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Heterogeneous photocatalytic degradation of diuron on zinc oxide: Influence of surface-dependent adsorption on kinetics,degradation pathway,and toxicity of intermediates 被引量:2
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作者 Sutaporn Meephon Thanyada Rungrotmongkol +2 位作者 somchintana puttamat Supareak Praserthdam Varong Pavarajarn 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2019年第10期97-111,共15页
Heterogeneous photocatalytic reaction has been generally applied for degradation of toxic contaminants.Degradations of a compound using the same kind of catalyst that was synthesized differently are commonly found in ... Heterogeneous photocatalytic reaction has been generally applied for degradation of toxic contaminants.Degradations of a compound using the same kind of catalyst that was synthesized differently are commonly found in literature.However,the reported degradation intermediates are normally inconsistent.This issue is especially important for the degradation of toxic compounds because intermediates may be more toxic than their parent compounds and understanding the reason is necessary if appropriate catalysts are to be designed.This work systematically compares the photocatalytic degradation of diuron,a toxic recalcitrant herbicide,on two forms of zinc oxide(ZnO),i.e.,conventional particles with zinc-and oxygen-terminated polar surfaces as the dominating planes,and nanorods with mixed-terminated nonpolar surfaces.Experimental and theoretical results indicate that both the rate of reaction and the degradation pathway depend on the adsorption configuration of diuron onto the surface.Diuron molecules adsorb in different alignments on the two surfaces,contributing to the formation of different degradation intermediates.Both the aliphatic and aromatic sides of diuron adsorb on the polar surfaces simultaneously,leading to an attack by hydroxyl radicals from both ends.On the other hand,on the mixed-terminated surface,only the aliphatic part adsorbs and is degraded.The exposed surface is therefore the key factor controlling the degradation pathway.For diuron degradation on ZnO,a catalyst confined tomixed-terminated surfaces,i.e.,ZnO nanorods,is more desirable,as it avoids the formation of intermediates with potent phytotoxicity and cytogenotoxicity. 展开更多
关键词 DIURON Photocatalysis ADSORPTION Degradation pathway Mechanism Toxicity
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