采用无水乙醇浸渍法和水溶液离子交换法制备了锆改性Y型分子筛,通过X射线粉末衍射(XRD)、氮气吸附-脱附,固体核磁共振(^(27 )Al MAS NMR)、傅里叶红外光谱(FT-IR)等手段进行表征。结果表明:所制备的锆改性Y型分子筛具有较好的微孔结构...采用无水乙醇浸渍法和水溶液离子交换法制备了锆改性Y型分子筛,通过X射线粉末衍射(XRD)、氮气吸附-脱附,固体核磁共振(^(27 )Al MAS NMR)、傅里叶红外光谱(FT-IR)等手段进行表征。结果表明:所制备的锆改性Y型分子筛具有较好的微孔结构和较高的水热稳定性,锆很难与分子筛骨架铝发生同晶置换作用;采用无水乙醇浸渍法更有利于锆进入分子筛孔道中与骨架铝氧四面体相互作用,所制备的分子筛具有更高的结晶度和比表面积,更好的水热稳定性;含有锆改性Y型分子筛的裂化催化剂具有较高的重油转化能力和汽油收率,抗重金属污染能力强。展开更多
A novel heavy oil catalytic cracking catalyst RCC-1 was developed by using the ultra-stable zeolite, which was hydrothermally treated and modified through cleaning its pores to serve as the active component. The chemi...A novel heavy oil catalytic cracking catalyst RCC-1 was developed by using the ultra-stable zeolite, which was hydrothermally treated and modified through cleaning its pores to serve as the active component. The chemical composition and physicochemical properties of RCC-1 catalyst were studied by XRF, BET, pore volume analysis, attrition index analysis, and particle size distribution determination methods, and its catalytic cracking performance was also evaluated by a microreactor for light oil cracking and the ACE device. The test results showed that the new type of heavy oil catalytic cracking catalyst RCC-1 had good physicochemical properties and heavy oil cracking ability, strong anti-metallic contamination capability, good product distribution, good coke selectivity and gasoline selectivity, and excellent reduction of gasoline olefin content characteristics.展开更多
In the past several decades,SINOPEC has devoted continuously great efforts to the development of DCC technology,the only commercial process using heavy feeds aiming at propylene production.Recently,a series of researc...In the past several decades,SINOPEC has devoted continuously great efforts to the development of DCC technology,the only commercial process using heavy feeds aiming at propylene production.Recently,a series of research breakthroughs have been achieved in molecular refining.Based on the detailed analysis on the complex DCC reaction network,an innovative catalyst technology has been developed to Optimize Catalysis Kinetics (OCK in brief).The deep-cracking process can be improved with optimizing the availability of the active sites.The updated MFI and beta zeolites are used to boost the propylene selectivity.The latest generation catalyst DMMC-1 has been applied commercially.Compared with the best historical records in the past,the propylene yield upon application of the catalyst DMMC-1 increases by 2.4 m% coupled with an improved distribution of products.The DCC technology continues to assume a leading position for manufacturing propylene from heavy feedstocks.展开更多
文摘采用无水乙醇浸渍法和水溶液离子交换法制备了锆改性Y型分子筛,通过X射线粉末衍射(XRD)、氮气吸附-脱附,固体核磁共振(^(27 )Al MAS NMR)、傅里叶红外光谱(FT-IR)等手段进行表征。结果表明:所制备的锆改性Y型分子筛具有较好的微孔结构和较高的水热稳定性,锆很难与分子筛骨架铝发生同晶置换作用;采用无水乙醇浸渍法更有利于锆进入分子筛孔道中与骨架铝氧四面体相互作用,所制备的分子筛具有更高的结晶度和比表面积,更好的水热稳定性;含有锆改性Y型分子筛的裂化催化剂具有较高的重油转化能力和汽油收率,抗重金属污染能力强。
文摘A novel heavy oil catalytic cracking catalyst RCC-1 was developed by using the ultra-stable zeolite, which was hydrothermally treated and modified through cleaning its pores to serve as the active component. The chemical composition and physicochemical properties of RCC-1 catalyst were studied by XRF, BET, pore volume analysis, attrition index analysis, and particle size distribution determination methods, and its catalytic cracking performance was also evaluated by a microreactor for light oil cracking and the ACE device. The test results showed that the new type of heavy oil catalytic cracking catalyst RCC-1 had good physicochemical properties and heavy oil cracking ability, strong anti-metallic contamination capability, good product distribution, good coke selectivity and gasoline selectivity, and excellent reduction of gasoline olefin content characteristics.
文摘In the past several decades,SINOPEC has devoted continuously great efforts to the development of DCC technology,the only commercial process using heavy feeds aiming at propylene production.Recently,a series of research breakthroughs have been achieved in molecular refining.Based on the detailed analysis on the complex DCC reaction network,an innovative catalyst technology has been developed to Optimize Catalysis Kinetics (OCK in brief).The deep-cracking process can be improved with optimizing the availability of the active sites.The updated MFI and beta zeolites are used to boost the propylene selectivity.The latest generation catalyst DMMC-1 has been applied commercially.Compared with the best historical records in the past,the propylene yield upon application of the catalyst DMMC-1 increases by 2.4 m% coupled with an improved distribution of products.The DCC technology continues to assume a leading position for manufacturing propylene from heavy feedstocks.
