This article investigated molybdenum recovery from oxygen pressure water leaching residue of Ni-Mo ore using alkaline leaching, followed by chemical treatment of leach liquor. Parameters affecting Mo leaching rate, su...This article investigated molybdenum recovery from oxygen pressure water leaching residue of Ni-Mo ore using alkaline leaching, followed by chemical treatment of leach liquor. Parameters affecting Mo leaching rate, such as sodium hydroxide concentration, reaction time, a liquid- to-solid ratio, and temperature for the preliminary alkaline leaching were experimentally determined. The results showed that more than 88 % of molybdenum was leached under the optimum conditions (2.5 ml.g-1 NaOH, 80 ℃, a liquid to solid ratio 3 ml.g-1, and reaction time 3 h). After the purification of leach liquor, a CaMoO4 product of 99.2 % purity could be obtained by CaCla precipitation method. The whole Mo recovery reached about 82.7 %.展开更多
基金supported by the National High Technology Research and Development Program of China(No.2009AA06Z106)Yunnan Provincial Science and Technology Department of China(No.2011GA004)
文摘This article investigated molybdenum recovery from oxygen pressure water leaching residue of Ni-Mo ore using alkaline leaching, followed by chemical treatment of leach liquor. Parameters affecting Mo leaching rate, such as sodium hydroxide concentration, reaction time, a liquid- to-solid ratio, and temperature for the preliminary alkaline leaching were experimentally determined. The results showed that more than 88 % of molybdenum was leached under the optimum conditions (2.5 ml.g-1 NaOH, 80 ℃, a liquid to solid ratio 3 ml.g-1, and reaction time 3 h). After the purification of leach liquor, a CaMoO4 product of 99.2 % purity could be obtained by CaCla precipitation method. The whole Mo recovery reached about 82.7 %.