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Effects of imidazolium-based ionic liquids on the isobaric vapor–liquid equilibria of methanol+dimethyl carbonate azeotropic systems 被引量:4
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作者 songsong chen Li Dong +4 位作者 Junping Zhang Weiguo cheng Feng Huo Qian Su Wei Hua 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2020年第3期766-776,共11页
The separation of methanol(MeOH)and dimethyl carbonate(DMC)is important but difficult due to the formation of an azeotropic mixture.In this work,isobaric vapor–liquid equilibrium(VLE)data for the ternary systems cont... The separation of methanol(MeOH)and dimethyl carbonate(DMC)is important but difficult due to the formation of an azeotropic mixture.In this work,isobaric vapor–liquid equilibrium(VLE)data for the ternary systems containing different imidazolium–based ionic liquids(ILs),i.e.MeOH+DMC+1-butyl-3-methy-limidazolium bis[(trifluoromethyl)sulfonyl]imide([Bmim][Tf2N]),MeOH+DMC+1-ethyl-3-methyl-imidazolium bis[(trifluoromethyl)sulfonyl]imide([Emim][Tf2N]),and MeOH+DMC+1-ethyl-3-methylimidazolium hexafluorophosphate([Emim][PF6])were measured at 101.3 kPa.The mole fraction of IL was varied from0.05 to 0.20.The experimental data were correlated with the NRTL and Wilson equations,respectively.The results show that imidazolium-based ILs were beneficial to improve the relative volatility of MeOH to DMC,and[Bmim][Tf2 N]showed a much more excellent performance on the activity coefficient of MeOH.The interaction energies of system components were calculated using Gaussian program,and the effects of cation and anion on the separation coefficient of the azeotropic system were discussed. 展开更多
关键词 Vapor liquid equilibria Ionic liquid AZEOTROPE Separation Interaction energy
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An Eye-Movement Study on the Cognitive Neuroscience Mechanisms of Chinese Classifier Construction
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作者 Yan Liu Junyan Wei songsong chen 《教育研究前沿(中英文版)》 2021年第1期36-43,共8页
The study manipulated semantic and syntactic variables to explore the cognitive neuroscience mechanisms of Chinese classifier construction"yi+N(CL)+N".It was indicated:First,the mismatch could be dissolved i... The study manipulated semantic and syntactic variables to explore the cognitive neuroscience mechanisms of Chinese classifier construction"yi+N(CL)+N".It was indicated:First,the mismatch could be dissolved if and only if the CL and modified noun were semantically related,which implied the significance of semantics in dissolving syntactic conflicts and processing linguistic items.Second,syntactic and semantic information were both activated at the early and late stages of language processing,which is consistent with the claims of the extended Concurrent Model.Third,the Access Mechanism of CLs,i.e.items in ordinary partitive phrases and temporary partitive phrases was identified.The former were addressed in a direct way,while the latter were processed in an assembled way. 展开更多
关键词 Cognitive Neuroscience Mechanisms Chinese Classifier Construction COMPREHENSION
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甲基丙烯酸甲酯-甲醇-水共沸体系萃取分离工艺模拟 被引量:4
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作者 张军平 陈嵩嵩 +4 位作者 盛贵阳 王蕾 蒋元力 顾晓华 张香平 《过程工程学报》 CAS CSCD 北大核心 2018年第6期1323-1331,共9页
针对甲基丙烯酸甲酯-甲醇-水共沸体系,分别选择水、正己烷和水-正己烷双溶剂为萃取剂建立分离流程进行模拟,建立单溶剂、双溶剂萃取工艺过程进行全流程模拟,采用灵敏度分析优化工艺过程的溶剂比和操作温度.结果表明,双溶剂萃取工艺比水... 针对甲基丙烯酸甲酯-甲醇-水共沸体系,分别选择水、正己烷和水-正己烷双溶剂为萃取剂建立分离流程进行模拟,建立单溶剂、双溶剂萃取工艺过程进行全流程模拟,采用灵敏度分析优化工艺过程的溶剂比和操作温度.结果表明,双溶剂萃取工艺比水、正己烷单溶剂萃取工艺能耗分别降低15.1%和34.9%.采用绿色度评价方法量化3种分离工艺对环境的影响,水、正己烷、水-正己烷双溶剂萃取工艺的绿色度分别为-7.25,-21.3和-6.75gd. 展开更多
关键词 甲基丙烯酸甲酯 共沸体系 双溶剂萃取 工艺模拟 绿色度
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煤基甲醇芳构化分离过程多目标优化 被引量:2
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作者 郭艳东 苏航 +2 位作者 陈嵩嵩 霍锋 张军平 《过程工程学报》 CAS CSCD 北大核心 2021年第1期71-82,共12页
国内煤化工产品普遍存在产能过剩和同质化严重的问题,开发以煤基甲醇合成二甲苯的新技术具有重大意义。针对煤基甲醇合成二甲苯技术中面临分离过程能耗高的难题,本工作基于甲醇芳构化技术,利用Aspen Plus与Matlab的交互链接,对非芳烃、... 国内煤化工产品普遍存在产能过剩和同质化严重的问题,开发以煤基甲醇合成二甲苯的新技术具有重大意义。针对煤基甲醇合成二甲苯技术中面临分离过程能耗高的难题,本工作基于甲醇芳构化技术,利用Aspen Plus与Matlab的交互链接,对非芳烃、苯、甲苯、二甲苯、三甲苯的分离过程开展了多目标优化研究。采用NSGA-Ⅱ遗传算法,以苯-甲苯收率、二甲苯收率、年度总成本和能耗指标作为四个目标函数,分别针对传统双塔精馏序列工艺和分隔壁塔精馏工艺进行了多目标优化,发现回流比对年度总成本的影响最明显。在满足约束条件的前提下,基于最低的年度总成本对两个分离工艺进行了比较。结果表明,分隔壁塔工艺较双塔精馏序列工艺的最低年度总成本低7.7%,换热器花费低16.1%,能耗指标低26.3%。分隔壁塔工艺成本低、能耗低,具有环保、绿色、可持续性的优势。 展开更多
关键词 煤基甲醇 芳构化 多组分精馏 分隔壁塔 NSGA-Ⅱ遗传算法 多目标优化
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酯交换法制备碳酸二甲酯过程模拟与系统?分析 被引量:2
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作者 陈嵩嵩 董丽 +2 位作者 张军平 成卫国 华炜 《过程工程学报》 CAS CSCD 北大核心 2018年第6期1307-1314,共8页
针对酯交换制备过程中甲醇-碳酸二甲酯共沸体系难分离的问题,分别选择变压精馏、碳酸乙烯酯(EC)萃取精馏与乙二醇(EG)萃取精馏3种分离过程进行模拟与能量集成,对比了3种工艺流程的分离能耗,采用有效能([火用])分析方法分析了能耗最低的... 针对酯交换制备过程中甲醇-碳酸二甲酯共沸体系难分离的问题,分别选择变压精馏、碳酸乙烯酯(EC)萃取精馏与乙二醇(EG)萃取精馏3种分离过程进行模拟与能量集成,对比了3种工艺流程的分离能耗,采用有效能([火用])分析方法分析了能耗最低的变压分离过程的有效能([火用])损失.结果表明,3种工艺流程的能耗EG萃取精馏>EC萃取精馏>变压精馏,碳酸二甲酯生产过程中内部循环物流能量是输入总能量的1.55倍,变压共沸分离过程的[火用]损失为7.9%。 展开更多
关键词 碳酸二甲酯 共沸物分离 过程模拟 系统集成 [火用]分析
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Future evolution of automated demand response system in smart grid for low-carbon economy 被引量:12
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作者 Huaguang YAN Bin LI +4 位作者 songsong chen Ming ZHONG Dezhi LI Limin JIANG Guixiong HE 《Journal of Modern Power Systems and Clean Energy》 SCIE EI 2015年第1期72-81,共10页
Smart grid construction is an important carrier and an effective way to promote the development of lowcarbon economy.Demand response(DR)is commonly regarded as an important core technology in smart grid field,and it r... Smart grid construction is an important carrier and an effective way to promote the development of lowcarbon economy.Demand response(DR)is commonly regarded as an important core technology in smart grid field,and it reflects the flexible and interactive features of the core business in smart electricity.It is the developing direction of automated demand response(ADR)technology,and its main features are the standardization of information exchange,together with the intelligence of decision-making and the automation of implementations.ADR technology can improve the efficiency of the whole power system and enhance the ability to accept new energy sources.This paper analyzes the role of demand response in improving efficiency and low-carbon energy saving power systems.The automated demand response system architecture is investigated,and the ADR roadmap of commercial/industrial and residential customer is proposed.The key technologies for ADR system are analyzed,including demand response strategy,information exchanging model,measurement and verification techniques,and multi-agent scheduling techniques.To ensure the interoperability between the grid side and the user side,the ADR business in smart grid user interface standards is concluded to support further demand side management project. 展开更多
关键词 Demand response Information model System architecture Load shifting
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