The gas-liquid-liquid reactive extraction system for preparing hydrogen peroxide via anthraquinone was investigated. The oxidation reaction of hydrogenated working solution was combined with the extraction of hydrogen...The gas-liquid-liquid reactive extraction system for preparing hydrogen peroxide via anthraquinone was investigated. The oxidation reaction of hydrogenated working solution was combined with the extraction of hydrogen peroxide from working solution in a sieve plate column. The reaction of 2-ethylanthrahydroquionone with oxygen and the liquid-liquid extraction of hydrogen peroxide take place simultaneously. The oxygen was introduced with hydrogenated working solution through a nozzle in the bottom of the column, which worked as agitated air as well as oxidation reagent. The results showed the oxidation and extraction do not hamper each other, on the contrary, the presence of oxidation gas in the column can promote the transfer of hydrogen peroxide from organic phase to aqueous phase, thus the reaction efficiency and extraction efficiency increased with increasing gas superficial velocity. Furthermore, the oxidation efficiency is almost 100% and the extraction efficiency is higher than 90% in this process.展开更多
The preparation of hydrogen peroxide from anthrahydroquinone by reactive extraction was investigated.The integration process of oxidation of anthrahydroquinone by air and extraction of hydrogen peroxide from the organ...The preparation of hydrogen peroxide from anthrahydroquinone by reactive extraction was investigated.The integration process of oxidation of anthrahydroquinone by air and extraction of hydrogen peroxide from the organic phase with water was carried out in a sieve plate column under pressure.The conversion of anthrahydroquinone increased with increasing pressure resulting in an increase of hydrogen peroxide concentration in the aqueous phase.However,no change in extraction efficiency of hydrogen peroxide was observed.A mathematical model for gas-liquid-liquid reactive extraction was established.In themodel,the effects of pressure and gas superficial velocity on reaction were considered.With increasing gas superficial velocity,the conversion of anthrahydroquinone increased,and the fraction of hydrogen peroxide extracted reached a plateau with a maximum of 72.94%.However,both the conversion of anthrahydroquinone and the fraction of hydrogen peroxide extracted decreased with increasing organic phase superficial velocity.展开更多
文摘The gas-liquid-liquid reactive extraction system for preparing hydrogen peroxide via anthraquinone was investigated. The oxidation reaction of hydrogenated working solution was combined with the extraction of hydrogen peroxide from working solution in a sieve plate column. The reaction of 2-ethylanthrahydroquionone with oxygen and the liquid-liquid extraction of hydrogen peroxide take place simultaneously. The oxygen was introduced with hydrogenated working solution through a nozzle in the bottom of the column, which worked as agitated air as well as oxidation reagent. The results showed the oxidation and extraction do not hamper each other, on the contrary, the presence of oxidation gas in the column can promote the transfer of hydrogen peroxide from organic phase to aqueous phase, thus the reaction efficiency and extraction efficiency increased with increasing gas superficial velocity. Furthermore, the oxidation efficiency is almost 100% and the extraction efficiency is higher than 90% in this process.
文摘The preparation of hydrogen peroxide from anthrahydroquinone by reactive extraction was investigated.The integration process of oxidation of anthrahydroquinone by air and extraction of hydrogen peroxide from the organic phase with water was carried out in a sieve plate column under pressure.The conversion of anthrahydroquinone increased with increasing pressure resulting in an increase of hydrogen peroxide concentration in the aqueous phase.However,no change in extraction efficiency of hydrogen peroxide was observed.A mathematical model for gas-liquid-liquid reactive extraction was established.In themodel,the effects of pressure and gas superficial velocity on reaction were considered.With increasing gas superficial velocity,the conversion of anthrahydroquinone increased,and the fraction of hydrogen peroxide extracted reached a plateau with a maximum of 72.94%.However,both the conversion of anthrahydroquinone and the fraction of hydrogen peroxide extracted decreased with increasing organic phase superficial velocity.
