Photonic crystals(PCs)exhibit promising structural coloration properties and possess extensive application prospects in diverse optical fields.However,state-of-the-art inorganic or polymeric PCs show limited adaptivit...Photonic crystals(PCs)exhibit promising structural coloration properties and possess extensive application prospects in diverse optical fields.However,state-of-the-art inorganic or polymeric PCs show limited adaptivity as their configurations are fixed once formed.Herein,bio-organic adaptive PCs are fabricated via drop-casting of amphiphilic guanine-based peptide nucleic acid selfassembled microspheres.The high formation activation energy of up to 81.8 kJ·mol−1 suggests that the self-assembly step dominates the entire process.Therefore,the configurations along with the structural coloration of the supramolecular PCs are sensitive to self-assembly influencing parameters,showing temperature-encoded structural color evolution and solvent polaritydependent solvatochromism.Our findings demonstrate that the supramolecular PCs are adaptive,thus showing promising potential for detection of organic solvents of different polarities in a visual and real-time manner for environmental protection or optical applications.展开更多
Hydrogen bonds are non-covalent interactions and essential for assembling supermolecules into ordered structures in biological systems,endowing crystals with fascinating physical properties,and inspiring the construct...Hydrogen bonds are non-covalent interactions and essential for assembling supermolecules into ordered structures in biological systems,endowing crystals with fascinating physical properties,and inspiring the construction of eco-friendly electromechanical devices.However,the interplay between hydrogen bonding and the physical properties is not fully understood at the molecular level.Herein,we demonstrate that the physical property of biological crystals with double-layer structures could be enhanced by rationally controlling hydrogen bonding interactions between amino and carboxyl groups.Different hydrogen bonding interactions result in various thermal,mechanical,electronic,and piezoelectric properties.In particular,the weak interaction between O and H atoms contributes to low mechanical strength that permits important ion displacement under stress,giving rise to a strong piezoelectric response.This study not only reveals the correlation between the hydrogen bonding and physical properties in double-layer structures of biological crystals but also demonstrates the potential of these crystals as functional biomaterials for high-performance energy-harvesting devices.Theoretical calculations and experimental verifications in this work provide new insights into the rational design of biomaterials with desirable physical properties for bioelectrical devices by modulating intermolecular interactions.展开更多
基金the National Key Research and Development Program of China(No.2022YFE0100800)the National Natural Science Foundation of China(No.52175551)。
文摘Photonic crystals(PCs)exhibit promising structural coloration properties and possess extensive application prospects in diverse optical fields.However,state-of-the-art inorganic or polymeric PCs show limited adaptivity as their configurations are fixed once formed.Herein,bio-organic adaptive PCs are fabricated via drop-casting of amphiphilic guanine-based peptide nucleic acid selfassembled microspheres.The high formation activation energy of up to 81.8 kJ·mol−1 suggests that the self-assembly step dominates the entire process.Therefore,the configurations along with the structural coloration of the supramolecular PCs are sensitive to self-assembly influencing parameters,showing temperature-encoded structural color evolution and solvent polaritydependent solvatochromism.Our findings demonstrate that the supramolecular PCs are adaptive,thus showing promising potential for detection of organic solvents of different polarities in a visual and real-time manner for environmental protection or optical applications.
基金the National Nature Science Foundation of China(grant nos.52192610,51973170,12002054,and 52202186)Ministry of Science and Technology of China(grant no.SQ2021YFE010405)+7 种基金Israel Science Foundation and National Natural Sciences Foundation of China Bilateral grant(grant no.3145/19)Ministry of Science and Technology of Israel project(grant no.3-18130)the China-Israel Cooperative Scientific Research,Fundamental Research Funds for the Central Universities(grant no.ZDRC2205)Fundamental Research Funds for the Central Universities(grant no.JC2107)Natural Science Foundation of Shaanxi Province(grant nos.2019JCW-17 and 2020JCW-15)Development and Planning Guide Foundation of Xidian University(grant no.21103200005)Fundamental Research Funds for the Central Universities(grant no.JC2107)State Scholarship Fund of China Scholarship Council(grant no.202006960032).
文摘Hydrogen bonds are non-covalent interactions and essential for assembling supermolecules into ordered structures in biological systems,endowing crystals with fascinating physical properties,and inspiring the construction of eco-friendly electromechanical devices.However,the interplay between hydrogen bonding and the physical properties is not fully understood at the molecular level.Herein,we demonstrate that the physical property of biological crystals with double-layer structures could be enhanced by rationally controlling hydrogen bonding interactions between amino and carboxyl groups.Different hydrogen bonding interactions result in various thermal,mechanical,electronic,and piezoelectric properties.In particular,the weak interaction between O and H atoms contributes to low mechanical strength that permits important ion displacement under stress,giving rise to a strong piezoelectric response.This study not only reveals the correlation between the hydrogen bonding and physical properties in double-layer structures of biological crystals but also demonstrates the potential of these crystals as functional biomaterials for high-performance energy-harvesting devices.Theoretical calculations and experimental verifications in this work provide new insights into the rational design of biomaterials with desirable physical properties for bioelectrical devices by modulating intermolecular interactions.