A new heteronuclear complex, dimer [(2-OH2)2Ba2(H2O)4][VO2(tpa)]24H2O (tpa: 2,4,6-tripicolinate trianion), was synthesized and structurally determined by X-ray diffraction technique where all hydrogen atoms have been ...A new heteronuclear complex, dimer [(2-OH2)2Ba2(H2O)4][VO2(tpa)]24H2O (tpa: 2,4,6-tripicolinate trianion), was synthesized and structurally determined by X-ray diffraction technique where all hydrogen atoms have been located directly. The coordination geometry of V(V) ion is a distorted trigonal bipyrimid and that of Ba(II) ion is a capped square antiprism. One 2-O bridging bond and two hydrogen bonds act between the coordination geometries. A 1-D extended porous construction containing 20-member cavities is observed in the crystal.展开更多
基金This project is supported by NNSF of China(60172003)Specialized Research Foundations of Shandong Province(11120106).
文摘A new heteronuclear complex, dimer [(2-OH2)2Ba2(H2O)4][VO2(tpa)]24H2O (tpa: 2,4,6-tripicolinate trianion), was synthesized and structurally determined by X-ray diffraction technique where all hydrogen atoms have been located directly. The coordination geometry of V(V) ion is a distorted trigonal bipyrimid and that of Ba(II) ion is a capped square antiprism. One 2-O bridging bond and two hydrogen bonds act between the coordination geometries. A 1-D extended porous construction containing 20-member cavities is observed in the crystal.
