Full-scale model tests were carried out on a 30 m span prestressed concrete box girder and a 20 m span prestressed concrete hollow slab. Failure models were prestressed reinforcement tensile failure and crushing of ro...Full-scale model tests were carried out on a 30 m span prestressed concrete box girder and a 20 m span prestressed concrete hollow slab. Failure models were prestressed reinforcement tensile failure and crushing of roof concrete,respectively. The ductility indexes of the box girder and hollow slab were 1.99 and 1.23, respectively,according to the energy viewpoint. Based on the horizontal section hypothesis,the nonlinear computation procedure was established using the limited banding law,and it could carry out the entire performance analysis including the unloading,mainly focusing on the ways to achieve the unloading curves computation through stress-strain,moment-curvature and load-displacement curves. Through the procedure,parameters that influence on the bearing capacity,deformation performance and ductility of the structures were analyzed. Those parameters were quantity of prestressed reinforcement and tension coefficients of prestressed reinforcement. From the analysis,some useful conclusions can be obtained.展开更多
以[^(14)C]碳酸钡为放射性同位素原料,通过乙炔环三聚、苯羧基化和甲基化、胺化、环化、亲核取代、格氏、还原、氧化等反应和反相高效液相色谱(HPLC)纯化获得了2种放射性同位素碳-14标记毒氟磷[N-[2-(4-甲基[苯基-U-^(14)C_6]苯并噻唑基...以[^(14)C]碳酸钡为放射性同位素原料,通过乙炔环三聚、苯羧基化和甲基化、胺化、环化、亲核取代、格氏、还原、氧化等反应和反相高效液相色谱(HPLC)纯化获得了2种放射性同位素碳-14标记毒氟磷[N-[2-(4-甲基[苯基-U-^(14)C_6]苯并噻唑基)]-2-氨基-2-氟苯基-O,O-二乙基甲基膦酸酯(2,20.6 m Ci)和N-[2-(4-甲基苯并噻唑基)]-2-氨基-2-氟苯基-O,O-二乙基[^(14)C]甲基膦酸酯(3,32.4 m Ci)],其结构经核磁共振氢谱(~1H NMR)和在线放射性高效液相色谱-二极管阵列检测器/质谱联用(HPLC-FSA/PDA/MS)分析确认,反应总放化收率/化学收率分别为31%和67%.放射性薄层层析-同位素成像分析(TLC-IIA)、离线放射性高效液相色谱(HPLC-LSC),HPLC-FSA/PDA/MS和液体闪烁测量(LSC)分析表明,两种标记物的放化纯度和化学纯度均大于98%,比活度分别为25.5,55.5 m Ci/mmol.该标记物可作为放射性示踪剂,用于毒氟磷的代谢、残留和环境行为等研究.展开更多
基金National Natural Science Foundation of China(No.50678063)
文摘Full-scale model tests were carried out on a 30 m span prestressed concrete box girder and a 20 m span prestressed concrete hollow slab. Failure models were prestressed reinforcement tensile failure and crushing of roof concrete,respectively. The ductility indexes of the box girder and hollow slab were 1.99 and 1.23, respectively,according to the energy viewpoint. Based on the horizontal section hypothesis,the nonlinear computation procedure was established using the limited banding law,and it could carry out the entire performance analysis including the unloading,mainly focusing on the ways to achieve the unloading curves computation through stress-strain,moment-curvature and load-displacement curves. Through the procedure,parameters that influence on the bearing capacity,deformation performance and ductility of the structures were analyzed. Those parameters were quantity of prestressed reinforcement and tension coefficients of prestressed reinforcement. From the analysis,some useful conclusions can be obtained.
文摘以[^(14)C]碳酸钡为放射性同位素原料,通过乙炔环三聚、苯羧基化和甲基化、胺化、环化、亲核取代、格氏、还原、氧化等反应和反相高效液相色谱(HPLC)纯化获得了2种放射性同位素碳-14标记毒氟磷[N-[2-(4-甲基[苯基-U-^(14)C_6]苯并噻唑基)]-2-氨基-2-氟苯基-O,O-二乙基甲基膦酸酯(2,20.6 m Ci)和N-[2-(4-甲基苯并噻唑基)]-2-氨基-2-氟苯基-O,O-二乙基[^(14)C]甲基膦酸酯(3,32.4 m Ci)],其结构经核磁共振氢谱(~1H NMR)和在线放射性高效液相色谱-二极管阵列检测器/质谱联用(HPLC-FSA/PDA/MS)分析确认,反应总放化收率/化学收率分别为31%和67%.放射性薄层层析-同位素成像分析(TLC-IIA)、离线放射性高效液相色谱(HPLC-LSC),HPLC-FSA/PDA/MS和液体闪烁测量(LSC)分析表明,两种标记物的放化纯度和化学纯度均大于98%,比活度分别为25.5,55.5 m Ci/mmol.该标记物可作为放射性示踪剂,用于毒氟磷的代谢、残留和环境行为等研究.
