Hemicellulose in corn straw is a group of complex heteropolysaccharides which are composed of different sugar units, including mannans, xylans, arabinans and galactans. This study developed a simple and practical proc...Hemicellulose in corn straw is a group of complex heteropolysaccharides which are composed of different sugar units, including mannans, xylans, arabinans and galactans. This study developed a simple and practical process for production of 5-hydroxymethyl furfural(HMF) using hemicellulose that was extracted from corn straw. In the hemicellulose degradation process HCOOH/HCOONa was used as buffer solution, and the optimum conditions for maximum HMF yield were explored. Various extraction conditions including NaOH concentration, reaction time,temperature, solid-to-liquid ratio and precipitant were tested for hemicellulose obtaining, giving the optimum condition of 55 °C, 4 h, solid-to-liquid ratio of 1:10, 1.5 mol·L^(-1) NaOH solution and ethanol as precipitant with the yield of 34.16%. Dehydration of hemicellulose under HCOOH/HCOONa buffer solution process, using solution medium of pH = 0.8 hydrolyzed hemicellulose in corn straw at 190 °C after 190 min and 82% of HMF yield was achieved.展开更多
By reasearch on geographic distribution,nine genera in bipolar distribution are selected from Permian brachiopods.These taxa originated from middle-high latitude areas in the boreal realm,of which five genera were der...By reasearch on geographic distribution,nine genera in bipolar distribution are selected from Permian brachiopods.These taxa originated from middle-high latitude areas in the boreal realm,of which five genera were derived from Late Carboniferous,and other four genera originated from Permian.They were all in bipolar distribution during some different stages in Permian.Specific diversity for each genus was high in the boreal realm,whereas in the Gondwana realm was very low.Perdurability was long in the boreal realm,and short in the Gondwana realm.It was the time when these nine genera came to their maximum diversity that these genera appeared in the Gondwana and formed bipolar distribution;while they also migrated to the low latitude from high latitude.This shows very close relationship between several main cooling events in Permian and the migration of genera from the boreal realm to the Gondwana realm through the Tethys.Therefore,the cooling events might be the main drive which caused these cold-water-type brachiopods migrated to the Gondwana realm and being bipolar distribution.In this process,the planula tolerance to warm water would be another important factor.展开更多
基金Supported by the National Natural Science Foundation of China(No.21576067)
文摘Hemicellulose in corn straw is a group of complex heteropolysaccharides which are composed of different sugar units, including mannans, xylans, arabinans and galactans. This study developed a simple and practical process for production of 5-hydroxymethyl furfural(HMF) using hemicellulose that was extracted from corn straw. In the hemicellulose degradation process HCOOH/HCOONa was used as buffer solution, and the optimum conditions for maximum HMF yield were explored. Various extraction conditions including NaOH concentration, reaction time,temperature, solid-to-liquid ratio and precipitant were tested for hemicellulose obtaining, giving the optimum condition of 55 °C, 4 h, solid-to-liquid ratio of 1:10, 1.5 mol·L^(-1) NaOH solution and ethanol as precipitant with the yield of 34.16%. Dehydration of hemicellulose under HCOOH/HCOONa buffer solution process, using solution medium of pH = 0.8 hydrolyzed hemicellulose in corn straw at 190 °C after 190 min and 82% of HMF yield was achieved.
基金Supported by Project of Doctoral Program of Ministry Education (No.20060183023)
文摘By reasearch on geographic distribution,nine genera in bipolar distribution are selected from Permian brachiopods.These taxa originated from middle-high latitude areas in the boreal realm,of which five genera were derived from Late Carboniferous,and other four genera originated from Permian.They were all in bipolar distribution during some different stages in Permian.Specific diversity for each genus was high in the boreal realm,whereas in the Gondwana realm was very low.Perdurability was long in the boreal realm,and short in the Gondwana realm.It was the time when these nine genera came to their maximum diversity that these genera appeared in the Gondwana and formed bipolar distribution;while they also migrated to the low latitude from high latitude.This shows very close relationship between several main cooling events in Permian and the migration of genera from the boreal realm to the Gondwana realm through the Tethys.Therefore,the cooling events might be the main drive which caused these cold-water-type brachiopods migrated to the Gondwana realm and being bipolar distribution.In this process,the planula tolerance to warm water would be another important factor.
