Spatial separation of oxidation/reduction cocatalyst is an effective means to improve the efficiency of charge separation in photocatalytic reaction systems.Herein,a yolk-shell Pd@NH_(2)-UiO-66@Cu_(2)O heterojunction ...Spatial separation of oxidation/reduction cocatalyst is an effective means to improve the efficiency of charge separation in photocatalytic reaction systems.Herein,a yolk-shell Pd@NH_(2)-UiO-66@Cu_(2)O heterojunction was designed and synthesized by integration of electron collector Pd and hole collector Cu_(2)O inside and outside of a photoactive metal-organic framework(MOF)NH_(2)-UiO-66,respectively.The obtained Pd@NH_(2)-UiO-66@Cu_(2)O heterojunction effectively inhibits the electron and hole recombination through the photo-induced electrons and holes flow inward and outward of the composite,and promotes the reduction and oxidation abilities for the oxidative coupling of benzylamine to imines.Compared with Pd/NH_(2)-UiO-66@Cu_(2)O,Pd@NH_(2)-UiO-66,and Pd/NH_(2)-UiO-66,Pd@NH_(2)-UiO-66@Cu_(2)O exhibits the highest photocatalytic activity.More importantly,Pd@NH_(2)-UiO-66@Cu_(2)O shows a conversion rate of benzylamine up to 99%either by oxidation under aerobic conditions or by strong adsorption of H atom(Hads)under anaerobic conditions.In addition,the catalyst shows good stability and can be recycled at least ten times.This work provides useful guidance on construction of MOFs-based composites with spatially separated photoinduced charge carriers to realize efficient oxidation coupling of benzylamine in both aerobic and anaerobic conditions.展开更多
We determined the effects of quartz sand(QS),water treatment plant sludge(WTPS),aluminum-based P-inactivation agent(Al-PIA),and lanthanum-modified bentonite(LMB)thin-layer capping on controlling phosphorus and nitroge...We determined the effects of quartz sand(QS),water treatment plant sludge(WTPS),aluminum-based P-inactivation agent(Al-PIA),and lanthanum-modified bentonite(LMB)thin-layer capping on controlling phosphorus and nitrogen release from the sediment,using a static simulation experiment.The sediment in the experiment was sampled from Yundang Lagoon(Xiamen,Fujian Province,China),which is a eutrophic waterbody.The total phosphorus(TP),ammonium nitrogen(NH4+-N),and total organic carbon(TOC)levels in the overlying water were measured at regular intervals,and the changes of different P forms in WTPS,Al-PIA,and sediment of each system were analyzed before and after the test.The average TP reduction rates of LMB,Al-PIA,WTPS,and QS were 94.82,92.14,86.88,and 10.68%,respectively,when the release strength of sediment TP was 2.26–9.19 mg/(m^(2)·d)and the capping strength of the materials was 2 kg/m^(2).Thin-layer capping of LMB,WTPS,and Al-PIA could effectively control P release from the sediment(P<0.05).However,thin-layer capping of LMB,Al-PIA,and QS did not significantly reduce the release of ammonium N and organic matter(P>0.05).Based on our results,LMB,Al-PIA,and WTPS thin-layer capping promoted the migration and transformation of easily released P in sediment.The P adsorbed by WTPS and Al-PIA mainly occurred in the form of NAIP.展开更多
In this study, biologically inspired silk fibroin grafted polyacrylonitrile(SF-g-PAN) filtration membrane was prepared using ZnCl_2 aqueous solution as solvent, avoiding the use of organic solvents. Phase inversion oc...In this study, biologically inspired silk fibroin grafted polyacrylonitrile(SF-g-PAN) filtration membrane was prepared using ZnCl_2 aqueous solution as solvent, avoiding the use of organic solvents. Phase inversion occurred when Zn^(2+)and Cl-ions gradually diffused into water, creating a well-connected ion channel network and the SF-g-PAN filtration membrane was obtained. The membranes were observed by SEM and 3D ultra-depth microscope. The hydrophilic property, pore size distribution and dye rejection of the membrane were investigated. Results showed that the membrane has no finger hole formation because ZnCl_2 aqueous solution has a lower curing rate parameter compared with organic solvents. SF-gPAN membrane possessed good anti-fouling properties and pH sensitivity. The pore size distribution of the SF-g-PAN membrane was 0.25–1.04 nm. The rejection of direct yellow 27(Mw = 662.6) and amaranth(Mw = 604.5) was 96.51% and 30.63%, with the flux of 72.32 L m^(-2) h^(-1) and 73.83 L m^(-2) h^(-1) respectively at0.1 MPa. The SF-g-PAN membrane has a wide range of applications prospect in fine separation, dye desalination, waste water treatment and biomedical fields.展开更多
Objective:The purpose of the current study was to discuss the interrelation among alexithy-mia and negative psychology of nursing personnel and their coping style,so as to provide a theoret-ical basis for better menta...Objective:The purpose of the current study was to discuss the interrelation among alexithy-mia and negative psychology of nursing personnel and their coping style,so as to provide a theoret-ical basis for better mental health education and psychological intervention for nursing personnel.Methods:A questionnaire survey was administered to 503 nursing personnel sampled from a hospital in Henan Province between May and June 2010 by means of survey instruments of the Toronto Alexithymia Scale-20 Items(TAS-20),the Trait Coping Style Questionnaire(TCSQ),and the General Health Questionnaire(GHQ-20).Results:(1)Alexithymia and a negative coping style had a positive correlation with negative psychology(P<0.01),while a positive coping style had a negative correlation with negative psy-chology(P<0.01).(2)The model fitting indices of coping style as intermediate variables between alexithymia and negative psychology were χ^(2)/df=1.459,RMSEA=0.030,CFI=0.995,IFI=0.995,RFI=0.966,TCI=0.989,and NEI=0.985,indicating a good model fitting.Ninety-nine percent of the total variation of negative psychology could be explained by alexithymia and coping style,of which the indirect effect affecting negative psychology by coping style accounted for 94.59%of the total.Conclusion:Alexithymia and coping style were very important factors for improvement of current mental status of the nursing personnel,especially for a change in negative coping style and selection of good coping style.展开更多
基金The authors were supported by the National Key Research and Development Program on the Monitoring,Early Warning and Prevention of Major Natural Disasters[grant number 2018YFC1507104]the Flexible Talents Introducing Project of Xinjiang(2019).
基金This work was supported by the National Key R&D Program on the Monitoring,Early Warning and Prevention of Major Natural Disasters[grant number 2017YFC1502103]the Key Special Project for the Introducing Talents Team of the Southern Marine Science and Engineering Guangdong Laboratory(Guangzhou)[grant number GML2019ZD0601]the National Natural Science Foundation of China[grant numbers 41875136,41305099,and 41801019].
基金supported by the National Natural Science Foundation of China(Nos.21771163 and 22171247)Zhongyuan thousand talents project.
文摘Spatial separation of oxidation/reduction cocatalyst is an effective means to improve the efficiency of charge separation in photocatalytic reaction systems.Herein,a yolk-shell Pd@NH_(2)-UiO-66@Cu_(2)O heterojunction was designed and synthesized by integration of electron collector Pd and hole collector Cu_(2)O inside and outside of a photoactive metal-organic framework(MOF)NH_(2)-UiO-66,respectively.The obtained Pd@NH_(2)-UiO-66@Cu_(2)O heterojunction effectively inhibits the electron and hole recombination through the photo-induced electrons and holes flow inward and outward of the composite,and promotes the reduction and oxidation abilities for the oxidative coupling of benzylamine to imines.Compared with Pd/NH_(2)-UiO-66@Cu_(2)O,Pd@NH_(2)-UiO-66,and Pd/NH_(2)-UiO-66,Pd@NH_(2)-UiO-66@Cu_(2)O exhibits the highest photocatalytic activity.More importantly,Pd@NH_(2)-UiO-66@Cu_(2)O shows a conversion rate of benzylamine up to 99%either by oxidation under aerobic conditions or by strong adsorption of H atom(Hads)under anaerobic conditions.In addition,the catalyst shows good stability and can be recycled at least ten times.This work provides useful guidance on construction of MOFs-based composites with spatially separated photoinduced charge carriers to realize efficient oxidation coupling of benzylamine in both aerobic and anaerobic conditions.
基金supported by the National Natural Science Fund of China(Grant No.51878300)the Natural Science Foundation of Fujian Province of China(Grant No.2019J01052)Project of production,study and research of colleges and universities of Xiamen City(Grant No.3502Z20203044).
文摘We determined the effects of quartz sand(QS),water treatment plant sludge(WTPS),aluminum-based P-inactivation agent(Al-PIA),and lanthanum-modified bentonite(LMB)thin-layer capping on controlling phosphorus and nitrogen release from the sediment,using a static simulation experiment.The sediment in the experiment was sampled from Yundang Lagoon(Xiamen,Fujian Province,China),which is a eutrophic waterbody.The total phosphorus(TP),ammonium nitrogen(NH4+-N),and total organic carbon(TOC)levels in the overlying water were measured at regular intervals,and the changes of different P forms in WTPS,Al-PIA,and sediment of each system were analyzed before and after the test.The average TP reduction rates of LMB,Al-PIA,WTPS,and QS were 94.82,92.14,86.88,and 10.68%,respectively,when the release strength of sediment TP was 2.26–9.19 mg/(m^(2)·d)and the capping strength of the materials was 2 kg/m^(2).Thin-layer capping of LMB,WTPS,and Al-PIA could effectively control P release from the sediment(P<0.05).However,thin-layer capping of LMB,Al-PIA,and QS did not significantly reduce the release of ammonium N and organic matter(P>0.05).Based on our results,LMB,Al-PIA,and WTPS thin-layer capping promoted the migration and transformation of easily released P in sediment.The P adsorbed by WTPS and Al-PIA mainly occurred in the form of NAIP.
基金supported by the National Natural Science Foundation of China (Nos. 51678409, 145 708407, 21476172)Tianjin Science Technology Research Funds of China (Nos. 16JCZDJC37500, 15JCZDJC38300)+1 种基金Program for Innovative Research Team in University of Tianjin (No. TD13-5042)Science Foundation for the Youth Teachers of Peking Union Medical College (No. 2014ZLGC0754)
文摘In this study, biologically inspired silk fibroin grafted polyacrylonitrile(SF-g-PAN) filtration membrane was prepared using ZnCl_2 aqueous solution as solvent, avoiding the use of organic solvents. Phase inversion occurred when Zn^(2+)and Cl-ions gradually diffused into water, creating a well-connected ion channel network and the SF-g-PAN filtration membrane was obtained. The membranes were observed by SEM and 3D ultra-depth microscope. The hydrophilic property, pore size distribution and dye rejection of the membrane were investigated. Results showed that the membrane has no finger hole formation because ZnCl_2 aqueous solution has a lower curing rate parameter compared with organic solvents. SF-gPAN membrane possessed good anti-fouling properties and pH sensitivity. The pore size distribution of the SF-g-PAN membrane was 0.25–1.04 nm. The rejection of direct yellow 27(Mw = 662.6) and amaranth(Mw = 604.5) was 96.51% and 30.63%, with the flux of 72.32 L m^(-2) h^(-1) and 73.83 L m^(-2) h^(-1) respectively at0.1 MPa. The SF-g-PAN membrane has a wide range of applications prospect in fine separation, dye desalination, waste water treatment and biomedical fields.
基金Natural Science Fund Project of the Education Department of Henan Province[Relationship model between alexithymia and psychosomatic health of medical workers(2011A320010)].
文摘Objective:The purpose of the current study was to discuss the interrelation among alexithy-mia and negative psychology of nursing personnel and their coping style,so as to provide a theoret-ical basis for better mental health education and psychological intervention for nursing personnel.Methods:A questionnaire survey was administered to 503 nursing personnel sampled from a hospital in Henan Province between May and June 2010 by means of survey instruments of the Toronto Alexithymia Scale-20 Items(TAS-20),the Trait Coping Style Questionnaire(TCSQ),and the General Health Questionnaire(GHQ-20).Results:(1)Alexithymia and a negative coping style had a positive correlation with negative psychology(P<0.01),while a positive coping style had a negative correlation with negative psy-chology(P<0.01).(2)The model fitting indices of coping style as intermediate variables between alexithymia and negative psychology were χ^(2)/df=1.459,RMSEA=0.030,CFI=0.995,IFI=0.995,RFI=0.966,TCI=0.989,and NEI=0.985,indicating a good model fitting.Ninety-nine percent of the total variation of negative psychology could be explained by alexithymia and coping style,of which the indirect effect affecting negative psychology by coping style accounted for 94.59%of the total.Conclusion:Alexithymia and coping style were very important factors for improvement of current mental status of the nursing personnel,especially for a change in negative coping style and selection of good coping style.
