Sediments from cryoconite holes and dirt cones on the surface of Svalbard glaciers:main chemical and physicochemical properties

The paper discussed the influence of the forms of sediment accumulation on the surface of glaciers on their chemical and physicochemical properties.The materials sampled from the surface of five glaciers of the Svalbard Archipelago was analyzed.We studied such forms of sediment accumulation as dirt cones-the ice core covered with sediments and cryoconite holes-hollows on the glacier surface containing cryoconite material.Parameters such as total organic carbon content,microbiological activity,pH,the content of mobile forms of potassium and phosphorus,and concentrations of heavy and trace metals were studied.Also,mesomorphological studies were carried out and the polydisperse composition of the sediments was determined.According to the results of this work,it was found that the content of organic carbon in the material selected from dirt cones and cryoconite holes can be up to 2.5%,but the content of clay particles in it is mainly at the 10–15%level.Potassium concentrations are up to 250 mg/kg,and phosphorus is up to 800 mg/kg.The content of metals is typical or lower than in the previously published data.The main influence on the chemical composition of materials has a geographical factor of the sampling site,rather than the form of material accumulation.

Migration of organic carbon and trace elements in the system glacier-soil in the Central Caucasus alpine environment

Rapid deglaciation is one of the most important challenges in the Earth science today.One reason of this is specific supraglacial sediments–cryoconites,which represent carbon-containing dust with organomineral matter and living organisms.Investigation of physical and chemical characteristics of cryoconites in the Central Caucasus is necessary in order to understand their influence on alpine territories biogeochemical cycles,pollution and development in conditions of intensive glacial melting and active anthropogenic influence.For this research cryoconites as well as moraines,soil-like bodies and soils have been sampled from the alpine Bezengi Glacier and adjacent Khulamo-Bezengi Gorge.Key physicochemical features(pH values,total organic carbon content,microbial respiration,particle-size distribution)as well as content of trace elements have been defined in sampled materials and several pollution indices(Geoaccumulation index,Contamination factor and Degree of pollution)have been calculated.Results obtained show low values of total organic carbon in cryoconites(max.0.23%)but high values(max.7.54%)in top horizon of soils located in floodplain,indicating its active fluvioglacial transfer which may further accelerate the development of soils.Microbiological activity in the studied soils was mostly influenced by additional input of labile organic carbon from cryoconites with water flows.Particle-size distribution was similar among the studied cryoconites,indicating dominance of sand fraction(up to 85.28%)while studied soils showed higher variability due to influence of weathering.Among the trace elements,cryoconites were mostly polluted by Zn(max.85.70 mg·kg^(-1))which corresponds to high pollution according to pollution indices;Pb(max.24.90 mg·kg^(-1))and Cu(max.17.40 mg·kg^(-1)),up to moderate pollution level.Redistribution of polluted cryoconite material as well as local anthropogenic activities increased pollution of periglacial soils by Zn(max.89.20 mg·kg^(-1)),Pb(max.15.00 mg·kg^(-1))and Cu(max.12.80 mg·kg^(-1)),which was also proven by the pollution indices with up to high level of pollution.