Raw and fried plantain chips obtained from the use and re-use of olive, refined palm olein and coconut oils were investigated for the proximate, mineral compositions, computed mineral ratios and the mineral safety ind...Raw and fried plantain chips obtained from the use and re-use of olive, refined palm olein and coconut oils were investigated for the proximate, mineral compositions, computed mineral ratios and the mineral safety index using standard analytical methods. For the selected oils (both use and re-use): first and second re-use and the fresh plantain chips (unprocessed plantain chips;UPC) had the following range results: proximate composition (%) (moisture: 8.20 - 12.3, crude protein: 9.70 - 8.60, fat: 7.40 - 12.9, fibre: 3.50 - 4.90, ash: 2.80 - 3.80 and carbohydrates: 63.5 - 64.8), % energy contributions (PEC: 63.4 - 70.8, PEF: 20.2 - 28.6, PEP: 8.03 - 9.66, UEDP: 4.49 - 5.08). The mineral composition (mg/100g) of the samples had the following greater than 80.0: Ca, Mg, K and P;Fe, Cu, Mn and Zn recorded values ranging between 1.00 and 4.00;Co, Se and Ni had their concentrations between 0.00 and 0.0363 whereas Pb and Cd recorded levels lower than 0.0006. In the mineral ratios, only K/(Ca + Mg) values fell within the acceptable ideal range. No MSI aberration was observed for the minerals from all the samples obtained from the various oils. The chi-square analysis showed that on parameter wise comparisons, there were no significant differences among the levels as treated based on the various oils except gross energy, Mg, K, P, Ca/P, Fe/Pb and K/Co. Also on pairwise comparison from linear correlation and regression, all these parameters were significantly different at r = 0.01 between the unprocessed and fried plantain samples: proximate, percentage energy distribution, mineral and mineral ratios. Generally, the first (day) frying showed fairly high nutrient concentration than the first and second re-use oils products. Therefore, for optimum nutrient preservation from fried plantain chips re-use of oil for frying should be sparingly allowed. However, olive showed highest level of nutrients in terms of proximate and mineral compositions.展开更多
Sulfadiazine Schiff base and Phenyl dithiocarbamate mixed ligand metal complexes have been synthesized and characterized. The characterization of metal complexes is based on the results of the solubility, colour, melt...Sulfadiazine Schiff base and Phenyl dithiocarbamate mixed ligand metal complexes have been synthesized and characterized. The characterization of metal complexes is based on the results of the solubility, colour, melting points and elemental analysis as well as the spectroscopic studies. The results obtained from the spectroscopic spectra revealed from the UV-visible showed the presence of chromophoric groups while the FTIR results confirmed that the metals coordinated through the two nitrogen atoms of Sulfadiazine Schiff base and sulphur atom of the N-phenyl dithiocarbamate. Also the antimicrobial activities of the metal complexes proved that the metal complexes are more active than the parent ligands.展开更多
文摘Raw and fried plantain chips obtained from the use and re-use of olive, refined palm olein and coconut oils were investigated for the proximate, mineral compositions, computed mineral ratios and the mineral safety index using standard analytical methods. For the selected oils (both use and re-use): first and second re-use and the fresh plantain chips (unprocessed plantain chips;UPC) had the following range results: proximate composition (%) (moisture: 8.20 - 12.3, crude protein: 9.70 - 8.60, fat: 7.40 - 12.9, fibre: 3.50 - 4.90, ash: 2.80 - 3.80 and carbohydrates: 63.5 - 64.8), % energy contributions (PEC: 63.4 - 70.8, PEF: 20.2 - 28.6, PEP: 8.03 - 9.66, UEDP: 4.49 - 5.08). The mineral composition (mg/100g) of the samples had the following greater than 80.0: Ca, Mg, K and P;Fe, Cu, Mn and Zn recorded values ranging between 1.00 and 4.00;Co, Se and Ni had their concentrations between 0.00 and 0.0363 whereas Pb and Cd recorded levels lower than 0.0006. In the mineral ratios, only K/(Ca + Mg) values fell within the acceptable ideal range. No MSI aberration was observed for the minerals from all the samples obtained from the various oils. The chi-square analysis showed that on parameter wise comparisons, there were no significant differences among the levels as treated based on the various oils except gross energy, Mg, K, P, Ca/P, Fe/Pb and K/Co. Also on pairwise comparison from linear correlation and regression, all these parameters were significantly different at r = 0.01 between the unprocessed and fried plantain samples: proximate, percentage energy distribution, mineral and mineral ratios. Generally, the first (day) frying showed fairly high nutrient concentration than the first and second re-use oils products. Therefore, for optimum nutrient preservation from fried plantain chips re-use of oil for frying should be sparingly allowed. However, olive showed highest level of nutrients in terms of proximate and mineral compositions.
文摘Sulfadiazine Schiff base and Phenyl dithiocarbamate mixed ligand metal complexes have been synthesized and characterized. The characterization of metal complexes is based on the results of the solubility, colour, melting points and elemental analysis as well as the spectroscopic studies. The results obtained from the spectroscopic spectra revealed from the UV-visible showed the presence of chromophoric groups while the FTIR results confirmed that the metals coordinated through the two nitrogen atoms of Sulfadiazine Schiff base and sulphur atom of the N-phenyl dithiocarbamate. Also the antimicrobial activities of the metal complexes proved that the metal complexes are more active than the parent ligands.
