In this study,an environment-friendly layered double hydroxide(LDH)film has been deposited on Mg Ca alloy by a two-step technique.To improve the chemical conversion technique and control the film properties,batch stud...In this study,an environment-friendly layered double hydroxide(LDH)film has been deposited on Mg Ca alloy by a two-step technique.To improve the chemical conversion technique and control the film properties,batch studies have been carried out to address various process parameters such as pH value,treatment temperature and immersion time.The chemical composition was determined by X-ray diffractometry and energy dispersive X-ray spectroscopy.The morphology was characterized by scanning electron microscopy.The corrosion resistance of the samples with various films was compared by polarization curves and immersion test.It is found that the transformation duration of Mg-Fe LDH is long.Too high pH value and temperature has harmful effect on the purity of the film composition.The corrosion resistance of the films formed at low value of pH or high temperature or short treatment time is deteriorative.The optimum process is as follows:the sample is first immersed in the solution containing Fe^(3+)/HCO_(3)^-/CO_(3)^(2-)with a pH value of 5 at a temperature of 55℃for 1 h to form a precursor film,and then this precursor film is immersed into the solution containing Fe^(3+)/HCO_(3)^-/CO_(3)^(2-)with a pH of 11 at 55℃for 24 h to obtain the Mg-Fe LDH conversion film.展开更多
基金financial support by the Sichuan Science and Technology Program(No.2020YFG0165)the Projects in Sichuan Province Education Office(No.18ZA0453)+1 种基金the National Natural Science Foundation of China(No.51501156)the Sichuan Science and Technology Program(No.2019JDTD0024&No.2019ZHCG0048)。
文摘In this study,an environment-friendly layered double hydroxide(LDH)film has been deposited on Mg Ca alloy by a two-step technique.To improve the chemical conversion technique and control the film properties,batch studies have been carried out to address various process parameters such as pH value,treatment temperature and immersion time.The chemical composition was determined by X-ray diffractometry and energy dispersive X-ray spectroscopy.The morphology was characterized by scanning electron microscopy.The corrosion resistance of the samples with various films was compared by polarization curves and immersion test.It is found that the transformation duration of Mg-Fe LDH is long.Too high pH value and temperature has harmful effect on the purity of the film composition.The corrosion resistance of the films formed at low value of pH or high temperature or short treatment time is deteriorative.The optimum process is as follows:the sample is first immersed in the solution containing Fe^(3+)/HCO_(3)^-/CO_(3)^(2-)with a pH value of 5 at a temperature of 55℃for 1 h to form a precursor film,and then this precursor film is immersed into the solution containing Fe^(3+)/HCO_(3)^-/CO_(3)^(2-)with a pH of 11 at 55℃for 24 h to obtain the Mg-Fe LDH conversion film.
