Aiming to the low-grade rhodium-containing waste materials, a new process was proposed to enrich and activate rhodium by smelting using iron oxide as a trapping agent and activator. A rhodium concentrate was obtained ...Aiming to the low-grade rhodium-containing waste materials, a new process was proposed to enrich and activate rhodium by smelting using iron oxide as a trapping agent and activator. A rhodium concentrate was obtained by the separation of base metals and precious metals. The concentrate was reacted with dilute aqua regia to obtain rhodium solution. The factors influencing the enrichment and activation effects were discussed in this paper. The results showed that the dissolution rate is greater than 99% under the optimum conditions. In this process, the activation of rhodium was finished in the enrichment process. The iron oxide is both a trapping agent and activator, which simplifies the process and reduce the cost.展开更多
On the basis of reviewing the progress in the high efficient enrichment from secondary resources of low grade precious metals at home and abroad, a process route of the high efficient enrichment precious metals from s...On the basis of reviewing the progress in the high efficient enrichment from secondary resources of low grade precious metals at home and abroad, a process route of the high efficient enrichment precious metals from secondary resources of low-grade metals by adding iron oxide as the trapping agent, reducing agent, additive, mixing uniformly and grinding, pelletizing, reduction, grinding and separation, and selectively acid leaching iron has been put forward in this paper. The experiments of reduction, grinding and separation, and selectively acid leaching iron were carried out mainly. Under the decided experiment parameters and conditions, iron generated during the reduction can trap precious metals during reduction, high active alloy powders were obtained from the reduced products by grinding and separation, the concentration of precious metals was obtained by acid leaching high active alloy powders. The better enrichment effect was obtained by adopting the technical route of processing. Other low grade noble metal materials and enrichment ratio of precious metals from the materials to acid products was high through acid leaching. This process has the advantages of simple process, environmental-friendly, strong adaptability of raw materials, high concentration ratio, which was regarded as a kind of the general efficient enrichment technology of low grade precious metal materials.展开更多
基金The Nationa lBasic Research Program(973Plan)of China(2010CB735501)
文摘Aiming to the low-grade rhodium-containing waste materials, a new process was proposed to enrich and activate rhodium by smelting using iron oxide as a trapping agent and activator. A rhodium concentrate was obtained by the separation of base metals and precious metals. The concentrate was reacted with dilute aqua regia to obtain rhodium solution. The factors influencing the enrichment and activation effects were discussed in this paper. The results showed that the dissolution rate is greater than 99% under the optimum conditions. In this process, the activation of rhodium was finished in the enrichment process. The iron oxide is both a trapping agent and activator, which simplifies the process and reduce the cost.
基金The National Basic Research Program( 973 Plan) of China(2012CB724201)
文摘On the basis of reviewing the progress in the high efficient enrichment from secondary resources of low grade precious metals at home and abroad, a process route of the high efficient enrichment precious metals from secondary resources of low-grade metals by adding iron oxide as the trapping agent, reducing agent, additive, mixing uniformly and grinding, pelletizing, reduction, grinding and separation, and selectively acid leaching iron has been put forward in this paper. The experiments of reduction, grinding and separation, and selectively acid leaching iron were carried out mainly. Under the decided experiment parameters and conditions, iron generated during the reduction can trap precious metals during reduction, high active alloy powders were obtained from the reduced products by grinding and separation, the concentration of precious metals was obtained by acid leaching high active alloy powders. The better enrichment effect was obtained by adopting the technical route of processing. Other low grade noble metal materials and enrichment ratio of precious metals from the materials to acid products was high through acid leaching. This process has the advantages of simple process, environmental-friendly, strong adaptability of raw materials, high concentration ratio, which was regarded as a kind of the general efficient enrichment technology of low grade precious metal materials.