Developing high-capacity and low-cost cathode materials for metal-ion rechargeable batteries is the mainstream trend and is also the key to providing breakthroughs in making high-energy rechargeable batteries.Vanadium...Developing high-capacity and low-cost cathode materials for metal-ion rechargeable batteries is the mainstream trend and is also the key to providing breakthroughs in making high-energy rechargeable batteries.Vanadium has a variety of valence states and can form a variety of vanadate structures.As a typical positive electrode material,vanadate has abundant ion adsorption sites,a unique“pillar”framework,and a typical layered structure.Therefore,it has the advantages of high specific capacity and excellent rate performance,possessing the prospect of being a large-capacity energy storage material.In this review,we focus on applications of sodium vanadium oxides(NVO)in electrical energy storage(EES)devices and summarize sodium vanadate materials from three aspects,including crystal structure,electrochemical performance,and energy storage mechanism.The recent progress of NVO-based highperformance energy storage materials along with nanostructured design strategies was provided and discussed as well.This review is intended to serve as general guidance for researchers to develop desirable sodium vanadate materials.展开更多
基金the National Natural Science Foundation of China(Nos.51902296,22004112)the National Key R&D Program of China(No.2017YFA0208000)the Zhejiang Provincial Natural Science Foundation of China(No.LD21B050001)。
文摘Developing high-capacity and low-cost cathode materials for metal-ion rechargeable batteries is the mainstream trend and is also the key to providing breakthroughs in making high-energy rechargeable batteries.Vanadium has a variety of valence states and can form a variety of vanadate structures.As a typical positive electrode material,vanadate has abundant ion adsorption sites,a unique“pillar”framework,and a typical layered structure.Therefore,it has the advantages of high specific capacity and excellent rate performance,possessing the prospect of being a large-capacity energy storage material.In this review,we focus on applications of sodium vanadium oxides(NVO)in electrical energy storage(EES)devices and summarize sodium vanadate materials from three aspects,including crystal structure,electrochemical performance,and energy storage mechanism.The recent progress of NVO-based highperformance energy storage materials along with nanostructured design strategies was provided and discussed as well.This review is intended to serve as general guidance for researchers to develop desirable sodium vanadate materials.
