针对图像阴影去除算法中复杂地物或与阴影区域纹理相似的暗区域阴影去除不完全的问题,提出了一种注意力与多尺度融合的图像阴影去除算法。该算法基于生成对抗网络框架构建。利用自定义的空洞残差块进行特征提取,获得精确的阴影特征信息...针对图像阴影去除算法中复杂地物或与阴影区域纹理相似的暗区域阴影去除不完全的问题,提出了一种注意力与多尺度融合的图像阴影去除算法。该算法基于生成对抗网络框架构建。利用自定义的空洞残差块进行特征提取,获得精确的阴影特征信息并输入到注意力引导的编码网络;在注意力引导的编码阶段进行多尺度的特征融合,获取不同层次的感受野,使编码器能够在不同尺度上捕捉上下文信息;利用多重注意力机制引导判别网络对生成的无阴影图像进行鉴别,进而减少判别网络关键信息损失,提高判别网络的鉴别效果。分别在ISTD(dataset with image shadow triplets)与SRD(dataset for shadow removal)公开数据集上进行验证,实验结果表明:该算法视觉效果表现良好,单幅阴影去除后的图片与数据集中真实无阴影图片进行对比,SSIM(structural similarity)可达到0.978,PSNR(peak signal to noise ratio)可达到32.2 dB,RMSE(root mean squared error)可达到6.2,相比同类算法,具有显著优势,且对复杂地物或暗区域阴影去除效果良好。展开更多
Perovskite variants have attracted wide interest because of the lead-free nature and strong self-trapped exciton (STE) emission. Divalent Sn(II) in CsSnX3 perovskites is easily oxidized to tetravalent Sn(IV), and the ...Perovskite variants have attracted wide interest because of the lead-free nature and strong self-trapped exciton (STE) emission. Divalent Sn(II) in CsSnX3 perovskites is easily oxidized to tetravalent Sn(IV), and the resulted Cs2SnCl6 vacancy-ordered perovskite variant exhibits poor photoluminescence property although it has a direct band gap. Controllable doping is an effective strategy to regulate the optical properties of Cs2SnX6. Herein, combining the first principles calculation and spectral analysis, we attempted to understand the luminescence mechanism of Te4+-doped Cs2SnCl6 lead-free perovskite variants. The chemical potential and defect formation energy are calculated to confirm theoretically the feasible substitutability of tetravalent Te4+ ions in Cs2SnCl6 lattices for the Sn-site. Through analysis of the absorption, emission/excitation, and time-resolved photoluminescence (PL) spectroscopy, the intense green-yellow emission in Te4+:Cs2SnCl6 was considered to originate from the triplet Te(IV) ion 3P1→1S0 STE recombination. Temperature-dependent PL spectra demonstrated the strong electron-phonon coupling that inducing an evident lattice distortion to produce STEs. We further calculated the electronic band structure and molecular orbital levels to reveal the underlying photophysical process. These results will shed light on the doping modulated luminescence properties in stable lead-free Cs2MX6 vacancy-ordered perovskite variants and be helpful to understand the optical properties and physical processes of doped perovskite variants.展开更多
文摘针对图像阴影去除算法中复杂地物或与阴影区域纹理相似的暗区域阴影去除不完全的问题,提出了一种注意力与多尺度融合的图像阴影去除算法。该算法基于生成对抗网络框架构建。利用自定义的空洞残差块进行特征提取,获得精确的阴影特征信息并输入到注意力引导的编码网络;在注意力引导的编码阶段进行多尺度的特征融合,获取不同层次的感受野,使编码器能够在不同尺度上捕捉上下文信息;利用多重注意力机制引导判别网络对生成的无阴影图像进行鉴别,进而减少判别网络关键信息损失,提高判别网络的鉴别效果。分别在ISTD(dataset with image shadow triplets)与SRD(dataset for shadow removal)公开数据集上进行验证,实验结果表明:该算法视觉效果表现良好,单幅阴影去除后的图片与数据集中真实无阴影图片进行对比,SSIM(structural similarity)可达到0.978,PSNR(peak signal to noise ratio)可达到32.2 dB,RMSE(root mean squared error)可达到6.2,相比同类算法,具有显著优势,且对复杂地物或暗区域阴影去除效果良好。
基金This work was supported by the National Natural Science Foundation of China(Nos.21661010 and 11774134)Guangxi Natural Science Foundation(No.2017GXNSFGA198005)+1 种基金Natural Science Foundation of Hunan Province(No.2020JJ4424)Research Foundation of Education Bureau of Hunan Province(No.18A009)。
文摘Perovskite variants have attracted wide interest because of the lead-free nature and strong self-trapped exciton (STE) emission. Divalent Sn(II) in CsSnX3 perovskites is easily oxidized to tetravalent Sn(IV), and the resulted Cs2SnCl6 vacancy-ordered perovskite variant exhibits poor photoluminescence property although it has a direct band gap. Controllable doping is an effective strategy to regulate the optical properties of Cs2SnX6. Herein, combining the first principles calculation and spectral analysis, we attempted to understand the luminescence mechanism of Te4+-doped Cs2SnCl6 lead-free perovskite variants. The chemical potential and defect formation energy are calculated to confirm theoretically the feasible substitutability of tetravalent Te4+ ions in Cs2SnCl6 lattices for the Sn-site. Through analysis of the absorption, emission/excitation, and time-resolved photoluminescence (PL) spectroscopy, the intense green-yellow emission in Te4+:Cs2SnCl6 was considered to originate from the triplet Te(IV) ion 3P1→1S0 STE recombination. Temperature-dependent PL spectra demonstrated the strong electron-phonon coupling that inducing an evident lattice distortion to produce STEs. We further calculated the electronic band structure and molecular orbital levels to reveal the underlying photophysical process. These results will shed light on the doping modulated luminescence properties in stable lead-free Cs2MX6 vacancy-ordered perovskite variants and be helpful to understand the optical properties and physical processes of doped perovskite variants.
