The functional materials based on natural zeolite(clinoptilolite),TiO2-zeolite and Ag-TiO2-zeolite have been successfully synthesized by solid-state reaction in fast-hydrothermal conditions.The obtained functional mat...The functional materials based on natural zeolite(clinoptilolite),TiO2-zeolite and Ag-TiO2-zeolite have been successfully synthesized by solid-state reaction in fast-hydrothermal conditions.The obtained functional materials were investigated by X-ray diffraction(XRD),FT-IR(Fourier transform infrared)spectroscopy,DRUV-VIS(diffuse reflectance ultraviolet-visible)spectroscopy,BET(Brunauer-Emmett-Teller)and SEM/EDX(scanning electron microscope/energy dispersive X-ray spectrometer)analyses.The XRD results indicated that the clinoptilolite structure has a good thermal stabilization after the fast-hydrothermal treatment.Also,the high specific surface area about 92.55 m2·g 1was noticed for Ag-TiO2-zeolite functional material.The presence of dopants was evidenced from EDX spectra.The enhanced bactericidal activity of Ag-TiO2-zeolite catalyst is proved through damaging of Enterococcus faecalis colonies under visible irradiation,at different material doses and irradiation times.展开更多
基金Supported by the Sectoral Operational Programme Human Resources Development(SOP HRD)Financed from the European Social Fundthe Romanian Government under the Contract Number POSDRU/89/1.5/S/63700
文摘The functional materials based on natural zeolite(clinoptilolite),TiO2-zeolite and Ag-TiO2-zeolite have been successfully synthesized by solid-state reaction in fast-hydrothermal conditions.The obtained functional materials were investigated by X-ray diffraction(XRD),FT-IR(Fourier transform infrared)spectroscopy,DRUV-VIS(diffuse reflectance ultraviolet-visible)spectroscopy,BET(Brunauer-Emmett-Teller)and SEM/EDX(scanning electron microscope/energy dispersive X-ray spectrometer)analyses.The XRD results indicated that the clinoptilolite structure has a good thermal stabilization after the fast-hydrothermal treatment.Also,the high specific surface area about 92.55 m2·g 1was noticed for Ag-TiO2-zeolite functional material.The presence of dopants was evidenced from EDX spectra.The enhanced bactericidal activity of Ag-TiO2-zeolite catalyst is proved through damaging of Enterococcus faecalis colonies under visible irradiation,at different material doses and irradiation times.
