An aluminum(Al)based nearly guided-wave surface plasmon resonance(NGWSPR)sensor is investigated in the far-ultraviolet(FUV)region.By simultaneously optimizing the thickness of Al and dielectric films,the sensitivity o...An aluminum(Al)based nearly guided-wave surface plasmon resonance(NGWSPR)sensor is investigated in the far-ultraviolet(FUV)region.By simultaneously optimizing the thickness of Al and dielectric films,the sensitivity of the optimized Al-based FUV-NGWSPR sensor increases from 183/RIU to 309/RIU,and its figure of merit rises from 26.47 RIU^(-1)to 32.59 RIU^(-1)when the refractive index of dielectric increases from 2 to 5.Compared with a traditional FUV-SPR sensor without dielectric,the optimized FUV-NGWSPR sensor can realize simultaneous improvement of sensitivity and figure of merit.In addition,the FUV-NGWSPR sensor with realistic materials(diamond,Ta_(2)O_(5),and GaN)is also investigated,and 137.84%,52.70%,and 41.89%sensitivity improvements are achieved respectively.This work proposes a method for performance improvement of FUV-SPR sensors by exciting nearly guided-wave,and could be helpful for the high-performance SPR sensor in the short-wavelength region.展开更多
Zinc ion hybrid supercapacitors(ZHS)have received much attention due to the enhanced potential window range and high specific capacity.However,the appropriate positive materials with high electrochemical performance a...Zinc ion hybrid supercapacitors(ZHS)have received much attention due to the enhanced potential window range and high specific capacity.However,the appropriate positive materials with high electrochemical performance are still a challenge.Herein,NH_(4)^(+)and glycerate anions pre-inserted Mo glycerate(N-MoG)spheres are synthesized and serve as the template to form NH_(4)^(+)intercalated Ni_(3)S_(2)/Ni_(3)O_(2)(OH)_(4)@MoS_(2)core–shell nanoflower(N-NiMo-OS)in-situ grown on nickel foam(NF)(N-NiMo-OS/NF)by sulfurization treatment.Compared with the product using traditional MoG as a template,N-NiMo-OS/NF inheriting a larger core structure from N-MoG delivers enhanced space for ions transport and volume expansion during the energy storage process,together with the synergistic effects of multi-components and the heterostructure,the as-prepared N-NiMo-OS/NF nanoflower exhibits excellent performance for the battery-type hybrid supercapacitors(BHS)and ZHS devices.Notably,the ZHS device delivers superior electrochemical performance to the BHS device,such as a higher specific capacity of 327.5 mAh·g^(−1)at 1 A·g^(−1),a preeminent energy density of 610.6 Wh·kg^(−1)at 1710 W·kg^(−1),long cycle life.The in-situ Raman,ex-situ X-ray photoelectron spectroscopy(XPS),theoretical calculation demonstrate the extra Zn^(2+)insertion/extraction storage mechanism provides enhanced electrochemical performance for ZHS device.Therefore,the dual-ion pre-inserted strategy can be extended for other advanced electrode materials in energy storage fields.展开更多
基金Project supported by the National Natural Science Foundation of China(Grant Nos.61805007 and 11547241)
文摘An aluminum(Al)based nearly guided-wave surface plasmon resonance(NGWSPR)sensor is investigated in the far-ultraviolet(FUV)region.By simultaneously optimizing the thickness of Al and dielectric films,the sensitivity of the optimized Al-based FUV-NGWSPR sensor increases from 183/RIU to 309/RIU,and its figure of merit rises from 26.47 RIU^(-1)to 32.59 RIU^(-1)when the refractive index of dielectric increases from 2 to 5.Compared with a traditional FUV-SPR sensor without dielectric,the optimized FUV-NGWSPR sensor can realize simultaneous improvement of sensitivity and figure of merit.In addition,the FUV-NGWSPR sensor with realistic materials(diamond,Ta_(2)O_(5),and GaN)is also investigated,and 137.84%,52.70%,and 41.89%sensitivity improvements are achieved respectively.This work proposes a method for performance improvement of FUV-SPR sensors by exciting nearly guided-wave,and could be helpful for the high-performance SPR sensor in the short-wavelength region.
基金the National Natural Science Foundation of China(Nos.21702116,51772162,and 52072197)the 111 Project of China(No.D20017)+5 种基金Shandong Provincial Key Research and Development Program,China(No.2019GSF107087)Qingdao Postdoctoral Sustentation Fund,Youth Innovation and Technology Foundation of Shandong Higher Education Institutions,China(No.2019KJC004)Outstanding Youth Foundation of Shandong Province,China(No.ZR2019JQ14)Taishan Scholar Young Talent Program(No.tsqn201909114)Major Scientific and Technological Innovation Project(No.2019JZZY020405)Major Basic Research Program of Natural Science Foundation of Shandong Province(No.ZR2020ZD09).
文摘Zinc ion hybrid supercapacitors(ZHS)have received much attention due to the enhanced potential window range and high specific capacity.However,the appropriate positive materials with high electrochemical performance are still a challenge.Herein,NH_(4)^(+)and glycerate anions pre-inserted Mo glycerate(N-MoG)spheres are synthesized and serve as the template to form NH_(4)^(+)intercalated Ni_(3)S_(2)/Ni_(3)O_(2)(OH)_(4)@MoS_(2)core–shell nanoflower(N-NiMo-OS)in-situ grown on nickel foam(NF)(N-NiMo-OS/NF)by sulfurization treatment.Compared with the product using traditional MoG as a template,N-NiMo-OS/NF inheriting a larger core structure from N-MoG delivers enhanced space for ions transport and volume expansion during the energy storage process,together with the synergistic effects of multi-components and the heterostructure,the as-prepared N-NiMo-OS/NF nanoflower exhibits excellent performance for the battery-type hybrid supercapacitors(BHS)and ZHS devices.Notably,the ZHS device delivers superior electrochemical performance to the BHS device,such as a higher specific capacity of 327.5 mAh·g^(−1)at 1 A·g^(−1),a preeminent energy density of 610.6 Wh·kg^(−1)at 1710 W·kg^(−1),long cycle life.The in-situ Raman,ex-situ X-ray photoelectron spectroscopy(XPS),theoretical calculation demonstrate the extra Zn^(2+)insertion/extraction storage mechanism provides enhanced electrochemical performance for ZHS device.Therefore,the dual-ion pre-inserted strategy can be extended for other advanced electrode materials in energy storage fields.