Negative thermal expansion and phase transition of low-temperature Mg_(2)NiH_(4)

The negative thermal expansion(NTE) phenomenon is of great significance in fabricating zero thermal expansion(ZTE) materials to avoid thermal shock during heating and cooling. NTE is observed in limited groups of materials, e.g., metal cyanides, oxometallates, and metalorganic frameworks, but has not been reported in the family of metal hydrides. Herein, a colossal and continuous negative thermal expansion is firstly developed in the low-temperature phases of LT1-and LT2-Mg_(2)NiH_(4) between 488 K and 733 K from in-situ transmission electron microscope(TEM) video, with the volume contraction reaching 18.7% and 11.3%, respectively. The mechanisms for volume contraction of LT1 and LT2 phases are elucidated from the viewpoints of phase transformation, magnetic transition, and dehydrogenation, which is different from common NTE materials containing flexible polyhedra units in the structure. The linear volume shrinkage of LT2 in the temperature of 488-553 K corresponds to the phase transition of LT2→HT with a thermal expansion coefficient of -799.7 × 10^(-6) K^(-1) revealed by in-situ synchrotron powder X-ray diffraction. The sudden volume contraction in LT1 between 488 and 493 K may be caused by the rapid dehydrogenation of LT1 to Mg_(2)Ni. The revealed phenomenon in single composite material with different structures would be significant for preparing zero thermal expansion materials by tuning the fraction of LT1 and LT2 phases.

Catalytic effect of Ni@rGO on the hydrogen storage properties of MgH2

Uniform-uispersed Ni nanoparticics(NPs)anchored on reduced graphene oxide(Ni@rGO)catalyzed MgH2(MH-Ni@rGO)has been fabricated by mechanical milling.The effects of milling time and Ni loading amount on the hydrogen storage properties of MgH2 have been investigated.The initial hydrogen desorption temperature of MgH2 catalyzed by 10 wt.%Ni4@rGO6 for milling 5 h is significantly decreased from 251℃ to 190℃.The composite can absorb 5.0 wt.%hydrogen in 20 min at 100℃,while it can desorb 6.1 wt.%within 15 min at 300℃.Through the investigation of the phase transformation and dehydrogenation kinetics during hydrogen ab/desorption cycles,we found that the in-situ formed Mg2Ni/Mg2NiH4 exhibited better catalytic effect than Ni.When Ni loading amount is 45 wt.%,the rGO in Ni@rGO catalysts can prevent the reaction of Ni and Mg due to the strong interaction between rGO and Ni NPs.

The degradation of cathodic Fe/N/C catalyst in PEMFCs:The evolution of remanent active sites after demetallation

The state-of-the-art Fe/N/C catalyst has presented comparable initial cathode performance to the benchmark Pt/C catalyst in proton exchange membrane fuel cells(PEMFCs).However,the major bottleneck is its significant activity decay in real-world PEMFC cells.The superposed“fast decay”and“slow decay”have been well documented to describe the degradation process of Fe/N/C catalysts during PEMFC operation.The fast decay has been well understood in close relation to the demetallation at the initial 15-h stability test.Nevertheless,it is still unclear how the remanent active sites evolve after demetallation.To this end,the catalyst performance and evolution of a typical Fe/N/C active site were herein investigated through postmortem characterizations of the membrane electrode assemblies(MEAs)after different operations.It is presented that 1 bar pressure and 80℃ temperature are the optimized conditions for Fe/N/C MEA.Particularly,the“fast decay”in the initial 15 h is immune to the various operating parameters,while the“slow decay”highly depends on the applied temperature and pressure.According to the X-ray absorption spectra(XAS)analysis and stability test of MEA,the gradual evolution of Fe-N coordination to Fe-O is found correlated with the“slow decay”and accounts for the catalyst decay after the demetallation process.

Effect of ozonated water on normal vaginal microecology and Lactobacillus

To the Editor:The female vagina is a complex microecology system.Generally,the vaginal microbiota of healthy women is dominated by H2O2-producing Lactobacillus,which decomposes glycogen in vaginal epithelial cells into lactic acid,maintaining the normal acidic environment of the vagina.

Research on the big data of traditional taxi and online car-hailing:A systematic review

The purpose of this paper is to provide a summary of a quick overview of the latest developments and unprecedented opportunities for scholars who want to set foot in the field of traditional taxi and online car-hailing(TTOC).From the perspectives of peoples(e.g.,passenger,driver,and policymaker),vehicle,road,and environment,this paper describes the current research status of TTOC's big data in six hot topics,including the ridership factor,spatio-temporal distribution and travel behavior,cruising strategy and passenger service market partition,route planning,transportation emission and new-energy,and TTOC's data extensional application.These topics were included in five mainstreams as follows:(1)abundant studies often focus only on determinant analysis on given transportation(taxi,transit,online car-hailing);the exploration of ridership patterns for a multimodal transportation mode is rare;furthermore,multiple aspects of factors were not considered synchronously in a wide time span;(2)travel behavior research mainly concentrates on the commuting trips and distribution patterns of various travel indices(e.g.,distance,displacement,time);(3)the taxi driver-searching strategy can be divided into autopsychic cruising and system dispatching;(4)the spatio-temporal distribution character of TTOC's fuel consumption(FC)and greenhouse gas(GHG)emissions has become a hotspot recently,and there has been a recommendation for electric taxi(ET)in urban cities to decrease transportation congestion is proposed;and(5)based on TTOC and point of interest(POI)multi-source data,many machine learning algorithms were used to predict travel condition indices,land use,and travel behavior.Then,the main bottlenecks and research directions that can be explored in the future are discussed.We hope this result can provide an overview of current fundamental aspects of TTOC's utilization in the urban area.

Comment： Closing phosphorus cycle from natural waters： re-capturing phosphorus through an integrated water-energy-food strategy

Phosphorus （P） reserve, largely derived from phosphate rock, is essential for crop growth to support the growing world population. However, a significant proportion of phosphorus used as a fertilizer runs into natural waters, causing eutro- phication and ecological damage. Moreover, most P in the food is eventually discharged as waste after being digested by human and animals. Thus, industrial activities have created a one-way flow of non-renewable P from rocks to farms to lakes, rivers and oceans.

Utilization of hepatitis B virus-positive allografts in liver transplantation:a new arrow to the bowstring for expanding the donor pool?

Liver disease accounts for approximately 2 million deaths per year worldwide,including 1 million due to complications of cirrhosis and 1 million due to viral hepatitis and hepatocellular carcinoma(HCC)(1).Liver transplantation(LTx)is the definitive management for end-stage liver disease and HCC in both children and adults.However,the number of liver transplant candidates on the waiting list exceeds that of available allografts.Approximately one-third of the global population has serological evidence of past or current hepatitis B virus(HBV)infection,including 250 million people with chronic HBV infection.The concept of using HBV-positive liver allografts has been implemented to expand the organ pool worldwide(2).Especially in regions with high or intermediate prevalence of HBV infection,these allografts can be an optimal choice for LTx recipients.Over the decades,LTx from HBV-exposed allografts has shifted from the first case in the 1980s to expanded practice supported by positive outcomes,particularly with the availability of safe and effective clinical therapies(3).