Organic azides have shown versatile reactivity to induce various organic transformations for the synthesis of nitrogencontaining organic molecules such as 1,3-dipolar cycloadditions with unsaturated bonds,the Curtius ...Organic azides have shown versatile reactivity to induce various organic transformations for the synthesis of nitrogencontaining organic molecules such as 1,3-dipolar cycloadditions with unsaturated bonds,the Curtius rearrangement,and formation of nitrogen-centered radicals,most of which are driven by the entropic loss of molecular dinitrogen[1].展开更多
文摘Organic azides have shown versatile reactivity to induce various organic transformations for the synthesis of nitrogencontaining organic molecules such as 1,3-dipolar cycloadditions with unsaturated bonds,the Curtius rearrangement,and formation of nitrogen-centered radicals,most of which are driven by the entropic loss of molecular dinitrogen[1].
