Cone-straight nozzle has been widely used in well bore cleaning,assisting drilling in petroleum industries due to its good clustering properties.The structure including cone angle and throat length has also been studi...Cone-straight nozzle has been widely used in well bore cleaning,assisting drilling in petroleum industries due to its good clustering properties.The structure including cone angle and throat length has also been studied by scholars and been optimized.However,the internal flow properties have not been investigated clearly especially the boundary layer flow.In this paper LES model is used to capture the small-scale flow state near the nozzle wall.The RNG k-epsilon model is used to validate the accuracy of the LES simulation,the simulation data shows a good agreement.Three different inlet velocities are considered in simulations.The velocity distribution,shear stress,boundary layer thickness,skin friction coefficient and Reynolds stress are analyzed,the boundary layer separation and transition are discussed.The state of flow inside nozzle is laminar with inlet velocity of 1 m/s and gradually transferred into turbulent with the increasing inlet velocity.The most severe turbulence is at the entrance of the throat section,the vortex structure appears at the entrance of converging section and dose not survive,the vortex structure appears in sequence along the throat section wall when the inlet velocity is set to 5 m/s and 10 m/s the flow properties along the conical nozzle are revealed clearly,the main flow resistance is mainly produced in throat section.All these works aim to provide theoretical support for the further processing optimization of the nozzle structure and reduce the flow resistance of nozzle.展开更多
Tubing collars’influence on hydrodynamic behavior of annular duct flow has been investigated using Particle Image Velocity(PIV)technology.PIV has become an efficient method for complex transient flows visualization.A...Tubing collars’influence on hydrodynamic behavior of annular duct flow has been investigated using Particle Image Velocity(PIV)technology.PIV has become an efficient method for complex transient flows visualization.A water flow loop with two replaceable variable cross-sections(VCS),75-90 mm and 90-110 mm,in a 129 mm inner diameter(ID)pipe was used.The whole field of the variable cross-section annulus(VCSA)was visualized,including forward-facing step(FFS),narrow annulus(NA),and backwardfacing step(BFS)flow.The VCSA ratio and Reynolds(Re)number influence on streamline distribution,velocity distribution,and turbulence intensity were discussed.Results showed that the recirculation is easier to form in BFS than FFS flow under the same condition.The VCSA ratio affects the formation of recirculation zones and the location of the reattachment point.Reynolds number mainly affects BFS flow by influencing the main velocity component-axial velocity.The turbulence intensity is relatively high in BFS than FFS flow and is larger at y/h>1.0 than y/h<1.0.Furthermore,the streamwise cohere nt structures reveal that the first two modes are predominant and represent the main characteristics of the flow by proper orthogonal decomposition(POD)method.展开更多
Through interface engineering and content control strategy,a PdBi bimetallic interface structure was constructed for the first time to selectively convert CO_(2)to formate with a remarkably high Faraday efficiency(FEf...Through interface engineering and content control strategy,a PdBi bimetallic interface structure was constructed for the first time to selectively convert CO_(2)to formate with a remarkably high Faraday efficiency(FEformate)of 94%and a partial current density(jformate)of 34 mA·cm^(−2)at−0.8 V vs.reversible hydrogen electrode(RHE)in an H-cell.Moreover,the PdBi interface electrocatalyst even exhibited a high current density of 180 mA·cm^(−2)with formate selectivity up to 92%in a flow cell and could steadily operate for at least 20 h.Electrochemical in-situ attenuated total reflection surface enhanced infrared absorption spectroscopy(ATR-SEIRAS)confirmed that the PdBi interface could greatly weaken the adsorption of*CO intermediates due to electronic and geometric effects.Density functional theory(DFT)calculations also established that the PdBi interface regulated the CO_(2)-to-formate pathway by reducing the energy barrier toward HCOOH and largely weakening the adsorption of*CO intermediates on the catalyst surface.This study reveals that the unique PdBi bimetallic interface can provide a novel platform to study the reaction mechanism through combining in-situ ATR-SEIRAS and DFT calculations.展开更多
基金financial support from National Key Research and Development Program of China(2019YFB1504202)111 Plan (Grant No.B17045)the National Science Fund for Distinguished Young Scholars (Grant No.51725404)。
文摘Cone-straight nozzle has been widely used in well bore cleaning,assisting drilling in petroleum industries due to its good clustering properties.The structure including cone angle and throat length has also been studied by scholars and been optimized.However,the internal flow properties have not been investigated clearly especially the boundary layer flow.In this paper LES model is used to capture the small-scale flow state near the nozzle wall.The RNG k-epsilon model is used to validate the accuracy of the LES simulation,the simulation data shows a good agreement.Three different inlet velocities are considered in simulations.The velocity distribution,shear stress,boundary layer thickness,skin friction coefficient and Reynolds stress are analyzed,the boundary layer separation and transition are discussed.The state of flow inside nozzle is laminar with inlet velocity of 1 m/s and gradually transferred into turbulent with the increasing inlet velocity.The most severe turbulence is at the entrance of the throat section,the vortex structure appears at the entrance of converging section and dose not survive,the vortex structure appears in sequence along the throat section wall when the inlet velocity is set to 5 m/s and 10 m/s the flow properties along the conical nozzle are revealed clearly,the main flow resistance is mainly produced in throat section.All these works aim to provide theoretical support for the further processing optimization of the nozzle structure and reduce the flow resistance of nozzle.
基金financial support of the National Key R&D Program of China(No.2019YFB1504102)the National Natural Science Foundation of China(52020105001)the National Science Fund for Distinguished Young Scholars(51725404)and their approval of publishing this paper。
文摘Tubing collars’influence on hydrodynamic behavior of annular duct flow has been investigated using Particle Image Velocity(PIV)technology.PIV has become an efficient method for complex transient flows visualization.A water flow loop with two replaceable variable cross-sections(VCS),75-90 mm and 90-110 mm,in a 129 mm inner diameter(ID)pipe was used.The whole field of the variable cross-section annulus(VCSA)was visualized,including forward-facing step(FFS),narrow annulus(NA),and backwardfacing step(BFS)flow.The VCSA ratio and Reynolds(Re)number influence on streamline distribution,velocity distribution,and turbulence intensity were discussed.Results showed that the recirculation is easier to form in BFS than FFS flow under the same condition.The VCSA ratio affects the formation of recirculation zones and the location of the reattachment point.Reynolds number mainly affects BFS flow by influencing the main velocity component-axial velocity.The turbulence intensity is relatively high in BFS than FFS flow and is larger at y/h>1.0 than y/h<1.0.Furthermore,the streamwise cohere nt structures reveal that the first two modes are predominant and represent the main characteristics of the flow by proper orthogonal decomposition(POD)method.
基金supported by the National Natural Science Foundation of China(Nos.22003074 and 22002087)Youth Innovation Promotion Association CAS,Shanghai Key Laboratory of Molecular Catalysis and Innovative Materials(No.2021MCIMKF03)Baoshan Iron&Steel Co.,Ltd.(Baosteel),located in Shanghai,China.
文摘Through interface engineering and content control strategy,a PdBi bimetallic interface structure was constructed for the first time to selectively convert CO_(2)to formate with a remarkably high Faraday efficiency(FEformate)of 94%and a partial current density(jformate)of 34 mA·cm^(−2)at−0.8 V vs.reversible hydrogen electrode(RHE)in an H-cell.Moreover,the PdBi interface electrocatalyst even exhibited a high current density of 180 mA·cm^(−2)with formate selectivity up to 92%in a flow cell and could steadily operate for at least 20 h.Electrochemical in-situ attenuated total reflection surface enhanced infrared absorption spectroscopy(ATR-SEIRAS)confirmed that the PdBi interface could greatly weaken the adsorption of*CO intermediates due to electronic and geometric effects.Density functional theory(DFT)calculations also established that the PdBi interface regulated the CO_(2)-to-formate pathway by reducing the energy barrier toward HCOOH and largely weakening the adsorption of*CO intermediates on the catalyst surface.This study reveals that the unique PdBi bimetallic interface can provide a novel platform to study the reaction mechanism through combining in-situ ATR-SEIRAS and DFT calculations.