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BC/CoNi_(2)S_(4)@PPy柔性复合电极材料的制备及电化学性能 被引量:2
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作者 彭思源 杨实润 +4 位作者 周静红 隋志军 章涛 石易 周兴贵 《电化学》 CAS CSCD 北大核心 2021年第1期14-25,共12页
本文采用溶剂热、原位聚合和真空抽滤相结合的方法制备了用于超级电容器的细菌纤维素/镍钴硫化物/聚吡咯(BC/CoNi_(2)S_(4)@PPy)柔性电极材料,通过X射线衍射、场发射扫描电镜、红外光谱、氮气吸脱附、拉伸强度和接触角表征了材料的形貌... 本文采用溶剂热、原位聚合和真空抽滤相结合的方法制备了用于超级电容器的细菌纤维素/镍钴硫化物/聚吡咯(BC/CoNi_(2)S_(4)@PPy)柔性电极材料,通过X射线衍射、场发射扫描电镜、红外光谱、氮气吸脱附、拉伸强度和接触角表征了材料的形貌结构、组成、机械性能和亲水性,并采用循环伏安法和恒电流充放电测试了复合材料的电化学性能。结果表明,表面含氧官能团丰富的BC纤维网络结构对氧化还原活性物质CoNi_(2)S_(4)的生长和导电聚合物PPy的分布具有引导作用,CoNi_(2)S_(4)均匀分布在BC网络中,且PPy均匀包覆在BC纤维和CoNi_(2)S_(4)纳米球表面构成具有丰富孔隙结构的三维导电网络,使得该复合材料具有较好的机械性(抗拉强度达28.0±0.1 MPa)、亲水性(对6 mol·L^(-1)KOH的瞬间接触角为43.6°)及良好的导电性。该电极材料在1 A·g^(-1)下比电容高达2670 F·g^(-1),充放电循环10000次后比电容的保持率为82.73%,且经1000次反复弯曲后电化学性能保持不变。此外,将其与活性炭组成的非对称超级电容器,在1 A·g^(-1)下比电容为1428 F·g^(-1),最高能量密度和功率密度分别达49.8 Wh·kg^(-1)和741.8 W·kg^(-1)。 展开更多
关键词 柔性电极材料 细菌纤维素 镍钴硫化物 聚吡咯
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Temperature-dependent tensile properties of ultrafine-grained C-doped CoCrFeMnNi high-entropy alloy 被引量:1
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作者 Yan-Zhong Tian si-yuan peng +6 位作者 Shang-Feng Chen Zi-Jian Gu Yang Yang Xiu-Ling Shang Guan-Yu Deng Li-Hong Su Shi-Jie Sun 《Rare Metals》 SCIE EI CAS CSCD 2022年第8期2877-2885,共9页
Metallic materials can be strengthened by various kinds of plastic deformation strategies.However,the deformed materials suffer poor ductility and thermal stability due to the high-density defects.In this work,we prep... Metallic materials can be strengthened by various kinds of plastic deformation strategies.However,the deformed materials suffer poor ductility and thermal stability due to the high-density defects.In this work,we prepared fully recrystallized ultrafine-grained(UFG)1%CCoCrFeMnNi high-entropy alloy(C-HEA)through cold rolling and annealing process.Quasi-static tensile tests were performed at temperatures between 77 and 823 K.Deformation micros true tures of the samples after tensile tests were characterized,and deformation mechanisms were discussed.There is a transition of deformation mechanisms from twinning and dislocation slip to dislocation slip and grain boundary sliding with temperature increasing.The UFG C-HEA exhibits balanced strength and ductility from the cryogenic temperature to high temperatures,indicating highly adaptive microstructure and mechanical properties.The strength and uniform elongation of the UFG C-HEA decrease monotonously with temperature increasing,but the elongation to failure exhibits the lowest value at the medium temperature.The grain boundary sliding is supposed to assist the unconventionally high elongation at 823 K. 展开更多
关键词 High-entropy alloy Temperature DUCTILITY STRENGTH Ultrafine grain
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