The slow water dissociation is the rate-determining step that slows down the reaction rate in alkaline hydrogen evolution reaction(HER).Optimizing the surface electronic structure of the catalyst to lower the energy b...The slow water dissociation is the rate-determining step that slows down the reaction rate in alkaline hydrogen evolution reaction(HER).Optimizing the surface electronic structure of the catalyst to lower the energy barrier of water dissociation and regulating the binding strength of adsorption intermediates are crucial strategy for boosting the catalytic performance of HER.In this study,RuO_(2)/BaRuO_(3)(RBRO)heterostructures with abundant oxygen vacancies and lattice distortion were in-situ constructed under a low temperature via the thermal decomposition of gel-precursor.The RBRO heterostructures obtained at 550℃ exhibited the highest HER activity in 1 M KOH,showing an ultra-low overpotential of 16 mV at 10 mA cm^(-2)and a Tafel slope of 33.37 m V dec^(-1).Additionally,the material demonstrated remarkable durability,with only 25 mV of degradation in overpotential after 200 h of stability testing at 10 mA cm^(-2).Density functional theory calculations revealed that the redistribution of charges at the heterojunction interface can optimize the binding energies of H*and OH*and effectively lower the energy barrier of water dissociation.This research offers novel perspectives on surpassing the water dissociation threshold of alkaline HER catalysts by means of a systematic design of heterogeneous interfaces.展开更多
BACKGROUND Granulomatous lobular mastitis(GLM)is a rare benign inflammatory disease of the breast and is classified under comedo mastitis in traditional Chinese medicine(TCM).The etiology of this disease is unknown,an...BACKGROUND Granulomatous lobular mastitis(GLM)is a rare benign inflammatory disease of the breast and is classified under comedo mastitis in traditional Chinese medicine(TCM).The etiology of this disease is unknown,and it mainly occurs in women of childbearing age.The diagnosis depends on histopathological biopsy.At present,there is no systematic and standardized treatment plan for GLM.In the absence of evidence supporting an infectious etiology,affected patients might continue to receive multiple courses of antibiotics and unnecessary surgery.CASE SUMMARY A 37-year-old Chinese woman with a history of coronavirus disease 2019 infection presented with swelling and pain in the left breast.She also had erythema,nodules in the lower extremities,arthritis in both knees,cough,and headache.In the early stage of GLM,the mass was not significantly reduced by conservative treatment with internal application of TCM;hence,surgical treatment was carried out.The aim of postoperative treatment was to drain the pus,eliminate the necrosed tissue,and expand the muscles;fumigation and washing using TCM was applied.CONCLUSION Combined internal and external treatment with TCM,following the principle of“Prioritize internal treatment before ulceration and emphasize external treatment after ulceration”was effective in our patient with GLM.The prognosis was good.We believe that TCM offered valuable therapeutic benefits in this disease.展开更多
基于视觉的手部位姿估计技术应用于诸多领域,具备着广泛的国际应用市场前景和巨大发展潜力。然而,手部自身存在检测目标过小、手指高自由度以及手部自遮挡等问题。通过对目前存在的难点分析,将手部位姿估计任务分为手部检测和手部关键...基于视觉的手部位姿估计技术应用于诸多领域,具备着广泛的国际应用市场前景和巨大发展潜力。然而,手部自身存在检测目标过小、手指高自由度以及手部自遮挡等问题。通过对目前存在的难点分析,将手部位姿估计任务分为手部检测和手部关键点检测,提出基于改进的Faster R-CNN的手部位姿估计方法。首先提出基于改进的Faster R-CNN手部检测网络,将传统Faster R-CNN网络中的对ROI(regional of interest)的最大值池化,更改为ROI Align,并增加损失函数用于区分左右手。在此基础上增加了头网络分支用以训练输出MANO(hand model with articulated and non-rigid deformations)手部模型的姿态参数和形状参数,得到手部关键点三维坐标,最终得到手部的三维位姿估计结果。实验表明,手部检测结果中存在的自遮挡和尺度问题得到了解决,并且检测结果的准确性有所提高,本文手部检测算法准确率为85%,比传统Faster R-CNN算法提升13%。手部关键点提取算法在MSRA、ICVL、NYU三个数据集分别取得关键点坐标的均方误差值(key-point mean square error,KMSE)为7.50、6.32、8.50的结果。展开更多
基金supported by the National Natural Science Foundation of China (21721003,22202080 and 22034006)。
文摘The slow water dissociation is the rate-determining step that slows down the reaction rate in alkaline hydrogen evolution reaction(HER).Optimizing the surface electronic structure of the catalyst to lower the energy barrier of water dissociation and regulating the binding strength of adsorption intermediates are crucial strategy for boosting the catalytic performance of HER.In this study,RuO_(2)/BaRuO_(3)(RBRO)heterostructures with abundant oxygen vacancies and lattice distortion were in-situ constructed under a low temperature via the thermal decomposition of gel-precursor.The RBRO heterostructures obtained at 550℃ exhibited the highest HER activity in 1 M KOH,showing an ultra-low overpotential of 16 mV at 10 mA cm^(-2)and a Tafel slope of 33.37 m V dec^(-1).Additionally,the material demonstrated remarkable durability,with only 25 mV of degradation in overpotential after 200 h of stability testing at 10 mA cm^(-2).Density functional theory calculations revealed that the redistribution of charges at the heterojunction interface can optimize the binding energies of H*and OH*and effectively lower the energy barrier of water dissociation.This research offers novel perspectives on surpassing the water dissociation threshold of alkaline HER catalysts by means of a systematic design of heterogeneous interfaces.
文摘BACKGROUND Granulomatous lobular mastitis(GLM)is a rare benign inflammatory disease of the breast and is classified under comedo mastitis in traditional Chinese medicine(TCM).The etiology of this disease is unknown,and it mainly occurs in women of childbearing age.The diagnosis depends on histopathological biopsy.At present,there is no systematic and standardized treatment plan for GLM.In the absence of evidence supporting an infectious etiology,affected patients might continue to receive multiple courses of antibiotics and unnecessary surgery.CASE SUMMARY A 37-year-old Chinese woman with a history of coronavirus disease 2019 infection presented with swelling and pain in the left breast.She also had erythema,nodules in the lower extremities,arthritis in both knees,cough,and headache.In the early stage of GLM,the mass was not significantly reduced by conservative treatment with internal application of TCM;hence,surgical treatment was carried out.The aim of postoperative treatment was to drain the pus,eliminate the necrosed tissue,and expand the muscles;fumigation and washing using TCM was applied.CONCLUSION Combined internal and external treatment with TCM,following the principle of“Prioritize internal treatment before ulceration and emphasize external treatment after ulceration”was effective in our patient with GLM.The prognosis was good.We believe that TCM offered valuable therapeutic benefits in this disease.
文摘基于视觉的手部位姿估计技术应用于诸多领域,具备着广泛的国际应用市场前景和巨大发展潜力。然而,手部自身存在检测目标过小、手指高自由度以及手部自遮挡等问题。通过对目前存在的难点分析,将手部位姿估计任务分为手部检测和手部关键点检测,提出基于改进的Faster R-CNN的手部位姿估计方法。首先提出基于改进的Faster R-CNN手部检测网络,将传统Faster R-CNN网络中的对ROI(regional of interest)的最大值池化,更改为ROI Align,并增加损失函数用于区分左右手。在此基础上增加了头网络分支用以训练输出MANO(hand model with articulated and non-rigid deformations)手部模型的姿态参数和形状参数,得到手部关键点三维坐标,最终得到手部的三维位姿估计结果。实验表明,手部检测结果中存在的自遮挡和尺度问题得到了解决,并且检测结果的准确性有所提高,本文手部检测算法准确率为85%,比传统Faster R-CNN算法提升13%。手部关键点提取算法在MSRA、ICVL、NYU三个数据集分别取得关键点坐标的均方误差值(key-point mean square error,KMSE)为7.50、6.32、8.50的结果。
