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5′-硝基水杨基荧光酮分光光度法测定维生素B_(12)中钴的含量 被引量:2
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作者 汤家华 程乐华 《巢湖学院学报》 2021年第3期78-85,共8页
以5′-硝基水杨基荧光酮(5′-NSAF)为显色剂,建立了分光光度法测定钴的新方法。研究表明:在pH为9.2的NH_(3)·H_(2)O-NH_(4)Cl缓冲介质中,在表面活性剂TritonX-100作用下,钴(Ⅱ)与5′-硝基水杨基荧光酮能生成一种红色配合物,配合物... 以5′-硝基水杨基荧光酮(5′-NSAF)为显色剂,建立了分光光度法测定钴的新方法。研究表明:在pH为9.2的NH_(3)·H_(2)O-NH_(4)Cl缓冲介质中,在表面活性剂TritonX-100作用下,钴(Ⅱ)与5′-硝基水杨基荧光酮能生成一种红色配合物,配合物在546 nm处有最大吸收,表观摩尔吸光系数为3.7×10^(4)L·mol^(-1)·cm^(-1),检出限(3s/k)为5.64×10^(-3)mg/L,钴(Ⅱ)的质量浓度在0~0.5μg/mL范围内与吸光度A有良好的线性关系。方法应用于维生素B_(12)注射液中钴含量的测定,结果满意。 展开更多
关键词 5′-硝基水杨基荧光酮 分光光度法 维生素B_(12)
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Comparative analysis on grain quality and yield of different panicle weight indica-japonica hybrid rice(Oryza sativa L.) cultivars 被引量:10
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作者 BIAN Jin-long REN Gao-lei +6 位作者 HAN Chao XU Fang-fu QIU Shi tang jia-hua ZHANG Hong-cheng WEI Hai-yan GAO Hui 《Journal of Integrative Agriculture》 SCIE CAS CSCD 2020年第4期999-1009,共11页
Indica-japonica hybrid rice(Oryza sativa L.) cultivars showed high yield potential and poor tasting quality when compared with common japonica rice cultivars. Large panicle is a prominent factor of high yield for indi... Indica-japonica hybrid rice(Oryza sativa L.) cultivars showed high yield potential and poor tasting quality when compared with common japonica rice cultivars. Large panicle is a prominent factor of high yield for indica-japonica hybrid rice cultivars, and the panicle weight varies greatly among different indica-japonica hybrid rice cultivars. It is important to research on yield and grain quality of different panicle weight indica-japonica hybrid rice cultivars. In this study, two different panicle types indica-japonica hybrid cultivars were used to research on the relation of yield and grain quality. The yields of two heavy panicle weights indica-japonica hybrid cultivars were significantly higher than that of two medium panicle weight rice cultivars. The cooking and eating quality and starch properties of different panicle type cultivars were evaluated. Yongyou 6715(medium panicle) and Yongyou 1852(heavy panicle) got the relatively higher cooking and eating quality. Rice cultivars with medium panicle weight had more large starch granules and higher relative crystallinity than cultivars with heavy panicle weight. Transition temperature and retrogradation enthalpy(ΔHret) of medium panicle type cultivars were significantly higher than that of heavy panicle type cultivars. There was no significant difference in amylose content among different panicle type cultivars. Protein content of heavy panicle type cultivar was higher than that of medium panicle type cultivar, and protein content is the main factor affect cooking and eating quality in this study. The cultivar Yongyou 6715 got the highest taste value with the lowest protein content. Thus, it is suggested that the emphasis on improving rice cooking and eating quality of indica-japonica hybrid rice cultivars is how to reduce the protein content in rice grain. According to the results of this study, medium panicle type with high grain weight is the desired panicle type for high quality indica-japonica hybrid rice breeding. 展开更多
关键词 YIELD EATING and cooking quality starch AMYLOSE CONTENT protein CONTENT morphology thermal properties
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光度法快速测定食盐中的碘含量
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作者 汤家华 程乐华 《安徽化工》 CAS 2022年第5期107-109,共3页
研究了在磷酸介质中,碘化钾被碘酸钾氧化成单质碘,单质碘与过量的碘化钾反应生成I_(3)^(-),I_(3)^(-)与可溶性淀粉发生反应生成一种蓝色配合物,且显色的程度与IO_(3)^(-)的量成正比,据此建立了光度法测定食盐中碘含量的分析方法。配合... 研究了在磷酸介质中,碘化钾被碘酸钾氧化成单质碘,单质碘与过量的碘化钾反应生成I_(3)^(-),I_(3)^(-)与可溶性淀粉发生反应生成一种蓝色配合物,且显色的程度与IO_(3)^(-)的量成正比,据此建立了光度法测定食盐中碘含量的分析方法。配合物的最大吸收波长为585 nm,碘的含量在0~70μg/25 mL的范围内服从比耳定律,表观摩尔吸光系数为9.68×10^(4)L·mol^(-1)·cm^(-1)。方法的应用范围广,选择性好,灵敏度高,分析成本低,方便快捷,应用于食盐中碘含量测定时,得到了满意的结果。 展开更多
关键词 光度法 快速测定 食盐
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