The iR and Raman spectra were rrieasured for[Fe_2Cr(μ_3-O)-(glycine)_6 (H_2O)_3] (NO_3)_7. 3H2O in the range of 2000～90 cm￣-1. The assignment of the main skeleton vibrations was made in comparison with related comp...The iR and Raman spectra were rrieasured for[Fe_2Cr(μ_3-O)-(glycine)_6 (H_2O)_3] (NO_3)_7. 3H2O in the range of 2000～90 cm￣-1. The assignment of the main skeleton vibrations was made in comparison with related compounds. A simplified model as well as a simplified general valence force field was used in the normal coordinate analysis of the skeleton and a set of force constants has been obtained. The calculated frequencies agree well with the observed ones, with a mean deviation of 1.8% which confirms the assignn: ient of their vibrational spectra. On the basis of the data obtained some discussions were made.展开更多
文摘The iR and Raman spectra were rrieasured for[Fe_2Cr(μ_3-O)-(glycine)_6 (H_2O)_3] (NO_3)_7. 3H2O in the range of 2000～90 cm￣-1. The assignment of the main skeleton vibrations was made in comparison with related compounds. A simplified model as well as a simplified general valence force field was used in the normal coordinate analysis of the skeleton and a set of force constants has been obtained. The calculated frequencies agree well with the observed ones, with a mean deviation of 1.8% which confirms the assignn: ient of their vibrational spectra. On the basis of the data obtained some discussions were made.
