The PMA/Eu2O3 porous and layered nanocomposite was prepared by in situ polymerization and characterized by means of X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscope (...The PMA/Eu2O3 porous and layered nanocomposite was prepared by in situ polymerization and characterized by means of X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscope (SEM), and inflared ray (IR). Microscopic investigation of the nanocomposite was carded out by atomic force microscopy (AFM). The results showed that the shape of the composite was layered and porous. Eu2O3 was grafted when methyl acrylate (MA) polymerized; thus Eu2O3 particles appeared on both sides of the chains of polymeric methyl acrylate (PMA).展开更多
HO-PAMAM-2. 5 G-protected lanthanum cluster was studied by Virtual Molecule (VM) software. Molecular dynamics (MD) simulation of the nanocomposite system was performed from the viewpoints of molecular structure an...HO-PAMAM-2. 5 G-protected lanthanum cluster was studied by Virtual Molecule (VM) software. Molecular dynamics (MD) simulation of the nanocomposite system was performed from the viewpoints of molecular structure and energy's fluctuation in NVT system. The motivation of this work was to understand the stability and mechanism of the nanocomposite in different proportion. simulation results reveal that The molecular dynamics when the quantity of La in per HO-PAMAM-2.5G amounted to 0 - 60, the radius of gyration of HO-PAMAM-2.5/La nanocomposite is obviously decreased.展开更多
基金This work was financially supported by the National Natural Science Foundation of China (No. 29875018) the Natural Science Foundation of Gansu Province, China (No. 32S051-A25-050) Gansu Key Laboratory of Polymer Materials, and the Doctorate Foundation of Northwestern Polytechnical University (No. CX200309).
文摘The PMA/Eu2O3 porous and layered nanocomposite was prepared by in situ polymerization and characterized by means of X-ray diffraction (XRD), transmission electron microscopy (TEM), scanning electron microscope (SEM), and inflared ray (IR). Microscopic investigation of the nanocomposite was carded out by atomic force microscopy (AFM). The results showed that the shape of the composite was layered and porous. Eu2O3 was grafted when methyl acrylate (MA) polymerized; thus Eu2O3 particles appeared on both sides of the chains of polymeric methyl acrylate (PMA).
文摘HO-PAMAM-2. 5 G-protected lanthanum cluster was studied by Virtual Molecule (VM) software. Molecular dynamics (MD) simulation of the nanocomposite system was performed from the viewpoints of molecular structure and energy's fluctuation in NVT system. The motivation of this work was to understand the stability and mechanism of the nanocomposite in different proportion. simulation results reveal that The molecular dynamics when the quantity of La in per HO-PAMAM-2.5G amounted to 0 - 60, the radius of gyration of HO-PAMAM-2.5/La nanocomposite is obviously decreased.