Precise carbon structure control by salt template for high performance sodium-ion storage

Carbon materials are considered to be one of the most promising anode materials for sodium-ion batteries(SIBs),but the well-ordered graphitic structure limits the intercalation of sodium ions.Besides,the sluggish intercalation kinetics of sodium ions impedes the rate performance.Thus,the precise structure control of carbon materials is important to improve the battery performance.Herein,a 3D porous hard-soft composite carbon(3DHSC)was prepared using the NaCl as the template and phenolic resin and pitch as carbon precursors.The NaCl template restrains the growth of the graphite crystallite during the carbonization process,resulting in small graphitic domains with expanded interlayer spacing which is favorable for the sodium storage.Moreover,the Na Cl templates help to create abundant mesopores and macropores for fast sodium ion diffusion.The porous structure and the graphite crystalline structure can be precisely controlled by simply adjusting the mass ratio of Na Cl,and thus,the suitable structure can be prepared to reach high capacity and rate performance while keeping a relatively high Coulombic efficiency.Typically,a high reversible capacity(215 mA h g^(-1)at 0.05 A g^(-1)),an excellent rate capability(97 mA h g^(-1)at 5 A g^(-1)),and a high initial Coulombic efficiency(60%)are achieved.

Intelligent Task Offloading and Collaborative Computation over D2D Communication

In this paper,the problem of computation offloading in the edge server is studied in a mobile edge computation(MEC)-enabled cell networks that consists of a base station(BS)integrating edge servers,several terminal devices and collaborators.In the considered networks,we develop an intelligent task offloading and collaborative computation scheme to achieve the optimal computation offloading.First,a distance-based collaborator screening method is proposed to get collaborators within the distance threshold and with high power.Second,based on the Lyapunov stochastic optimization theory,the system stability problem is transformed into a queue stability issue,and the optimal computation offloading is obtained by solving these three sub-problems:task allocation control,task execution control and queue update,respectively.Moreover,rigorous experimental simulation shows that our proposed computation offloading algorithm can achieve the joint optimization among the system efficiency,energy consumption and time delay compared to the mobility-aware and migration-enabled approach,Full BS and Full local.

Structural superlubricity at homogenous interface of pentagraphene

Two-dimensional(2D)van der Waals layered materials have been widely used as lubricant.Penta-graphene(PG),a 2D carbon allotrope exclusively composed of irregular carbon pentagons has recently been predicted to have superlubricating property.In the present study,by combining the molecular dynamics simulation and first-principles calculations,we investigated the frictional property of PG in both commensurate and incommensurate contacts.Our calculations show the ultra-low friction at the interface of relatively rotated bilayer PG with twist angles of more than 10°away from the commensurate configuration.Meanwhile,our calculations demonstrate the isotropy of the ultra-low friction at the interface of incommensurate contact,in contrast to the anisotropic of the commensurate contacting interface.Additionally,the evolution of friction force and the fluctuation of potential energy along sliding path correlate closely with the interface’s structure.The energetics and charge density explain the difference between the friction at the interfaces of the commensurate and incommensurate contacts.Not only that,we found the correlation between the intrinsic structural feature and interlayer binding energy.Importantly,our findings on the retainment of the ultra-low friction under work conditions indicates that the superlubricating state of PG has good practical adaptability.

Fast three-dimensional assembly of MoS_2 inspired by the gelation of graphene oxide

Two-dimensional (2D) materials, such as graphene, transition metal dichalcogenides (TMDs) and MXene [1-5], have attracted great attention in various applications due to their unique electronic properties, large surface area and sheet-like structure. However, the severe aggregation of the nanosheets (NSs) leads to the loss of accessible surface area and high ion diffusion resistance in practical uses.