A new copper（Ⅱ） complex [Cu2（MNA）2（2,2‘-bipy）2]·2.5H2 O with methy-5-norbornene-2,3-dicarboxylic acid（MNA） and 2,2’-bipyridine as ligands has been synthesized in the mixed solvents of DMF and water.It ...A new copper（Ⅱ） complex [Cu2（MNA）2（2,2‘-bipy）2]·2.5H2 O with methy-5-norbornene-2,3-dicarboxylic acid（MNA） and 2,2’-bipyridine as ligands has been synthesized in the mixed solvents of DMF and water.It crystallizes in monoclinic,space group P 1,with a = 10.4191（11）,b = 12.8883（13）,c = 16.1114（16） A,α = 70.8090（10）,β = 80.568（2）,γ = 77.440（2）o,V = 1984.3（4） A^3,Dc = 1.551 g/cm^3,Z = 2,F（000） = 962,the final GOOF = 1.051,R = 0.0431 and w R= 0.0980.The crystal structure shows that the whole molecule consists of two independent dinuclear units,in which two copper ions are bridged by two μ2-η^1：η^0 3-carboxylate groups of MNA^2-.The coordination environment of Cu（Ⅱ） ion is Cu O3N2,giving a distorted square pyramidal geometry.The spectroscopic characterization,thermal stability and magnetic properties of the complex were investigated.展开更多
A new cobalt-sodium coordination polymer [CoNa（C_9H_9N_3O_2S）_2·H_2O]_2·C_2H_3N·H_2O（1） has been synthesized with cobalt chloride,2-（2-hydroxy-3-methoxybenzylidene）hydrazinecarbothio amide（L） an...A new cobalt-sodium coordination polymer [CoNa（C_9H_9N_3O_2S）_2·H_2O]_2·C_2H_3N·H_2O（1） has been synthesized with cobalt chloride,2-（2-hydroxy-3-methoxybenzylidene）hydrazinecarbothio amide（L） and sodium hydroxide.It crystallizes in the triclinic space group P1,with a = 9.972（4）,b = 10.923（4）,c = 13.489（5） ？,α = 108.005（10）,β = 92.728（10）,γ = 93.16（1）o,V = 1392.0（9） ？~3,Mr = 1151.95,Dc = 1.374 g/cm^3,Z = 2,F（000） = 592,the final GOOF = 1.126,R = 0.1091 and wR = 0.2412.Each unit molecule consists of two cobalt ions and two sodium ions bridged by four 2-（2-hydroxy-3-methoxybenzylidene）hydrazinecarbothio amide anions.The coordination environment of Co ion is CoO_2N_2S_2,giving a distorted octahedral geometry and the Na（1） ion is NaO_4N,giving a distorted square pyramidal geometry.The results show that 1 shows one strong intense fluorescence emission wavelength of 429 nm with an excitation wavelength of 376 nm,and the electron transfer of 1 is irreversible in electrode reactions.展开更多
基金Supported by the Natural Science Foundation of Hunan Province(No.11JJ9006)Key Project of Science and Technology Plan of Hunan Province(2012FJ2002)the Construct Program of the Key Discipline in Hunan Province
文摘A new copper（Ⅱ） complex [Cu2（MNA）2（2,2‘-bipy）2]·2.5H2 O with methy-5-norbornene-2,3-dicarboxylic acid（MNA） and 2,2’-bipyridine as ligands has been synthesized in the mixed solvents of DMF and water.It crystallizes in monoclinic,space group P 1,with a = 10.4191（11）,b = 12.8883（13）,c = 16.1114（16） A,α = 70.8090（10）,β = 80.568（2）,γ = 77.440（2）o,V = 1984.3（4） A^3,Dc = 1.551 g/cm^3,Z = 2,F（000） = 962,the final GOOF = 1.051,R = 0.0431 and w R= 0.0980.The crystal structure shows that the whole molecule consists of two independent dinuclear units,in which two copper ions are bridged by two μ2-η^1：η^0 3-carboxylate groups of MNA^2-.The coordination environment of Cu（Ⅱ） ion is Cu O3N2,giving a distorted square pyramidal geometry.The spectroscopic characterization,thermal stability and magnetic properties of the complex were investigated.
基金Supported by Scientific Research Found of Hunan Provincial Education Department of China(17A049,17C0226)Industry and Research Key Project of Hengyang City(2017KJ155,2017KJ193)Doctoral Scientific Research Foundation of Hengyang Normal University(17D01)
文摘A new cobalt-sodium coordination polymer [CoNa（C_9H_9N_3O_2S）_2·H_2O]_2·C_2H_3N·H_2O（1） has been synthesized with cobalt chloride,2-（2-hydroxy-3-methoxybenzylidene）hydrazinecarbothio amide（L） and sodium hydroxide.It crystallizes in the triclinic space group P1,with a = 9.972（4）,b = 10.923（4）,c = 13.489（5） ？,α = 108.005（10）,β = 92.728（10）,γ = 93.16（1）o,V = 1392.0（9） ？~3,Mr = 1151.95,Dc = 1.374 g/cm^3,Z = 2,F（000） = 592,the final GOOF = 1.126,R = 0.1091 and wR = 0.2412.Each unit molecule consists of two cobalt ions and two sodium ions bridged by four 2-（2-hydroxy-3-methoxybenzylidene）hydrazinecarbothio amide anions.The coordination environment of Co ion is CoO_2N_2S_2,giving a distorted octahedral geometry and the Na（1） ion is NaO_4N,giving a distorted square pyramidal geometry.The results show that 1 shows one strong intense fluorescence emission wavelength of 429 nm with an excitation wavelength of 376 nm,and the electron transfer of 1 is irreversible in electrode reactions.
