Characterizations and Analysis of the Mold from Animal Specimens in Shenzhen Museum

Biological specimens play an important role in cultural exchange, science popularization, scientific research and economic window, but the preparation and preservation technology system of biological specimens is relatively unsafe and inefficient. Mold grows seriously on animal specimens, which is not only harmful to human beings’ health and environment, but also is one of the factors that restricts the development of the natural history museums where these specimens are kept. This paper identified the mold species of animal specimens by PCR with ITS primers, bio-micro-scopic observation, sequencing and phylogenetic tree analysis. The results showed the mold of animal specimens mainly belonged to Aspergillus and Neurospora. This study established the foundations of controlling and restoring the mold that infected animal specimens and guided a new methodology of preparation and environmental friendly exhibition for animal specimens.

UV光催化桐油基多元醇的制备及超支化聚氨酯的表征

首先将桐油与甲醇经过酯交换反应得到桐酸甲酯,再将其与过氧化氢和乙酸反应制备环氧桐酸甲酯;然后以三芳基硫金翁盐为催化剂,在UV光条件下催化环氧桐酸甲酯与二乙醇胺开环,制备桐油基多元醇;最后以桐油基多元醇、异佛尔酮二异氰酸酯、甲基丙烯酸羟乙酯等为原料,以二月桂酸二丁基锡为催化剂,经过两步法反应制备了桐油基超支化聚氨酯丙烯酸酯。结果表明,在UV光条件下,三芳基硫金翁盐可以催化环氧桐酸甲酯开环制备桐油基多元醇,其羟基值为599.54 mg KOH/g,相对分子质量为544;以桐油基多元醇为核得到的聚氨酯丙烯酸酯具有良好的光固化活性,以及良好的热稳定性能和力学性能,并且成膜的表面光滑、平整,其玻璃化转变温度为37.2℃,拉伸强度为8.58 MPa,断裂伸长率为23.31%,表面张力为41.36 mJ/m 2。