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二维相关红外光谱法表征2-O-甲基纤维素在离子液体Amim-Cl和Amim-(MeO)PHO_(2)中的溶解机理 被引量:2
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作者 胡慧洋 江佳浩 +5 位作者 肖亚飞 徐开俊 彭树华 巩沛鑫 王克 范敏敏 《高分子材料科学与工程》 EI CAS CSCD 北大核心 2021年第7期116-122,共7页
以微晶纤维素为原料合成了定向取代的2-O-甲基纤维素并制备了2种离子液体(Amim-Cl和Amim-(MeO)PHO_(2)),对2-O-甲基纤维素及其溶于离子液体Amim-Cl和Amim-(MeO)PHO_(2)的溶液进行了二维相关红外表征。通过分析2-O-甲基纤维素的氢键特征... 以微晶纤维素为原料合成了定向取代的2-O-甲基纤维素并制备了2种离子液体(Amim-Cl和Amim-(MeO)PHO_(2)),对2-O-甲基纤维素及其溶于离子液体Amim-Cl和Amim-(MeO)PHO_(2)的溶液进行了二维相关红外表征。通过分析2-O-甲基纤维素的氢键特征峰,揭示了不同羟基在其溶于离子液体过程中发挥的作用。研究结果表明,相较于纤维素,2-O-甲基纤维素中无2-OH…O-6氢键,仍存有分子内氢键3-OH…O-5和分子间氢键6-OH…O′-3。在2-O-甲基纤维素溶于离子液体的过程中,离子液体主要破坏的是分子间氢键6-OH…O′-3,而分子内氢键3-OH…O-5不受影响。离子液体的阴阳离子在溶解2-O-甲基纤维素的过程中均发挥了重要作用,与2-O-甲基纤维素6位羟基相互作用形成新的氢键是2-O-甲基纤维素溶于离子液体的主要动力。 展开更多
关键词 甲基纤维素 氢键 二维相关红外 离子液体
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Experimental investigation of shale breakdown pressure under liquid nitrogen pre-conditioning before nitrogen fracturing 被引量:3
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作者 Yu Wu Jing Tao +2 位作者 Jiehao Wang Yan Zhang shuhua peng 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2021年第4期611-620,共10页
Cryogenic fracturing with liquid nitrogen(LN_(2))offers the benefits of reducing the water consumption and adverse environmental impacts induced by water-based fracturing,as well as potentially enhancing the fracture ... Cryogenic fracturing with liquid nitrogen(LN_(2))offers the benefits of reducing the water consumption and adverse environmental impacts induced by water-based fracturing,as well as potentially enhancing the fracture complexity.We performed a series of laboratory experiments to explore the key mechanisms governing the breakdown pressures of shale during cryogenic fracturing.In this study,cylindrical shale samples were pre-conditioned by exposing a borehole to low-temperature LN_(2) for a certain time period,and then,the samples were fractured using gaseous N_(2) under triaxial stress and a high reservoir temperature.The effects of various key parameters on the breakdown pressure were investigated,including the duration of the low-temperature LN_(2) treatment,the confining pressure,the reservoir temperature,and the direction of the shale bedding relative to the borehole axis.The results demonstrate that the injection of low-temperature LN_(2) as a pre-fracturing fluid into a borehole can significantly reduce the breakdown pressure of the shale during subsequent nitrogen fracturing.This reduction in breakdown pressure can be further intensified by increasing the duration of the LN_(2) pre-conditioning.Without LN_(2) pre-conditioning,the breakdown pressure initially increases and then decreases with increasing reservoir temperature.When LN_(2) pre-conditioning is applied,the breakdown pressure keeps decreasing with increasing reservoir temperature.As the confining pressure increased,the breakdown pressure increased linearly in the tests with and without LN_(2) pre-conditioning.The experimental results demonstrate that LN_(2) preconditioning before N_(2) fracturing is a promising waterless fracturing technique that reduces the breakdown pressure and enhances the fracture complexity. 展开更多
关键词 Breakdown pressure Liquid nitrogen(LN_(2))pre-conditioning Nitrogen(N2)fracturing Thermal shock
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