The influence of aging on the microstructure and mechanical properties of Cu-11.6wt%Al-3.9wt%Ni-2.5wt%Mn shape memory alloy(SMA) was studied by means of scanning electron microscopy(SEM),transmission electron micr...The influence of aging on the microstructure and mechanical properties of Cu-11.6wt%Al-3.9wt%Ni-2.5wt%Mn shape memory alloy(SMA) was studied by means of scanning electron microscopy(SEM),transmission electron microscopy(TEM),X-ray diffractometer,and differential scanning calorimeter(DSC).Experimental results show that bainite,γ2,and α phase precipitates occur with the aging effect in the alloy.After aging at 300°C,the bainitic precipitates appear at the early stages of aging,while the precipitates of γ2 phase are observed for a longer aging time.When the aging temperature increases,the bainite gradually evolves into γ2 phase and equilibrium α phase(bcc) precipitates from the remaining parent phase.Thus,the bainite,γ2,and α phases appear,while the martensite phase disappears progressively in the alloy.The bainitic precipitates decrease the reverse transformation temperature while the γ2 phase precipitates increase these temperatures with a decrease of solute content in the retained parent phase.On the other hand,these precipitations cause an increasing in hardness of the alloy.展开更多
The kinetic,morphological,crystallographic,and magnetic characteristics of thermally induced martensites in Fe-13.4wt% Mn-5.2wt%Mo alloy were investigated by scanning electron microscopy(SEM),transmission electron m...The kinetic,morphological,crystallographic,and magnetic characteristics of thermally induced martensites in Fe-13.4wt% Mn-5.2wt%Mo alloy were investigated by scanning electron microscopy(SEM),transmission electron microscopy(TEM),and M(o|¨)ssbauer spectroscopy.The experimental results reveal that two types of thermal-induced martensites,e(hcp) andα'(bcc) martensites,are formed in the as-quenched condition,and these transformations have athermal characters.Mo addition to the Fe-Mn alloy does not change the coexistence ofεandα' martensites with the Mn content between 10wt%and 15wt%.Besides,M(o|¨)ssbauer spectra reveal a paramagnetic character with a singlet for theγ(fcc) austenite andεmartensite phases and a ferromagnetic character with a broad sextet for theα' martensite phase. The volume fraction ofα' martensite forming in the quenched alloy is much more than that of theεmartensite.展开更多
文摘The influence of aging on the microstructure and mechanical properties of Cu-11.6wt%Al-3.9wt%Ni-2.5wt%Mn shape memory alloy(SMA) was studied by means of scanning electron microscopy(SEM),transmission electron microscopy(TEM),X-ray diffractometer,and differential scanning calorimeter(DSC).Experimental results show that bainite,γ2,and α phase precipitates occur with the aging effect in the alloy.After aging at 300°C,the bainitic precipitates appear at the early stages of aging,while the precipitates of γ2 phase are observed for a longer aging time.When the aging temperature increases,the bainite gradually evolves into γ2 phase and equilibrium α phase(bcc) precipitates from the remaining parent phase.Thus,the bainite,γ2,and α phases appear,while the martensite phase disappears progressively in the alloy.The bainitic precipitates decrease the reverse transformation temperature while the γ2 phase precipitates increase these temperatures with a decrease of solute content in the retained parent phase.On the other hand,these precipitations cause an increasing in hardness of the alloy.
基金supported by the Kirikkale University Scientific Research Fund(Nos.2008/34 and 2008/35)
文摘The kinetic,morphological,crystallographic,and magnetic characteristics of thermally induced martensites in Fe-13.4wt% Mn-5.2wt%Mo alloy were investigated by scanning electron microscopy(SEM),transmission electron microscopy(TEM),and M(o|¨)ssbauer spectroscopy.The experimental results reveal that two types of thermal-induced martensites,e(hcp) andα'(bcc) martensites,are formed in the as-quenched condition,and these transformations have athermal characters.Mo addition to the Fe-Mn alloy does not change the coexistence ofεandα' martensites with the Mn content between 10wt%and 15wt%.Besides,M(o|¨)ssbauer spectra reveal a paramagnetic character with a singlet for theγ(fcc) austenite andεmartensite phases and a ferromagnetic character with a broad sextet for theα' martensite phase. The volume fraction ofα' martensite forming in the quenched alloy is much more than that of theεmartensite.