MoS2/Zn3In2S6 composite photocatalysts for enhancement of visible light-driven hydrogen production from formic acid

Enhancing the separation efficiency of photogenerated carriers is propitious for the promotion of photocatalytic hydrogen production from formic acid decomposition.Herein,MoS2/Zn3In2S6(MoS2/ZIS6)composite photocatalysts containing varying mass percentages of MoS2 were obtained by a straightforward synthetic method.The results confirmed that MoS2,as a cocatalyst,markedly promoted the photogenerated charge separation efficiency and visible light-driven hydrogen production activity of ZIS6(λ>400 nm).Specifically,the as-prepared 0.5%MoS2/ZIS6 photocatalyst exhibited the highest photocatalytic hydrogen production rate(74.25μmol·h^-1),which was approximately 4.3 times higher than that of ZIS6(17.47μmol·h^-1).The excellent performance of the 0.5%MoS2/ZIS6 photocatalyst may be due to the fact that MoS2 has a low Fermi energy level and can thus enrich photogenerated electrons from ZIS6,and furthermore reduce H+derived from formic acid,to form hydrogen.The structure and morphology of the MoS2/ZIS6 photocatalysts and the reactive species were determined by X-ray diffraction,transmission electron microscopy,and field emission scanning electron microscopy,among others;a plausible mechanistic rationale is discussed based on the results.

Self-assembly synthesis of S-scheme g-C_(3)N_(4)/Bi_(8)(CrO_(4))O_(11) for photocatalytic degradation of norfloxacin and bisphenol A

To realize the high-efficiency photodegradation of antibiotics,a novel S-scheme heterojunction photocatalyst g-C_(3)N_(4)/Bi_(8)(CrO_(4))O_(11) was proposed and successfully prepared in this work.The 10%g-C_(3)N_(4)/Bi_(8)(CrO_(4))O_(11) heterojunction exhibits the highest degradation rate of norfloxacin(NOR)and bisphenol A(BPA).The degradation rate of NOR on 10%g-C_(3)N_(4)/Bi_(8)(CrO_(4))O_(11) is about 1.38 and 2.33 times higher than that of pure Bi_(8)(CrO_(4))O_(11) and g-C_(3)N_(4),respectively.Further,the degradation rate of BPA over 10%g-C_(3)N_(4)/Bi_(8)(CrO_(4))O_(11) heterojunction is bout 1.35 and 9.11 times higher than that of pure Bi_(8)(CrO_(4))O_(11) and g-C_(3)N_(4),respectively.The formation of S-scheme heterojunction facilitates the separation of photogenerated electron-hole pairs and reduces the recombination of charge carriers,which was confirmed by photocurrent,electrochemical impedance spectroscopy,steady-state and time-resolved transient photoluminescence spectrum,etc.The in-situ X-ray photoelectron spectroscopy,radical trapping experiments and electron paramagnetic resonance results demonstrate that the charge transfer is in accord with S-scheme mechanism.

Activity of Corn Silk at Different Days after Silk Emergence

This study was carried out to evaluate the changes in silk activity of two corn cultivars Xundan 518 and Yongyou 618 after silk emergence. Artificial pollination was conducted at different days after silk emergence, and the ear length, ear diameter,barren tip length, 100-grain weight, grain number per ear and grain weight per ear were measured at harvest. The results showed that with the delay of pollination, the number and weight of grains per ear increased at first, peaked at D2 to D4, and decreased subsequently; ear diameter and 100-grain weight showed a downward trend. Correlation analysis revealed that grain number per ear and grain weight per ear were most closely correlated. Rapid silk extrusion and long-lasting silk activity proved that the two corn cultivars Xundan 518 and Yongyou 618 are tolerant to high temperature.

Clinical Research Progress on Physical Rehabilitation Therapy for Migraine

Migraine is a common and recurrent chronic disorder.Migraine is often associated with anxiety,depression and other emotional diseases.With the development of physical rehabilitation techniques,the long-term clinical efficacy of rehabilitation in the treatment of migraine and the prevention of recurrence have been widely accepted.This paper reviews the effectiveness of physical rehabilitation therapy in clinical treatment of migraine in recent years.

A novel Z-scheme CeO_(2)/g-C_(3)N_(4)heterojunction photocatalyst for degradation of Bisphenol A and hydrogen evolution and insight of the photocatalysis mechanism

CeO_(2)/g-C_(3)N_(4)heterojunction photocatalyst had been successfully fabricated through a one-step in-situ pyrolysis formation of 3D hollow CeO_(2)mesoporous nanospheres and 2D g-C_(3)N_(4)nanosheets together with simultaneous removal of carbon sphere templates after heat treatment.The sample shows high catalytic performances for photocatalytic hydrogen generation and photocatalytic oxidation of Bisphenol A(BPA)under visible light irradiation,and the catalytic degradation route of BPA was suggested by the degradation products determined by GC-MS.The enhancing catalytic activity was attributed to the effective interfacial charge migration and separation.Finally,it was proposed that the CeO_(2)/g-C_(3)N_(4)heterojunction photocatalyst could follow a more appropriate Z-scheme charge transfer mechanism,which was confirmed by the analysis of experiment and theoretical calculation results.

Some remarks on cotilting comodules

We study cotilting comodules and f-cotilting comodules and give a description of localization of f-cotilting comodules and classical tilting comodules. First, we introduce T-cotilting injective comodules and their dimensions which are important for researching cotilting comodules. Then we characterize the localization in f-cotilting comodules, finitely copresented comodules, and classical tilting comodules. In particular, we obtain a localizing property about finitely copresented comodules.

Some Remarks on Hom-Modules and Hom-Path Algebras

This paper deals with injective and projective right HomH-modules for a Hom-algebra H. In particular, Baer Criterion of injective Hom-module is obtained, and it is shown that Hom Mod H is an Abelian category. Next, the authors define Hom-path algebras and construct Hom-path algebras of some quivers.