Fine Particulate Matter and Heavy Metals Pollution Status in Ambient Air of Some Selected Industrial Sites in Northern Nigeria

Fine particulate matter and eight heavy metals (Ni, Co, Cu, Pb, Cd, Cr, Mn, and Zn) concentrations were determined in air samples collected from three industrial sites in northern Nigeria using a Handheld Portable Particle Counter for PM2.5 and PM10 with model number CW-HAT 200 and a High Volume Respirable Dust Sampler (APM 460 NL) in conjunction with an Atomic Absorption Spectrophotometer (Serial No. AA0904M046) Flame Test. The results of the fine particulates ranged from 11.0 - 46.0 μg.m-3 for PM2.5 and 22.0 - 88 μg.m-3 for PM10 across all the industrial sites investigated. Most of these results exceeded the WHO permissible levels of 25.0 μg.m-3 and 50.0 μg.m-3 for PM2.5 and PM10 and thus pose threats to people living and working close to these sites. The concentration of the heavy metals studied were found to be within WHO/EU set standards except for the concentrations of Ni, Pb, and Cd that exceeded the set standard by WHO/EU with toxicity potential >1 in the Terytex industry, Kano and Grand Cereals, Jos. Strong positive correlations were found between the fine particulates concentrations and heavy metals in all the studied sites suggesting that common anthropogenic sources contributed to the fine particulates and heavy metals recorded from the industrial areas. We suggested the installation of electrostatic precipitators to combat fine particulates emission from the stack and also recommended a proper legislative framework by the government to regulate and control industrial fugitive emissions to protect human health.

Assessment of Radionuclide Content of Shore Sediments Collected from the Bank of River Benue, North-Central Nigeria

Ionizing Radiation emitted from radionuclide has an adverse effect on human health. A continuing population exposure to naturally occurring radioactive materials (NORMS) found in our environment is one of the major scientific subjects that attract public attention. The assessment of radionuclide content of shore sediments of river Benue-North Central Nigeria was carried out using gamma-ray spectrometry. The activity concentrations of U-238, Th-232 and K-40 were found to have an average concentration of 1.17, 3.31 and 405.95 Bq·kg-1 respectively. The values gotten from present study were compared with the world average values. World average values of U-238, Th-232 and K-40 are 50 Bq·kg-1, 50 Bq·kg-1 and 500 Bq·kg-1 respectively. The mean concentration of daughter radionuclides generated from U-238, Th-232 was 4.32, 10.37, 5.24, 3.86, 11.87, and 6.52 for Bi-212, Pb-212, Bi-214, Pb-214, Ra-226 and Ac-228, respectively. The mean of the absorbed dose, Annual effective dose equivalent, for radium equivalent activity, and external hazard index, were evaluated to be 19.45 nGy·h-1, 23.82 μSv·y-1, 37.16 Bq·kg-1, 0.10 mSv·y1, below the permissible limit of 57 nGy·h-1, 70 μSv·y-1, 370 Bq·kg-1 and 1 mSv·y-1 respectively. These shore sediments from river Benue are therefore, radiologically safe for construction and other domestic and industrial purposes.

Assessment of Heavy Metals Concentration in Shore Sediments from the Bank of River Benue, North-Central Nigeria

Heavy metals are elements, whose density is greater than water. They are generated from our environment. Rocks, sediments, plants, water and aerosol particles represent the carriers of heavy metals. An accumulated amount of heavy metal in the body, either by inhalation, food or drinking water, can cause an adverse health effect to human. The Benue river passed through the town of makurdi, was high population of the inhabitant of Benue State dwells. The industrial and agricultural activities carried out in this region, increase the concentration of heavy metals. This may result to adverse health effect on the inhabitant of Makurdi. The objectives of this work were to determine the heavy metal concentration and its site contaminations along the bank of river Benue, Makurdi. An inductively coupled plasma optical emission spectrometry (ICP-OES) was used to determine the heavy metals concentration. The metals concentrations (Iron, Copper, Manganese, Lead, Zinc, Chromium, Arsenic, and Cadmium) of the three stations were found. This ranges from 3.55 - 9454.0 mg/kg, 0.20 - 8928.0 mg/kg and 2.80 - 13,657 mg/kg for stations 1, 2 and 3. With Fe recorded as the highest concentration in the sediment, this value is compared with the World Health Organisation (WHO) and World Surface Rock Average (WSRA) standard. The assessment on contamination status of heavy metals in the riverbank, showed low degree of contamination in stations 1 and 2, and moderate degree in station 3. The degree of enrichment to heavy metals in all the stations is deficient to minimal. The evaluation of the results of pollution load index (PLI) from this present study indicated PLI 1 in stations 1 and 3. Hence stations 1 and 3 are polluted, while station 2 is not polluted with heavy metals.