Mixed-dimensional van der Waals(vdW)heterostructures based on two-dimensional transition metal dichalcogenides and threedimensional semiconductors have led to a new era in next-generation optoelectronics due to the hi...Mixed-dimensional van der Waals(vdW)heterostructures based on two-dimensional transition metal dichalcogenides and threedimensional semiconductors have led to a new era in next-generation optoelectronics due to the high-quality interfaces and energy band complementation,especially in broadband photodetectors which can be used for all-weather navigation,object identification,etc.However,the reported photodetectors conventionally operated in photodiode mode with low responsivity and a narrow response spectrum.In this study,we report a p-WSe_(2)/n-Ge vdW heterojunction phototransistor with a Schottky barrier collector on n-Ge for broadband photodetection.Large hole/electron injection ratio from p-WSe_(2)/n-Ge heterojunction under forward bias due to their large bandgap offset renders the high photocurrent gain,while the Ge Schottky barrier limits the dark current.The responsivities of the phototransistor at 1.0 V emitter-collector bias are 55,95,and 120 A·W−1 at 405,1,310,and 1,550 nm,respectively,which is superior to that of the corresponding p-WSe_(2)/n-Ge photodiodes.The phototransistor shows a high photocurrent gain of 80,a specific detectivity of 1011 Jones,as well as a fast response time of 290μs at 1,550 nm.The results suggest that the novel phototransistor being implemented with complementary metal-oxide-semiconductor processing is an ideal strategy for high-performance broadband photodetection.展开更多
Inspired by the pomegranate natural artful structure,pomegranate micro/nano hierarchical plasma configuration of Fe/Fe3C@graphitized carbon(FFC/pCL)was constructed based on the green sol-gel method and in-situ chemica...Inspired by the pomegranate natural artful structure,pomegranate micro/nano hierarchical plasma configuration of Fe/Fe3C@graphitized carbon(FFC/pCL)was constructed based on the green sol-gel method and in-situ chemical vapor deposition(CVD)synthesis protocol.Pomegranate-like FFC/pCL successfully overcame the agglomeration phenomenon of magnetic nanoparticles with each seed of the pomegranate consisting of Fe/Fe_(3)C as cores and graphitized carbon layers as shells.The high-density arrangement of magnetic nanoparticles and the design of pomegranate-like heterostructures lead to enhanced plasmon resonance.Thus,the pomegranate-like FFC/pCL achieved a great electromagnetic wave(EMW)absorbing performance of 6.12 GHz wide band absorption at a low mass adding of only 16.7 wt.%.Such excellent EMW performance can be attributed to its unique pomegranate hierarchical plasma configuration with separated nanoscale iron cores,surface porous texture,and good carbon conductive network.This investigation provides a new paradigm for the development of magnetic/carbon based EMW absorbing materials by taking advantage of pomegranate hierarchical plasma configuration.展开更多
基金supported by the National Key Research and Development Program of China(No.2018YFB2200103)the National Natural Science Foundation of China(No.62074134).
文摘Mixed-dimensional van der Waals(vdW)heterostructures based on two-dimensional transition metal dichalcogenides and threedimensional semiconductors have led to a new era in next-generation optoelectronics due to the high-quality interfaces and energy band complementation,especially in broadband photodetectors which can be used for all-weather navigation,object identification,etc.However,the reported photodetectors conventionally operated in photodiode mode with low responsivity and a narrow response spectrum.In this study,we report a p-WSe_(2)/n-Ge vdW heterojunction phototransistor with a Schottky barrier collector on n-Ge for broadband photodetection.Large hole/electron injection ratio from p-WSe_(2)/n-Ge heterojunction under forward bias due to their large bandgap offset renders the high photocurrent gain,while the Ge Schottky barrier limits the dark current.The responsivities of the phototransistor at 1.0 V emitter-collector bias are 55,95,and 120 A·W−1 at 405,1,310,and 1,550 nm,respectively,which is superior to that of the corresponding p-WSe_(2)/n-Ge photodiodes.The phototransistor shows a high photocurrent gain of 80,a specific detectivity of 1011 Jones,as well as a fast response time of 290μs at 1,550 nm.The results suggest that the novel phototransistor being implemented with complementary metal-oxide-semiconductor processing is an ideal strategy for high-performance broadband photodetection.
基金supported by the Taishan Scholar Project(No.ts201511080)the China Postdoctoral Science Foundation(No.2021M691963)+3 种基金the Key Research and Development Program of Shandong Province of China(Nos.2020JMRH0503 and 2019JMRH0402)the Fundamental Research Funds for the Central Universities(No.HIT.OCEF.2021003)the National Natural Science Foundation of China(Nos.51672059 and 51772060)Doctoral Scientific Research Start-up Foundation from Shandong University of Technology(Nos.4041/419008 and 4041/420022).
文摘Inspired by the pomegranate natural artful structure,pomegranate micro/nano hierarchical plasma configuration of Fe/Fe3C@graphitized carbon(FFC/pCL)was constructed based on the green sol-gel method and in-situ chemical vapor deposition(CVD)synthesis protocol.Pomegranate-like FFC/pCL successfully overcame the agglomeration phenomenon of magnetic nanoparticles with each seed of the pomegranate consisting of Fe/Fe_(3)C as cores and graphitized carbon layers as shells.The high-density arrangement of magnetic nanoparticles and the design of pomegranate-like heterostructures lead to enhanced plasmon resonance.Thus,the pomegranate-like FFC/pCL achieved a great electromagnetic wave(EMW)absorbing performance of 6.12 GHz wide band absorption at a low mass adding of only 16.7 wt.%.Such excellent EMW performance can be attributed to its unique pomegranate hierarchical plasma configuration with separated nanoscale iron cores,surface porous texture,and good carbon conductive network.This investigation provides a new paradigm for the development of magnetic/carbon based EMW absorbing materials by taking advantage of pomegranate hierarchical plasma configuration.