950s,and will keep rising in the 21st century,leading to extensive degradation of permafrost.Permafrost degradation in NNE China has its own characteristics,such as northward shifts in the shape of a"W"for the permafrost southern boundary(SLP),discontinuous permafrost degradation into islandlike frozen soil,and gradually disappearing island permafrost.Permafrost degradation leads to deterioration of the ecological environment in cold regions.As a result,the belt of larch forests dominated by Larix gmelinii has shifted northwards and wetland areas with symbiotic relationships with permafrost have decreased significantly.With rapid retreat and thinning of permafrost and vegetation change,the CO2 and CH4 flux increases with mean air temperature from continuous to sporadic permafrost areas as a result of activity of methanogen enhancement,positively feeding back to climate warming.This paper reviews the features of permafrost degradation,the effects of permafrost degradation on wetland and forest ecosystem structure and function,and greenhouse gas emissions on latitudinal permafrost in NNE China.We also put forward critical questions about the aforementioned effects,including:(1)establish long-term permafrost observation systems to evaluate the distribution of permafrost and SLP change,in order to study the feedback of permafrost to climate change;(2)carry out research about the effects of permafrost degradation on the wetland ecosystem and the response of Xing'an larch to global change,and predict ecosystem dynamics in permafrost degradation based on long-term field observation;(3)focus intensively on the dynamics of greenhouse gas flux in permafrost degradation of Northeast China and the feedback of greenhouse gas emissions to climate change;(4)quantitative studies on the permafrost carbon feedback and vegetation carbon feedback due to permafrost change to climate multi-impact and estimate the balance of C in permafrost regions in the future.

Preparation and characterization of Pd/Fe bimetallic nanoparticles immobilized on Al_2O_3/PVDF membrane:Parameter optimization and dechlorination of dichloroacetic acid

Using a liquid-solid phase inversion method, a hybrid matrix poly（vinylidene fluoride）（PVDF） membrane was prepared with alumina（Al2O3） nanoparticle addition. Pd/Fe nanoparticles（NPs） were successfully immobilized on the Al2O3/PVDF membrane, which was characterized by Scanning Electron Microscopy（SEM） and Transmission Electron Microscopy（TEM）. The micrographs showed that the Pd/Fe NPs were dispersed homogeneously. Several important experimental parameters were optimized, including the mechanical properties, contact angle and surface area of Al2O3/PVDF composite membranes with different Al2O3 contents. At the same time, the ferrous ion concentration and the effect of hydrophilization were studied. The results showed that the modified Al2O3/PVDF membrane functioned well as a support. The Al2O3/PVDF membrane with immobilized Pd/Fe NPs exhibited high efficiency in terms of dichloroacetic acid（DCAA） dechlorination. Additionally, a reaction pathway for DCAA dechlorination by Pd/Fe NPs immobilized on the Al2O3/PVDF membrane system was proposed.