越南西北部Pu Sam Cap高钾碱性杂岩位于哀牢山剪切带南段西侧,由粗面岩、煌斑岩、碱性正长岩与碱性花岗岩组成。其中粗面岩不整合于晚白垩世陆相沉积岩之上,碱性侵入岩侵入到三叠纪陆源沉积岩、侏罗纪流纹岩及40～35Ma含角闪石二长岩-...越南西北部Pu Sam Cap高钾碱性杂岩位于哀牢山剪切带南段西侧,由粗面岩、煌斑岩、碱性正长岩与碱性花岗岩组成。其中粗面岩不整合于晚白垩世陆相沉积岩之上,碱性侵入岩侵入到三叠纪陆源沉积岩、侏罗纪流纹岩及40～35Ma含角闪石二长岩-花岗岩中。该杂岩的岩石具有低TiO2(<0.8%)、P2O5(<0.64%)和FeO*(<7.74%),高Na2O(1.41%～4.5%)和K2O(5.22%～9.4%)的地球化学属性,属于高钾碱性玄武质到高钾碱性长英质岩浆岩类型与钾质至超钾质岩浆系列。这套岩石富集大离子亲石元素LILE、轻稀土元素LREE和一组相容元素,具有明显的Ta、Nb和Ti异常,表明Pu Sam Cap高钾碱性杂岩形成于与俯冲带有关的大陆弧和后碰撞弧构造环境。锆石LA-ICPMS U-Pb年代学研究表明碱性正长岩与碱性花岗岩分别形成于32.70±0.24Ma、35.1±0.06Ma,上述年龄代表了Pu Sam Cap高钾碱性杂岩的侵入岩结晶年龄。两个样品中锆石的εHf(t)变化范围分别为-2.8～2.5和-4.9～0.1,在t-εHf(t)相关图上分析点落在下地壳和亏损地幔演化线之间,两阶段模式年龄变化范围为950～1286Ma和1107～1421Ma。该杂岩的εNd(t)变化范围-5.63～-3.26,具有低143Nd/144Nd比值(0.512336～0.512447)和高87Sr/86Sr比值(0.706254～0.707273),Sr-Nd同位素相关图上接近于EM2地幔端元趋势线,与大理地区新生代高钾岩浆岩十分相似,表明PuSamCap高钾碱性杂岩的岩浆是幔源岩浆和壳源岩浆的混合结果,同时可与大理地区新生代高钾岩浆岩对比,它们形成于哀牢山-红河左行走滑活动之前,墨江古特提斯洋盆的消减与印度-欧亚陆陆碰撞活动提供了宏观区域性构造背景。展开更多
The Sin Quyen-Lung Po district is an important Cu metallogenic province in Vietnam, but there are few temporal and genetic constraints on deposits from this belt. Suoi Thau is one of the representative Cu deposits ass...The Sin Quyen-Lung Po district is an important Cu metallogenic province in Vietnam, but there are few temporal and genetic constraints on deposits from this belt. Suoi Thau is one of the representative Cu deposits associated with granitic intrusion. The deposit consists of ore bodies in altered granite or along the contact zone between granite and Proterozoic meta-sedimentary rocks. The Cu-bearing intrusion is sub-alkaline I-type granite. It has a zircon U-Pb age of ~776 Ma, and has subduction-related geochemical signatures. Geochemical analysis reveals that the intrusion may be formed by melting of mafic lower crust in a subduction regime. Three stages of alteration and mineralization are identified in the Suoi Thau deposit, i.e., potassic alteration; silicification and Cu mineralization; and phyllic alteration. Two-phase aqueous fluid inclusions in quartz from silicification stage show wide ranges of homogenization temperatures （140-383℃） and salinities （4.18wt%- 19.13wt%）. The high temperature and high salinity natures of some inclusions are consistent with a magmatic derivation of the fluids, which is also supported by the H-O-S isotopes. Fluids in quartz have JD values of-41.9‰ to -68.8%. The fluids in isotopic equilibrium with quartz have j180 values ranging from 7.9‰ to 9.2%. These values are just plotted in the compositional field of magmatie- hydrothermal fluids in the ~Dwater versus jlSOwater diagram. Sulfide minerals have relatively uniform j34S values from 1.84%o to 3.57%0, which is supportive of a magmatic derivation of sulfur. The fluid inclusions with relatively low temperatures and salinities most probably represent variably cooled magmatic-hydrothermal fluids. The magmatic derivation of fluids and the close spatial relationship between Cu ore bodies and intrusion suggest that the Cu mineralization most likely had a genetic association with granite. The Suoi Thau deposit, together with other deposits in the region, may define a Neoproterozoic subduction-related ore-forming belt.展开更多
文摘越南西北部Pu Sam Cap高钾碱性杂岩位于哀牢山剪切带南段西侧,由粗面岩、煌斑岩、碱性正长岩与碱性花岗岩组成。其中粗面岩不整合于晚白垩世陆相沉积岩之上,碱性侵入岩侵入到三叠纪陆源沉积岩、侏罗纪流纹岩及40～35Ma含角闪石二长岩-花岗岩中。该杂岩的岩石具有低TiO2(<0.8%)、P2O5(<0.64%)和FeO*(<7.74%),高Na2O(1.41%～4.5%)和K2O(5.22%～9.4%)的地球化学属性,属于高钾碱性玄武质到高钾碱性长英质岩浆岩类型与钾质至超钾质岩浆系列。这套岩石富集大离子亲石元素LILE、轻稀土元素LREE和一组相容元素,具有明显的Ta、Nb和Ti异常,表明Pu Sam Cap高钾碱性杂岩形成于与俯冲带有关的大陆弧和后碰撞弧构造环境。锆石LA-ICPMS U-Pb年代学研究表明碱性正长岩与碱性花岗岩分别形成于32.70±0.24Ma、35.1±0.06Ma,上述年龄代表了Pu Sam Cap高钾碱性杂岩的侵入岩结晶年龄。两个样品中锆石的εHf(t)变化范围分别为-2.8～2.5和-4.9～0.1,在t-εHf(t)相关图上分析点落在下地壳和亏损地幔演化线之间,两阶段模式年龄变化范围为950～1286Ma和1107～1421Ma。该杂岩的εNd(t)变化范围-5.63～-3.26,具有低143Nd/144Nd比值(0.512336～0.512447)和高87Sr/86Sr比值(0.706254～0.707273),Sr-Nd同位素相关图上接近于EM2地幔端元趋势线,与大理地区新生代高钾岩浆岩十分相似,表明PuSamCap高钾碱性杂岩的岩浆是幔源岩浆和壳源岩浆的混合结果,同时可与大理地区新生代高钾岩浆岩对比,它们形成于哀牢山-红河左行走滑活动之前,墨江古特提斯洋盆的消减与印度-欧亚陆陆碰撞活动提供了宏观区域性构造背景。
基金supported by Vietnam National Foundation for Science and Technology Development under grant number 105.01–2012.06supported by Ministry of Natural Resources and Environment of The Socialist Republic of Vietnam for Science and Technology Development,Project TNMT.03.50 to Tran My Dung+1 种基金National Key Basic Research and Development(973)Project of China(2015CB452600)China Geological Survey(1212011120343)
文摘The Sin Quyen-Lung Po district is an important Cu metallogenic province in Vietnam, but there are few temporal and genetic constraints on deposits from this belt. Suoi Thau is one of the representative Cu deposits associated with granitic intrusion. The deposit consists of ore bodies in altered granite or along the contact zone between granite and Proterozoic meta-sedimentary rocks. The Cu-bearing intrusion is sub-alkaline I-type granite. It has a zircon U-Pb age of ~776 Ma, and has subduction-related geochemical signatures. Geochemical analysis reveals that the intrusion may be formed by melting of mafic lower crust in a subduction regime. Three stages of alteration and mineralization are identified in the Suoi Thau deposit, i.e., potassic alteration; silicification and Cu mineralization; and phyllic alteration. Two-phase aqueous fluid inclusions in quartz from silicification stage show wide ranges of homogenization temperatures （140-383℃） and salinities （4.18wt%- 19.13wt%）. The high temperature and high salinity natures of some inclusions are consistent with a magmatic derivation of the fluids, which is also supported by the H-O-S isotopes. Fluids in quartz have JD values of-41.9‰ to -68.8%. The fluids in isotopic equilibrium with quartz have j180 values ranging from 7.9‰ to 9.2%. These values are just plotted in the compositional field of magmatie- hydrothermal fluids in the ~Dwater versus jlSOwater diagram. Sulfide minerals have relatively uniform j34S values from 1.84%o to 3.57%0, which is supportive of a magmatic derivation of sulfur. The fluid inclusions with relatively low temperatures and salinities most probably represent variably cooled magmatic-hydrothermal fluids. The magmatic derivation of fluids and the close spatial relationship between Cu ore bodies and intrusion suggest that the Cu mineralization most likely had a genetic association with granite. The Suoi Thau deposit, together with other deposits in the region, may define a Neoproterozoic subduction-related ore-forming belt.
